Provided are Chemical Mechanical Planarization (CMP) formulations that offer high and tunable Cu removal rates and low copper dishing for the broad or advanced node copper or Through Silica Via (TSV). The CMP compositions provide high selectivity of Cu film vs. other barrier layers, such as Ta, TaN, Ti, and TiN, and dielectric films, such as TEOS, low-k, and ultra low-k films. The CMP polishing formulations comprise water; abrasive; single chelator, dual chelators or tris chelators; morpholino family compounds as Cu dishing reducing agents. Additionally, organic quaternary ammonium salt, corrosion inhibitor, oxidizer, pH adjustor and biocide can be used in the formulations.
所提供的
化学机械平坦化(
CMP)配方可为宽节点或先进节点
铜或
硅通孔(
TSV)提供高且可调的
铜去除率和低
铜偏移。与其他阻挡层(如
钽、
钽镍、
钛和
钛镍)和介电薄膜(如 TEOS、低 K 和超低 K 薄膜)相比,
CMP 组合物具有较高的
铜膜选择性。
CMP 抛光配方包括
水;研磨剂;单
螯合剂、双
螯合剂或三
螯合剂;作为
铜排减剂的吗啉族化合物。此外,配方中还可使用有机季
铵盐、缓蚀剂、氧化剂、pH 值调节剂和杀菌剂。