di(4-trifluoromethylphenyl)tindichloride | 77459-83-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di(4-trifluoromethylphenyl)tindichloride
• 英文别名: (p-CF3C6H4)2SnCl2；Dichloro-bis[4-(trifluoromethyl)phenyl]stannane
• CAS: 77459-83-7
• 化学式: C₁₄H₈Cl₂F₆Sn
• 分子量: 479.824
• InChiKey: HRGZOFKEQAQKNT-UHFFFAOYSA-L

物化性质

• 沸点：
  346.2±52.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.76
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  di(4-trifluoromethylphenyl)tindichloride 以 正己烷 、 苯 为溶剂， 生成 [(p-CF3C6H4)2Sn(OiPr)2]2
  参考文献：
  名称：

  Ring-opening polymerization of l-lactide by organotin(IV)alkoxides, R2Sn(OPri)2: Estimation of the activation parameters

  摘要：

  The ring-opening polymerization of L-lactide, L-LA, to give poly-L-lactide by R2Sn(OPri)(2) compounds, where R = Bu-n and p-XC6H4 (X = CF3, F, H, Me and OMe) has been studied in benzene over a temperature range. There is a relatively small variation in Delta H not equal as a function of R with all the values falling within the range 11 +/- 2 kcal mol(-1). The entropy of activation, Delta S not equal, is consistently large and negative, -50 +/- 5 eu, supporting the view that the ring-opening event, the enchainment step involves a highly ordered transition state. The crystal and molecular structures of the compounds Ph2Sn(OPri)(2), (p-FC6H4)(2)Sn(OPri)(2) and (p-Me2NC6H4)(3)SnOPri are also reported. While the latter compound is monomeric in the solid state the former are both dimeric with a pair of bridging OPri ligands. (c) 2007 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2007.06.002
• 作为产物：
  描述：

  对溴三氟甲苯 、 四氯化锡 反应 120.0h， 以61%的产率得到di(4-trifluoromethylphenyl)tindichloride
  参考文献：
  名称：

  “推-推和推-推”聚锡烷†

  摘要：

  描述了锡锡骨架上带有“推”或“拉”部分的聚锡烷的合成和表征。前体的四芳基- （1，2）锡烷转化成单- （3）和二氯- （4，5）由任一顺序氯化或通过用的SnCl再分配反应锡烷4。使用大量过量的（10x）NaBH 4将化合物4和5转化为可聚合的二氢化锡单体6和7。具有给电子芳基取代基的均聚物8（p -MeOC 6使用威尔金森氏催化剂通过脱氢聚合合成H 4-）。尝试使用相似的条件由7的脱氢偶联制备具有吸电子芳基取代基（p -CF 3 C 6 H 4-）的均聚物9，仅导致形成低分子量的低聚物。通过（n -Bu）2 Sn（NEt 2）2与单体6或7的缩聚反应合成了两种交替的聚合物10和11。。第一种是“推-推”交替聚合物10，它由一个重复单元组成，该重复单元在相邻的锡中心处由两个不同的供电子基团（p -MeOC 6 H 4-，n -Bu ）组成。第二种是“推挽式”交替聚合物11，在相邻的锡原子上同时带有给电子基团（n

  DOI：

  10.1039/c8dt03043j

文献信息

• Biddle, Brian N.; Gray, John S.; Crowe, Alan J., Journal of the Chemical Society, Dalton Transactions
  作者：Biddle, Brian N.、Gray, John S.、Crowe, Alan J.

  DOI：——

  日期：——
• “Push–push and push–pull” polystannanes
  作者：J. S. Dhindsa、B. F. Jacobs、A. J. Lough、D. A. Foucher

  DOI：10.1039/c8dt03043j

  日期：——

  moieties attached to the tin backbone are described. Precursor tetra aryl- (1, 2) stannanes were converted to mono- (3) and dichloro- (4, 5) stannanes by either sequential chlorination or by redistribution reactions with SnCl4. Compounds 4 and 5 were transformed to polymerisable tin dihydride monomers 6 and 7 using a large excess (10×) of NaBH4. Homopolymer 8 with electron donating aryl substituents (p-MeOC6H4-)

  描述了锡锡骨架上带有“推”或“拉”部分的聚锡烷的合成和表征。前体的四芳基- （1，2）锡烷转化成单- （3）和二氯- （4，5）由任一顺序氯化或通过用的SnCl再分配反应锡烷4。使用大量过量的（10x）NaBH 4将化合物4和5转化为可聚合的二氢化锡单体6和7。具有给电子芳基取代基的均聚物8（p -MeOC 6使用威尔金森氏催化剂通过脱氢聚合合成H 4-）。尝试使用相似的条件由7的脱氢偶联制备具有吸电子芳基取代基（p -CF 3 C 6 H 4-）的均聚物9，仅导致形成低分子量的低聚物。通过（n -Bu）2 Sn（NEt 2）2与单体6或7的缩聚反应合成了两种交替的聚合物10和11。。第一种是“推-推”交替聚合物10，它由一个重复单元组成，该重复单元在相邻的锡中心处由两个不同的供电子基团（p -MeOC 6 H 4-，n -Bu ）组成。第二种是“推挽式”交替聚合物11，在相邻的锡原子上同时带有给电子基团（n
• Ring-opening polymerization of l-lactide by organotin(IV)alkoxides, R2Sn(OPri)2: Estimation of the activation parameters
  作者：Malcolm H. Chisholm、Judith C. Gallucci、Clemens Krempner

  DOI：10.1016/j.poly.2007.06.002

  日期：2007.9

  The ring-opening polymerization of L-lactide, L-LA, to give poly-L-lactide by R2Sn(OPri)(2) compounds, where R = Bu-n and p-XC6H4 (X = CF3, F, H, Me and OMe) has been studied in benzene over a temperature range. There is a relatively small variation in Delta H not equal as a function of R with all the values falling within the range 11 +/- 2 kcal mol(-1). The entropy of activation, Delta S not equal, is consistently large and negative, -50 +/- 5 eu, supporting the view that the ring-opening event, the enchainment step involves a highly ordered transition state. The crystal and molecular structures of the compounds Ph2Sn(OPri)(2), (p-FC6H4)(2)Sn(OPri)(2) and (p-Me2NC6H4)(3)SnOPri are also reported. While the latter compound is monomeric in the solid state the former are both dimeric with a pair of bridging OPri ligands. (c) 2007 Published by Elsevier Ltd.