1-methyl-3-methylthiopyrrole | 102093-74-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1-methyl-3-methylthiopyrrole
• 英文别名: 3-methyltio-N-methylpyrrole；1-Methyl-3-methylsulfanylpyrrole
• CAS: 102093-74-3
• 化学式: C₆H₉NS
• 分子量: 127.21
• InChiKey: YFAGTINXWCVHAK-UHFFFAOYSA-N

物化性质

• 沸点：
  203.4±13.0 °C(Predicted)
• 密度：
  1.02±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  30.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-methyl-2-methylthiopyrrole 在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以33%的产率得到1-methyl-3-methylthiopyrrole
  参考文献：
  名称：

  Gilow, Helmuth M.; Brown, Christopher S.; Copeland, John N., Journal of Heterocyclic Chemistry, 1991, vol. 28, # 4, p. 1025 - 1034

  摘要：

  DOI：

文献信息

• HETEROCYCLIC COMPOUNDS AS ADENOSINE ANTAGONISTS
  申请人：GiraFpharma LLC

  公开号：US20190023666A1

  公开（公告）日：2019-01-24

  Aminopyrazine compounds as modulators of an adenosine receptor are provided. The compounds may find use as therapeutic agents for the treatment of diseases mediated through a G-protein-coupled receptor signaling pathway and may find particular use in oncology.

  提供了氨基吡嗪化合物作为腺苷受体的调节剂。这些化合物可能作为治疗经由G蛋白偶联受体信号通路介导的疾病的治疗剂，并且可能在肿瘤学中发挥特定作用。
• Synthesis of 2- and 3-Substituted N-Methylpyrroles
  作者：Elena Dvornikova、Krystyna Kamieńska-Trela

  DOI：10.1055/s-2002-32578

  日期：——

  A reliable method of synthesis of 3-bromo-N-methylpyrrole by the use of N-bromosuccinimide and a catalytic amount of PBr 3 is reported. The method described opens a facile route to a variety of 3-substituted pyrroles, which are otherwise difficult to access. In addition, conditions under which pure 2-bromo-N-methylpyrrole can be obtained have been established.

  报道了一种使用 N-溴代琥珀酰亚胺和催化量的 PBr 3 合成 3-溴-N-甲基吡咯的可靠方法。所描述的方法为各种 3-取代吡咯开辟了一条容易的途径，否则很难获得。此外，已经建立了可以获得纯 2-溴-N-甲基吡咯的条件。
• Process of manufacturing an electrically conductive material and a secondary battery using the electrically conductive material
  申请人：SANYO ELECTRIC CO., LTD.

  公开号：EP0219063A2

  公开（公告）日：1987-04-22

  An electrically conductive material containing no substantial amount of water and prepared by polymerizing, in the presence of an oxidizing agent, a compound having conjugated double bonds on a base material in a gas phase. The base material has spaces capable of retaining the oxidizing agent. The elecrically conductive material is used for at least one electrode of a secondary battery.

  一种不含大量水分的导电材料，其制备方法是在有氧化剂存在的情况下，在气相中聚合基材上具有共轭双键的化合物。基体材料具有能够保留氧化剂的空间。这种导电材料可用于二次电池的至少一个电极。
• Method for the preparation of a polymeric shaped article containing an electrically conductive polymer
  申请人：DSM N.V.

  公开号：EP0587204A1

  公开（公告）日：1994-03-16

  The invention relates to a method for the preparation of a polymeric shaped article containing an electrically conductive polymer, wherein a base shaped article containing a matrix polymer is contacted with an anode in the presence of an electrolyte-containing medium containing monomer units, which on polymerisation to form an electrically conductive polymer, and wherein a voltage is applied between the anode and a second electrode which is in contact with the electrolyte-containing medium. The method according to the invention is characterised in that the applied base shaped article possesses electrically conducting properties and that the contact between the shaped article and the anode is established by moving the article along the anode, at least part of the article being in contact with the anode. It has appeared that, in the method according to the invention, the shaped article does not adhere to the electrode so that the method may be practised continuously. A further advantage of the shaped article failing to adhere to the electrode is that the method according to the invention generates very little waste. Furthermore, it has appeared that the method according to the invention allows a shaped article to be produced with a very short polymerisation time, the electrically conductive polymer in which being homogeneously distributed. The applied base shaped article does not swell during wetting, so that the mechanical properties of the base shaped article do not deteriorate. As a result, if the method is applied, for instance, continuously, a higher rate of production can be applied.

  本发明涉及一种制备含有导电聚合物的聚合物成型品的方法，其中含有基质聚合物的基质成型品在含有单体单元的含电解质介质存在下与阳极接触，单体单元聚合后形成导电聚合物，在阳极和与含电解质介质接触的第二电极之间施加电压。根据本发明的方法，其特征在于所应用的基底成型品具有导电性能，成型品和阳极之间的接触是通过沿阳极移动成型品来建立的，成型品的至少一部分与阳极接触。根据本发明的方法，成型物品不会粘附在电极上，因此该方法可以连续使用。成型物品不附着在电极上的另一个优点是，根据本发明的方法产生的废料极少。此外，根据本发明的方法可以在很短的聚合时间内生产出异型制品，其中的导电聚合物分布均匀。在润湿过程中，应用的基底成型品不会膨胀，因此基底成型品的机械性能不会降低。因此，如果连续使用该方法，可以提高生产率。
• Dispersion of electrically conductive particles in a dispersing medium
  申请人：DSM N.V.

  公开号：EP0589529A1

  公开（公告）日：1994-03-30

  The invention relates to a dispersion of electrically conductive particles, comprising a binder and an electrically conductive polymer, and a stabiliser in a dispersing medium. The dispersion according to the invention is characterised in that the particles contain a non-ionic stabiliser. It has been found that the stability of the dispersion according to the invention is very good. In addition the dispersion according to the invention is extremely suitable for providing objects with a coating in a simple manner. The applied coating has good electrically conductive properties as well as good coating properties. The applied coating is homogeneously distributed over the coated object. Moreover the applied coating appears to adhere well to the object.

  本发明涉及一种导电微粒的分散体，包括分散介质中的粘合剂、导电聚合物和稳定剂。根据本发明的分散体的特点是颗粒中含有非离子稳定剂。研究发现，本发明的分散液稳定性非常好。此外，本发明的分散体非常适合以简单的方式为物体提供涂层。涂覆的涂层具有良好的导电性能和涂覆性能。涂层均匀地分布在被涂物体上。此外，涂覆的涂层看起来与物体附着良好。