trifluoro-1,1,1 diphenyl-2,2 propane | 112754-65-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trifluoro-1,1,1 diphenyl-2,2 propane
• 英文别名: 1,1,1-Trifluoro-2,2-diphenylpropane；(1,1,1-trifluoro-2-phenylpropan-2-yl)benzene
• CAS: 112754-65-1
• 化学式: C₁₅H₁₃F₃
• 分子量: 250.263
• InChiKey: BZLSCVAPEFKLSB-UHFFFAOYSA-N

物化性质

• 沸点：
  262.2±40.0 °C(Predicted)
• 密度：
  1.142±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险等级：
  IRRITANT
• 海关编码：
  2903999090

反应信息

• 作为产物：
  描述：

  1,1,1-三氟丙酮 、 苯 在 三氯化铝 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以20%的产率得到1-苯基-1-(三氟甲基)乙基氯
  参考文献：
  名称：

  Bonnet-Delpon, Daniele; Charpentier-Morize, Micheline, Bulletin de la Societe Chimique de France, 1986, # 6, p. 933 - 936

  摘要：

  DOI：

文献信息

• AROMATIC SULFONIC ACID DERIVATIVE, SULFONIC ACID GROUP-CONTAINING POLYMER, BLOCK CO-POLYMER, POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED BODY, AND SOLID POLYMER FUEL CELL
  申请人：Izuhara Daisuke

  公开号：US20140213671A1

  公开（公告）日：2014-07-31

  Provided are an aromatic sulfonic acid derivative and a sulfonic acid group-containing polymer, each of which has excellent proton conductivity even under low humidification conditions, while having excellent mechanical strength and chemical stability, and enables a solid polymer fuel cell to achieve high output and excellent physical durability when used therein. This aromatic sulfonic acid derivative has a specific structure and is characterized in that a sulfonic acid group is introduced into more than 50% of all the phenyl groups. This sulfonic acid group-containing polymer is characterized by being obtained by polymerization using the aromatic sulfonic acid derivative, and is also characterized by having a specific structure.

  提供了一种芳香磺酸衍生物和含有磺酸基团的聚合物，它们在低湿化条件下具有优异的质子导电性，同时具有优异的机械强度和化学稳定性，可使固体聚合物燃料电池在其中使用时实现高输出和优异的物理耐久性。这种芳香磺酸衍生物具有特定结构，其特点是将磺酸基团引入到超过50%的苯基中。这种含有磺酸基团的聚合物的特点是通过使用芳香磺酸衍生物进行聚合得到，并且具有特定的结构。
• DIAMINE COMPOUND, AND HEAT-RESISTANT RESIN OR HEAT-RESISTANT RESIN PRECURSOR USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20170334837A1

  公开（公告）日：2017-11-23

  Provided are a photosensitive resin composition which has excellent pattern processabilities (high sensitivity and high resolution) and is excellent in chemical resistance and thermal resistance after thermally treated; a heat-resistant resin or heat-resistant resin precursor used for the composition; and a diamine compound which is a raw material of the resin and the precursor. The diamine compound is a diamine compound represented by a general formula (1).

  提供了一种具有优异图案加工性（高灵敏度和高分辨率）且在热处理后具有优异化学耐性和热耐性的光敏树脂组合物；用于该组合物的耐热树脂或耐热树脂前体；以及作为树脂和前体原料的二胺化合物。该二胺化合物是由通式（1）表示的二胺化合物。
• POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED PRODUCT USING THE POLYMER ELECTROLYTE MATERIAL AND METHOD FOR MANUFACTURING THE POLYMER ELECTROLYTE MOLDED PRODUCT, MEMBRANE ELECTRODE COMPOSITE, AND SOLID POLYMER FUEL CELL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150155582A1

  公开（公告）日：2015-06-04

  It is an object of the present invention to provide a polymer electrolyte material which has excellent proton conductivity even under the conditions of a low humidity or a low temperature and is excellent in mechanical strength and fuel barrier properties, and which moreover can achieve high output, high energy density and long-term durability in forming a polymer electrolyte fuel cell therefrom, and a polymer electrolyte form article using the same and a method for producing the same, a membrane electrode assembly and a polymer electrolyte fuel cell, each using the same. The present invention employs the following means. Namely, the polymer electrolyte material of the present invention is a polymer electrolyte material including a constituent unit (A1) containing an ionic group and a constituent unit (A2) substantially not containing an ionic group, wherein a phase separation structure is observed by a transmission electron microscope and a crystallization heat measured by differential scanning calorimetry is 0.1 J/g or more, or a phase separation structure is observed by a transmission electron microscope and the degree of crystallinity measured by wide angle X-ray diffraction is 0.5% or more. Also, the polymer electrolyte form article, the membrane electrode assembly and the polymer electrolyte fuel cell of the present invention are characterized by being composed of such polymer electrolyte materials.

  本发明的目的是提供一种聚合物电解质材料，即使在低湿度或低温条件下也具有优异的质子导电性能，且具有优异的机械强度和阻挡燃料的性能，而且可以实现高输出、高能量密度和长期耐久性，形成聚合物电解质燃料电池，以及使用相同的聚合物电解质形式的文章和生产方法，以及膜电极组件和聚合物电解质燃料电池。本发明采用以下手段。即，本发明的聚合物电解质材料是一种聚合物电解质材料，包括含有离子基团的构成单元（A1）和基本不含离子基团的构成单元（A2），其中透射电子显微镜观察到相分离结构，差示扫描量热法测量的结晶热为0.1 J/g或更高，或透射电子显微镜观察到相分离结构，广角X射线衍射测量的结晶度为0.5％或更高。此外，本发明的聚合物电解质形式的文章、膜电极组件和聚合物电解质燃料电池的特点是由这种聚合物电解质材料组成。
• METHOD FOR PRODUCING POLYMER ELECTROLYTE MOLDED ARTICLE, POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MEMBRANE, AND POLYMER ELECTROLYTE FUEL CELL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150200413A1

  公开（公告）日：2015-07-16

  The present invention relates to a method for producing a polymer electrolyte molded article, which comprises forming a polymer electrolyte precursor having a protective group and an ionic group, and deprotecting at least a portion of protective groups contained in the resulting molded article to obtain a polymer electrolyte molded article. According to the present invention, it is possible to obtain a polymer electrolyte material and a polymer electrolyte molded article, which are excellent in proton conductivity and are also excellent in fuel barrier properties, mechanical strength, physical durability, resistance to hot water, resistance to hot methanol, processability and chemical stability. A polymer electrolyte fuel cell using a polymer electrolyte membrane, polymer electrolyte parts or a membrane electrode assembly can achieve high output, high energy density and long-term durability.

  本发明涉及一种制备聚合物电解质成型制品的方法，包括形成具有保护基和离子基的聚合物电解质前体，去除至少一部分所得成型制品中的保护基，以获得聚合物电解质成型制品。根据本发明，可以获得具有质子导电性优异、燃料阻隔性、机械强度、物理耐久性、耐热水性、耐热甲醇性、加工性和化学稳定性优异的聚合物电解质材料和聚合物电解质成型制品。使用聚合物电解质膜、聚合物电解质部件或膜电极组装的聚合物电解质燃料电池可以实现高输出、高能量密度和长期耐久性。
• SULFONIC ACID GROUP-CONTAINING POLYMER, SULFONIC ACID GROUP-CONTAINING AROMATIC COMPOUND AND METHOD OF MAKING THE SAME, AS WELL AS POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED PRODUCT AND SOLID POLYMER FUEL CELL USING THE SAME
  申请人：Chen Qiao

  公开号：US20150094446A1

  公开（公告）日：2015-04-02

  It is an object of the present invention to provide a sulfonic acid group-containing polymer and a sulfonic acid group-containing aromatic compound, which have excellent proton conductivity even under the low humidification condition, are excellent in mechanical strength and chemical stability and, moreover, can attain high output and excellent physical durability when processed into a solid polymer fuel cell, as well as a polymer electrolyte material, a polymer electrolyte molded product and a solid polymer fuel cell respectively using the same. The sulfonic acid group-containing polymer of the present invention is a sulfonic acid group-containing polymer comprising a constituent unit containing a sulfonic acid group (A1), and a constituent unit not containing a sulfonic acid group (A2), wherein the polymer contains a constituent unit having a specified structure as at least one constituent unit containing a sulfonic acid group (A1) at 25 mol % or more based on a sum of the constituent unit containing a sulfonic acid group (A1). Further, the polymer electrolyte material, polymer electrolyte molded product and solid polymer fuel cell of the present invention are constituted using such a sulfonic acid group-containing polymer.

  本发明的目的是提供一种含有磺酸基聚合物和含有磺酸基芳香化合物的物质，即使在低湿度条件下也具有优异的质子传导性能，具有良好的机械强度和化学稳定性，并且在加工成固态聚合物燃料电池时可以实现高输出和优异的物理耐久性，同时使用该物质制备聚合物电解质材料、聚合物电解质成型产品和固态聚合物燃料电池。本发明的磺酸基聚合物是一种含有磺酸基的聚合物，包括含有磺酸基的组分单元（A1）和不含磺酸基的组分单元（A2），其中该聚合物包含至少一种具有特定结构的组分单元作为含有磺酸基的组分单元（A1），其摩尔比例在含有磺酸基的组分单元（A1）的总和中占25摩尔％或更多。此外，本发明的聚合物电解质材料、聚合物电解质成型产品和固态聚合物燃料电池是使用这种磺酸基聚合物构成的。