2-phenyl-2-(phenylthio)ethyl acrylate | 1608154-14-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-phenyl-2-(phenylthio)ethyl acrylate
• 英文别名: (2-phenyl-2-phenylsulfanylethyl) prop-2-enoate
• CAS: 1608154-14-8
• 化学式: C₁₇H₁₆O₂S
• 分子量: 284.379
• InChiKey: ZIKFWDDKPLLCQV-UHFFFAOYSA-N

物化性质

• 沸点：
  428.1±45.0 °C(Predicted)
• 密度：
  1.15±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-phenyl-2-(phenylthio)ethanol 、 丙烯酰氯 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 10.0h， 以94%的产率得到2-phenyl-2-(phenylthio)ethyl acrylate
  参考文献：
  名称：

  [EN] SULPHUR CONTAINING HIGH REFRACTIVE INDEX MONOMER
  [FR] MONOMÈRE À INDICE DE RÉFRACTION ÉLEVÉ CONTENANT DU SOUFRE

  摘要：

  公开号：

  WO2014072995A3

文献信息

• COMPOSITION FOR DISPLAY SEALING MATERIAL, ORGANIC PROTECTION LAYER COMPRISING SAME, AND DISPLAY DEVICE COMPRISING SAME
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20170298164A1

  公开（公告）日：2017-10-19

  The present invention relates to a composition for a display sealing material having a photopolymerization initiator and a photocurable monomer, the photocurable monomer comprising: a monomer not having the aromatic hydrocarbon group; and a monomer having two or more substituted or unsubstituted phenyl groups of chemical formula 1, wherein about 5 wt % to about 45 wt % of the monomer having two or more substituted or unsubstituted phenyl groups is comprised on the basis of the photocurable monomer and about 55 wt % to about 95 wt % of the monomer not having the aromatic hydrocarbon group is comprised on the basis of the photocurable monomer.

  本发明涉及一种用于显示密封材料的组合物，其具有光聚合引发剂和光固化单体，所述光固化单体包括：不具有芳香族碳氢基团的单体；以及具有两个或更多取代或未取代苯基的化学式1的单体，其中以具有两个或更多取代或未取代苯基的单体为基础，包含约5重量％至约45重量％，以不具有芳香族碳氢基团的单体为基础，包含约55重量％至约95重量％。
• SULPHUR CONTAINING HIGH REFRACTIVE INDEX MONOMER
  申请人：COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

  公开号：US20150284324A1

  公开（公告）日：2015-10-08

  This invention discloses aromatic based sulfur containing hydrophobic acrylate monomer with high refractive index. The invention further discloses process for the preparation of 2-phenyl-2-(phenylthio)ethyl acrylate of the formula (I). This monomer can be polymerized to take the form of an optical products having high refractive index. Optical products made from this monomer having high refractive index can be thinner and provide same refractive power as product made from a material having a relatively low refractive index. In particular the polymeric material prepared from the novel monomer can be used for making intraocular lenses that are thinner than the conventionally used ones offering advantages of reduced volume of space and light weight materials.

  本发明揭示了一种具有高折射率的芳香基硫含量疏水丙烯酸酯单体。本发明还揭示了制备式(I)的2-苯基-2-(苯硫基)乙基丙烯酸酯的过程。该单体可以聚合成具有高折射率的光学产品。使用这种具有高折射率的单体制成的光学产品可以更薄，提供与使用折射率相对较低的材料制成的产品相同的折射功率。特别是，从新型单体制备的聚合材料可用于制造比传统使用的更薄的人工晶体眼内镜头，提供减少空间体积和轻质材料的优势。
• ACTINIC-RADIATION-CURABLE COMPOSITION AND LENS SHEET
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0735062A1

  公开（公告）日：1996-10-02

  An active energy ray-curable composition comprising (A) 20 to 80 parts by weight of a compound represented by the following general formula I: wherein R1 represents hydrogen or methyl, X and Y may be the same or different and represent methyl, chlorine, bromine or iodine, and t and u each independently represent an integer of 0-2, (B) 20 to 80 parts by weight of at least one compound having at least one acryloyl or methacryloyl group in the molecule, or (B-1) 10 to 90 parts by weight of at least one compound having at least two acryloyl or methacryloyl groups in the molecule and (B-2) 1 to 90 parts by weight of at least one monoacrylate or monomethacrylate compound having one acryloyl or methacryloyl group in the molecule, and (C) 0.01 to 5 parts by weight of an active energy ray-sensitive radical polymerization initiator with respect to 100 parts by weight of the total of components (A) and (B) or components (A), (B-1) and (B-2),    as well as a lens sheet comprising a lens section formed on at least one side of a transparent substrate using the composition.

  一种活性能量射线固化组合物，包括 (A) 20 至 80 份（按重量计）由以下通式 I 代表的化合物： 其中 R1 代表氢或甲基，X 和 Y 可以相同或不同，代表甲基、氯、溴或碘，t 和 u 各自独立地代表 0-2 的整数、 (B) 20 至 80 份（按重量计）分子中至少有一个丙烯酰基或甲基丙烯酰基的至少一种化合物，或 (B-1) 10 至 90 份（按重量计）分子中至少有两个丙烯酰基或甲基丙烯酰基的至少一种化合物，和 (B-2) 1 至 90 份（按重量计）分子中至少有一个丙烯酰基或甲基丙烯酰基的单丙烯酸酯或单甲基丙烯酸酯化合物，和 (C) 相对于 100 份（重量）组分（A）和（B）或组分（A）、（B-1）和（B-2）的总重量，0.01 至 5 份（重量）活性能射线敏感自由基聚合引发剂、 以及透镜片，该透镜片包括使用该组合物在透明基底的至少一面上形成的透镜部分。
• Composition for display sealing material, organic protection layer comprising same, and display device comprising same
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10316112B2

  公开（公告）日：2019-06-11

  A display sealing material composition includes a photopolymerization initiator and a photocuring monomer, the photocuring monomer comprising: a monomer not having the aromatic hydrocarbon group; and a monomer having two or more substituted or unsubstituted phenyl groups. An organic protection layer obtained by curing the composition for a display sealing material has approximately 400 nm/min or less plasma etching rate being represented by formula 1 below and approximately 2 nm or less surface roughness. Plasma etching rate(nm/min)=(T0−T1)/M,   wherein T0, T1, and M are set forth in the specification.

  一种显示密封材料组合物包括光聚合引发剂和光固化单体，光固化单体包括：不具有芳香烃基团的单体；具有两个或两个以上取代或未取代苯基的单体。通过固化用于显示器密封材料的组合物而获得的有机保护层，等离子刻蚀速率约为 400 nm/min 或更低，如下式 1 所示，表面粗糙度约为 2 nm 或更低。 等离子刻蚀速率（纳米/分钟）=（T0-T1）/M、 其中 T0、T1 和 M 见说明书。
• FLEXIBLE, HIGH REFRACTIVE INDEX HYDROPHOBIC COPOLYMER
  申请人：Council of Scientific & Industrial Research

  公开号：EP2941445A1

  公开（公告）日：2015-11-11