10-ethylphenazin-2(10H)-one | 42355-92-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 10-ethylphenazin-2(10H)-one
• 英文别名: 10-ethyl-phenazinium-2-olate；5-ethyl-3-hydroxy-phenazinium betaine；5-Aethyl-3-hydroxy-phenazinium-betain；5-ethyl 3-phenazinone；9-Aethyl-phenazinon-(2)；5-Ethyl-phenazin-3-one；10-ethylphenazin-2-one
• CAS: 42355-92-0
• 化学式: C₁₄H₁₂N₂O
• 分子量: 224.262
• InChiKey: LMZPSNYJVWNLHJ-UHFFFAOYSA-N

物化性质

• 沸点：
  351.1±42.0 °C(Predicted)
• 密度：
  1.21±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  32.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  10-ethylphenazin-2(10H)-one 在 硫酸 、 硝酸 作用下， 生成 5-ethyl-3-hydroxy-4-nitro-phenazinium-betaine
  参考文献：
  名称：

  Serebrjanyi, Ukrainskij Khimicheskij Zhurnal, 1956, vol. 22, p. 504,509

  摘要：

  DOI：
• 作为产物：
  描述：

  酚嗪 在 乙醚 、 乙基溴化镁 作用下， 生成 10-ethylphenazin-2(10H)-one
  参考文献：
  名称：

  Kiprianow; Priluzkii, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 1020,1025; engl. Ausg. S. 999, 1003

  摘要：

  DOI：

文献信息

• Synthesis, Photochemical Properties, and Cytotoxicity of 10-Alkylphenazin-2(10H)-ones
  作者：Kouji Kuramochi、Haruki Kohatsu、Takuya Hosokai、Kenji Ohgane、Shogo Kamo、Shinji Kamisuki、Yutaro Machida、Ryota Kobayashi、Tsuneomi Kawasaki

  DOI：10.3987/com-21-14420

  日期：——

  In the present study, the synthesis of a variety of 10-alkylphenazin-2(10H)-ones by oxidative coupling between N-alkylbenzene-1,2-diamine and 1,2,4-benzenetriol under an oxygen atmosphere was realized, and their photochemical and biological properties were investigated. 10-Methylphenazin-2(10H)-one, a reddish orange pigment, exhibited fluorescence in the visible light region upon exposure to ultraviolet

  在本研究中，通过在氧气气氛下，N-烷基苯-1，2-二胺和1,2,4-苯三酚之间的氧化偶联，实现了多种10-烷基吩嗪-2（10 H ）-的合成，并对其光化学和生物学特性进行了研究。10-Methylphenazin-2（10 H ）-one，一种红橙色颜料，在暴露于紫外光后在可见光区域显示荧光。有趣的是，10-methylphenazin-2（10 H ）-one发出的荧光由两个成分组成。另外，进行了各种合成化合物的细胞毒性评价。在这项研究中测试的化合物中，10-methylphenazin-2（10 H）-与正常MRC-5细胞相比，对人癌A549细胞表现出最具选择性的细胞毒活性。
• Monoaminophenazine leuco dyes and photothermographic materials containing same
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0671393A1

  公开（公告）日：1995-09-13

  Photothermographic elements incorporating leuco forms of phenazinium dyes to provide a developed colour image. The dye has a nucleaus of the general formula: in which;    X represents    Y is H or any substituent other than amino or amido,    R¹, R², R⁴ and R¹⁰ are independently selected from H, alkyl, aryl, alkylsulfonyl, arysulfonyl, alkylcarbonyl, arylcarbonyl, or    R¹ and R² together represent the necessary atoms to complete a cyclic structure or one or more of R¹, R² and R⁴ represent the necessary atoms to complete a cyclic structure fused to the nucleus having skeletal atoms selected from C, N, 0 and S, and    R¹¹ represents any group which will not prevent oxidative cleavage of the X-N bond,    with the proviso that when R¹ is C₂H₅    R² is not C₂H₄NHSO₂CH₃.

  光热成像元件采用苯并二氮杂染料的白态形式，以提供发展后的彩色图像。该染料具有一般式的核：其中; X代表; Y为H或任何不是氨基或酰胺基的取代基，R¹，R²，R⁴和R¹⁰独立地选自H，烷基，芳基，烷基磺酰基，芳基磺酰基，烷基羰基，芳基羰基，或R¹和R²一起代表必要的原子以完成环状结构，或者R¹，R²和R⁴中的一个或多个代表必要的原子以完成与骨架原子（选自C，N，0和S）融合的环状结构，R¹¹代表任何不会防止X-N键的氧化裂解的基团，但当R¹为C₂H₅时，R²不为C₂H₄NHSO₂CH₃。
• 359. The phenazine series. Part VI. Reactions of alkyl phenazonium salts; the phenazyls
  作者：Henry McIlwain

  DOI：10.1039/jr9370001704

  日期：——
• Kiprianow; Priluzkii, Ukrainskij Khimicheskij Zhurnal, 1956, vol. 22, p. 359,361
  作者：Kiprianow、Priluzkii

  DOI：——

  日期：——
• Exterior electrochromic reflective mirror element for a vehicular rearview mirror assembly
  申请人：Varaprasad V. Desaraju

  公开号：US20070184284A1

  公开（公告）日：2007-08-09

  An exterior electrochromic reflective mirror element for a vehicular exterior rearview mirror assembly comprises an electrochromic cross-linked polymeric solid film disposed between a first substrate and a second substrate. The electrochromic cross-linked polymeric solid film contacts a transparent conductive layer of the first substrate and a conductive layer comprising a metallic reflective layer of the second substrate. A visual indicator display is disposed to the rear of said second substrate and is part of a blind spot detection and display system and is actuated to emit light responsive to a detection of another overtaking vehicle in a side lane. Light emitted by the visual indicator display passes through the second substrate, through the electrochromic cross-linked polymeric solid film and through the first substrate to be viewed by a driver of the vehicle equipped with the exterior electrochromic reflective mirror element.