1-allyl-3-methylimidazolidin-2-one | 1215309-19-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 1-allyl-3-methylimidazolidin-2-one
• 英文别名: 1-Methyl-3-prop-2-enylimidazolidin-2-one
• CAS: 1215309-19-5
• 化学式: C₇H₁₂N₂O
• 分子量: 140.185
• InChiKey: GHRZHASGKBYVIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-甲基-2-咪唑啉酮 、 烯丙基醚 在 silver hexafluoroantimonate 、 氯[2-(二叔丁基磷)二苯基]金 作用下， 以 1,4-二氧六环 为溶剂， 反应 24.0h， 以98%的产率得到1-allyl-3-methylimidazolidin-2-one
  参考文献：
  名称：

  Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles

  摘要：

  A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF6 catalyzes the Intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regloselectivity and syn-stereoselectivity.

  DOI：

  10.1021/ol902923e

文献信息

• Organic polymers and novel polymerizable compound
  申请人：——

  公开号：US20030166808A1

  公开（公告）日：2003-09-04

  Organic polymers having water contact angles of 20° or smaller, preferably 7° or smaller and equipped with both high wettability and high transparency. The organic polymers may contain as partial structures polar structures of about 3 debyes or higher in dipole moment and are available especially from polymerization of polymerizable compounds having alkylene(thio)urea structures.

  具有20°或更小水接触角的有机聚合物，最好是7°或更小，并具有高润湿性和高透明度。这些有机聚合物可能包含大约3德拜或更高偶极矩的极性结构，特别是从具有烷基(硫)脲结构的可聚合化合物的聚合中获得。
• ORGANIC POLYMER AND NOVEL POLYMERIZABLE COMPOUND
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1361246A1

  公开（公告）日：2003-11-12

  Organic polymers having water contact angles of 20° or smaller, preferably 7° or smaller and equipped with both high wettability and high transparency. The organic polymers may contain as partial structures polar structures of about 3 debyes or higher in dipole moment and are available especially from polymerization of polymerizable compounds having alkylene(thio)urea structures.

  有机聚合物的水接触角为 20°或更小，最好为 7°或更小，并具有高润湿性和高透明性。有机聚合物的部分结构可包含偶极矩为 3 个或更高的极性结构，特别是通过具有亚烷基（硫）脲结构的可聚合化合物聚合而成。
• US6797805B2
  申请人：——

  公开号：US6797805B2

  公开（公告）日：2004-09-28
• Gold(I)-Catalyzed Amination of Allylic Alcohols with Cyclic Ureas and Related Nucleophiles
  作者：Paramita Mukherjee、Ross A. Widenhoefer

  DOI：10.1021/ol902923e

  日期：2010.3.19

  A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF6 catalyzes the Intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regloselectivity and syn-stereoselectivity.