Diiodoplatinum;triphenylstibane | 24151-01-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Diiodoplatinum;triphenylstibane
• 英文别名: diiodoplatinum;triphenylstibane
• CAS: 24151-01-7
• 化学式: C₃₆H₃₀I₂PtSb₂
• 分子量: 1155.02
• InChiKey: SYEWPQWZODPORO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.59
• 重原子数：
  41
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  、 三苯基锑 以 苯 为溶剂， 生成 Diiodoplatinum;triphenylstibane
  参考文献：
  名称：

  Preparation and properties of some triphenylarsine- and triphenyl-stibine-stabilized organoplatinum(II) compounds

  摘要：

  DOI：

  10.1021/ic50080a028

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.1.6.4.4, page 55 - 78
  作者：

  DOI：——

  日期：——
• Inorganic Linkage Isomerism of the Thiocyanate Ion
  作者：John L. Burmeister、Fred Basolo

  DOI：10.1021/ic50021a025

  日期：1964.11
• Palladium(II) and platinum(II) complexes of monodentate tertiary stibines
  作者：C.A. McAuliffe、I.E. Niven、R.V.(Dick) Parish

  DOI：10.1016/s0020-1693(00)90925-3

  日期：1977.1
• Trans influence of triphenylstibine. Crystal and molecular structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]
  作者：Ola F. Wendt、Alessandra Scodinu、Lars I. Elding

  DOI：10.1016/s0020-1693(97)06130-6

  日期：1998.8

  Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed. (C) 1998 Elsevier Science S.A. All rights reserved.