H3[(3,5-Cl2C6H3NCH2CH2)3N] | 919480-03-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: H3[(3,5-Cl2C6H3NCH2CH2)3N]
• 英文别名: N',N'-bis[2-(3,5-dichloroanilino)ethyl]-N-(3,5-dichlorophenyl)ethane-1,2-diamine
• CAS: 919480-03-8
• 化学式: C₂₄H₂₄Cl₆N₄
• 分子量: 581.199
• InChiKey: GXNLRLQNRXRXKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  34
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  39.3
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  H3[(3,5-Cl2C6H3NCH2CH2)3N] 、 五氯化钽 在 (C₂H₅)3N 作用下， 以 二氯甲烷 为溶剂， 以70%的产率得到[(3,5-Cl2C6H3NCH2CH2)3N]TaCl2
  参考文献：
  名称：

  Synthesis of tantalum and niobium complexes that contain the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2−, and the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3−

  摘要：

  Several niobium and tantalum compounds were prepared that contain either the diamidoamine ligand, [(3,4,5-F3C6H2N-CH2CH2)(2)NMe](2-) ([F3N2NMe](2-)), or the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)(3)N](3-) ([Cl2NNMe](3-)). The former include [F3N2NMe]TaCl3, [F3N2NMe]NbCl3, [F3N2NMe]TaMe3, [F3N2NMe]NbMe3, [(F3N2NMe)TaMe2][MeB(C6F5)(3)], [F3N2NMe]Ta(CHSi-Me-3)(CH2SiMe3), [F3N2NMe]Ta(CH2-t-Bu)Cl-2, [F3N2NMe]Ta(CH-t-Bu)(CHA and [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3). The latter include [ClN2NMe]TaCl2, [Cl2N2NMe]TaMe2, [Cl2NNMe]Ta(eta(2)-C2H4), and [Cl2N2NMe]Ta(eta(2)-C2H2). X-ray diffraction studies were carried out on [F3N2NMe]Ta(CHSiMe3)(CH2SiMe3), [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3) and [Cl2N2NMe]TaMe2.. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.044

文献信息

• Synthesis of tantalum and niobium complexes that contain the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2−, and the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3−
  作者：Lourdes Pia H. Lopez、Richard R. Schrock、Peter J. Bonitatebus

  DOI：10.1016/j.ica.2006.03.044

  日期：2006.12

  Several niobium and tantalum compounds were prepared that contain either the diamidoamine ligand, [(3,4,5-F3C6H2N-CH2CH2)(2)NMe](2-) ([F3N2NMe](2-)), or the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)(3)N](3-) ([Cl2NNMe](3-)). The former include [F3N2NMe]TaCl3, [F3N2NMe]NbCl3, [F3N2NMe]TaMe3, [F3N2NMe]NbMe3, [(F3N2NMe)TaMe2][MeB(C6F5)(3)], [F3N2NMe]Ta(CHSi-Me-3)(CH2SiMe3), [F3N2NMe]Ta(CH2-t-Bu)Cl-2, [F3N2NMe]Ta(CH-t-Bu)(CHA and [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3). The latter include [ClN2NMe]TaCl2, [Cl2N2NMe]TaMe2, [Cl2NNMe]Ta(eta(2)-C2H4), and [Cl2N2NMe]Ta(eta(2)-C2H2). X-ray diffraction studies were carried out on [F3N2NMe]Ta(CHSiMe3)(CH2SiMe3), [F3N2NMe]Ta(eta(2)-C2H4)(CH2CH3) and [Cl2N2NMe]TaMe2.. (c) 2006 Elsevier B.V. All rights reserved.