申请人:TEIJIN LIMITED
公开号:EP0169926A1
公开(公告)日:1986-02-05
A polyester composition with an excellent high-speed melt-spinning property, comprising
(A) 100 parts by weight of a matrix polyester resin comprising at least 80 molar % of an ethylene terephthalate recurring unit, and
(B) 0.2 to 7 parts by weight of a dispersoid dispersed in the matrix,
the dispersoid being such that, when it is contained in a predetermined amount (w) in a typical matrix polyester resin consisting of a polyethylene terephthalate having an intrinsic viscosity of 0.640, the resultant exemplary polyester composition satisfies the relationship (1):
wherein:
γ̇1 = shearing rate of 0.01 sec-1; γ̇2 = shearing rate of 5.0 sec-'; ηγ̇1(w) = melt viscosity (poise = 1/10 N·sec·m-2) of the exemplary polyester composition at γ̇1; ηγ̇1(0) = melt viscosity of matrix polyester resin at γ̇1; ηγ̇2(w) = melt viscosity of the exemplary polyester composition at γ̇2; and ηγ̇2(0) = melt viscosity of the matrix polyester resin at γ̇2.
一种具有优异高速熔融纺丝性能的聚酯组合物,包括
(A) 100 重量份的基体聚酯树脂,其中包含至少 80 摩尔%的对苯二甲酸乙二醇酯复 合单元,以及
(B) 0.2 至 7 份(按重量计)分散在基体中的分散体、
当分散体以预定量 (w) 加入由固有粘度为 0.640 的聚对苯二甲酸乙二醇酯组成的典型基体聚酯树脂中时,所得到的示例性聚酯组合物满足关系式 (1):
其中
γ1 = 剪切速率为 0.01 秒-1; γ2 = 剪切速率为 5.0 sec-';ηγ掺1(w) = 示例聚酯组合物在 γ掺1时的熔融粘度(泊 = 1/10 N-sec-m-2);ηγ掺1(0) = 基质聚酯树脂在 γ掺1时的熔融粘度;ηγ2(w) = 示例聚酯组合物在 γ2 时的熔融粘度;以及 ηγ2(0) = 基质聚酯树脂在 γ2 时的熔融粘度。