3-(n-nonyl)tetrahydrothiophene | 125213-02-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环戊烷
• 英文名称: 3-(n-nonyl)tetrahydrothiophene
• 英文别名: 3-Nonyltetrahydrothiophene；3-Nonylthiolane
• CAS: 125213-02-7
• 化学式: C₁₃H₂₆S
• 分子量: 214.415
• InChiKey: SIJCEFKRQXCLMU-UHFFFAOYSA-N

物化性质

• 沸点：
  138-140 °C(Press: 1 Torr)
• 密度：
  0.888±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-十一烯 在 1,2,3,4,5,6,7,8-八硫杂环辛烷 、 二氯二茂锆 、 三乙基铝 作用下， 生成 3-(n-nonyl)tetrahydrothiophene
  参考文献：
  名称：

  Nontraditional approach to the synthesis of 3-substituted tetrahydrothiophenes and tetrahydroselenophenes

  摘要：

  DOI：

  10.1007/bf00957191

文献信息

• Zirconium-catalyzed preparation of aluminacyclopentanes and synthesis of five-membered carbo- and heterocycles
  作者：Usein M Dzhemilev、Askhat G Ibragimov、Ruslan R Gilyazev、Leila O Khafizova

  DOI：10.1016/j.tet.2003.10.082

  日期：2004.2

  Novel ‘one-pot’ catalytic methods for the synthesis of cyclopentanols, tetrahydrothiophenes, silacyclopentanes and phospholanes are based on successive transformations of olefins and organoaluminium compounds (R2AlR′) in the presence of Cp2ZrCl2 catalyst. In situ generated aluminacyclopentanes serve as common intermediates in these processes.

  用于合成环戊醇，四氢噻吩，硅环戊烷和膦酸酯的新型“一锅法”催化方法是基于在Cp 2 ZrCl 2催化剂存在下烯烃和有机铝化合物（R 2 AlR'）的连续转化。原位生成的氧化铝环戊烷在这些过程中用作常见的中间体。
• Regio- and stereoselective synthesis for a novel class of organoaluminium compounds — substituted aluminacyclopentanes and aluminacyclopentenes assis
  作者：U.M. Dzhemilev、A.G. Ibragimov

  DOI：10.1016/0022-328x(94)88022-0

  日期：1994.2

  A novel regio- and stereoselective method has been developed for the catalytic cyclometallation of olefins and acetylenes with alkylalanes in the presence of Cp(2)ZrCl(2), to give in one stage high yields of 3-substituted aluminacyclopentanes and aluminacyclopentenes. Applications of these reactions to a wide range of linear and cyclic olefins and to those containing functional substituents have been studied. The transformation of the aluminacyclopentanes thus produced, into five-membered heterocycles, mono- and di-substituted cyclobutanes and cyclopropanes, has been demonstrated.
• DZHEMILEV, U. M.;M.;IBRAGIMOV, A. T.;ZOLOTAREV, A. P.;TOLSTIKOV, T. A., IZV. AN CCCP. CEP. XIM.,(1989) N, S. 1444
  作者：DZHEMILEV, U. M.、M.、IBRAGIMOV, A. T.、ZOLOTAREV, A. P.、TOLSTIKOV, T. A.

  DOI：——

  日期：——