phenyl di(but-3-en-1-yl) phosphate | 6612-66-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl di(but-3-en-1-yl) phosphate
• 英文别名: di(3-buten-1-yl) phenyl phosphate；Bis--phenyl-phosphat；Bis-buten-3-yl-phenyl-phosphat；Phosphoric acid, di(3-butenyl) phenyl ester；bis(but-3-enyl) phenyl phosphate
• CAS: 6612-66-4
• 化学式: C₁₄H₁₉O₄P
• 分子量: 282.276
• InChiKey: JMGQLNXBPAMTPR-UHFFFAOYSA-N

物化性质

• 沸点：
  331.2±35.0 °C(Predicted)
• 密度：
  1.102±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  二氯磷酸苯酯 在 吡啶 作用下， 以 乙醚 为溶剂， 生成 phenyl di(but-3-en-1-yl) phosphate
  参考文献：
  名称：

  二环丙基碳酰氯磷酸酯的制备及其在磷酸化反应中的应用

  摘要：

  已经合成了用于磷酸化反应的二环丙基羰基磷酰氯。该试剂和伯或仲醇产生相应的酯。它与核苷的伯羟基和仲羟基官能团反应形成核苷酸三酯。用酸水溶液将磷酸二环丙基羰基甲基酯水解为磷酸单薄荷酯。核苷酸三酯产生的游离核苷酸的量反映了它们在酸中的不稳定性，因此，从2'，3'-异亚丙基-尿苷中产生的尿苷5'磷酸盐的总产率为53％，而在12中仅获得了胸苷3'的磷酸盐。 ％来自5′-O-三苯甲基胸苷。

  DOI：

  10.1016/0040-4020(66)80003-0

文献信息

• Long-term stable photoactive composition, such as phosphorescent composition or TTA-photon upconversion composition
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP2851407A1

  公开（公告）日：2015-03-25

  A long-term stable photoactive composition, such as a phosphorescent composition or a TTA-photon upconversion composition, contains at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, and at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond, and wherein the at least one compound capable of reacting with singlet oxygen is contained in the composition in such an amount that the number of terminal unsaturated carbon-carbon bonds is at least 100 times higher in the composition than the number of molecules of all compounds having a triplet state capable of energy transfer via an emissive process or a non-emissive process.

  一种长期稳定的光活性组合物，如磷光组合物或 TTA 光子上转换组合物，包含至少一种化合物，该化合物具有能够通过发射过程或非发射过程进行能量转移的三重态，以及至少一种能够与单线态氧反应的化合物，其中至少一种能够与单线态氧反应的化合物包含至少一个末端不饱和碳-碳键、其中至少一种能与单线态氧反应的化合物在组合物中的含量，使组合物中末端不饱和碳-碳键的数量比所有具有能通过发射过程或非发射过程进行能量转移的三重态的化合物分子数量至少高 100 倍。
• <b>Conformation of Organophosphorus Compounds. II. Proton Magnetic Resonance Studies of Some Phosphites, Phosphonites, Phosphates, Phosphonates and Additional Phosphinates</b>
  作者：T. H. Siddall、C. A. Prohaska

  DOI：10.1021/ja00877a010

  日期：1962.9
• Unsaturated Polyphosphoesters via Acyclic Diene Metathesis Polymerization
  作者：Filippo Marsico、Manfred Wagner、Katharina Landfester、Frederik R. Wurm

  DOI：10.1021/ma301508s

  日期：2012.11.13

  A powerful methodology for the synthesis of unsaturated polyphosphoesters (UPPEs) relying on acyclic diene metathesis (ADMET) polymerization is described. A facile two-step protocol gives fast access to structurally versatile and potentially degradable and biocompatible materials. For the first time this allows to control the microstructure of either backbone and/or side chains of polyphosphoesters. Four different, monomers are polymerized under different conditions to yield UPPEs with molecular weights ranging from 7000 up to 50 000 g.mol(-1) with reasonable polydispersity. The unsaturated and saturated polyphosphoesters are characterized in detail with various techniques. A major benefit of the UPPEs is revealed by differential scanning calorimetry proving the control over thermal properties with tunable melting or glass transition temperatures for the different saturated and unsaturated PPEs which is an important feature for future applications. This unique combination of the benefits of metathesis polymerization and phosphorus chemistry is a highly versatile system for materials in many applications ranging from adhesives to biomaterials.
• LONG-TERM STABLE PHOTOACTIVE COMPOSITION, SUCH AS PHOSPHORESCENT COMPOSITION OR TTA-PHOTON UPCONVERSION COMPOSITION
  申请人：Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

  公开号：EP3049502B1

  公开（公告）日：2020-04-01
• [EN] LONG-TERM STABLE PHOTOACTIVE COMPOSITION, SUCH AS PHOSPHORESCENT COMPOSITION OR TTA-PHOTON UPCONVERSION COMPOSITION<br/>[FR] COMPOSITION PHOTOACTIVE STABLE À LONG-TERME, TELLE QU'UNE COMPOSITION PHOSPHORESCENTE OU UNE COMPOSITION DE CONVERSION ASCENDANTE DE PHOTONS PAR TTA
  申请人：MAX PLANCK GES ZUR FÖRDERUNG DER WISSENSCHAFTEN E V

  公开号：WO2015044129A1

  公开（公告）日：2015-04-02

  A long-term stable photoactive composition, namely a phosphorescent composition or a TTA-photon upconversion composition, contains: a) at least one compound, which has a triplet state capable of energy transfer via an emissive process or a non-emissive process, wherein the at least one compound having a triplet state is i) at least one phosphorescent compound and/ or ii) at least one sensitizer compound being capable of absorbing radiation at a first frequency v1and at least one emissive compound, wherein the at least one sensitizer compound is capable of transferring energy to the at least one emissive compound and wherein the at least one emissive compound, after obtaining energy transferred from the at least one sensitizer compound, is capable of emitting light at a second frequency v2, wherein the following equation is fulfilled: v2>v1, wherein the at least one sensitizer compound is capable of a triplet-triplet energy transfer to the at least one emissive compound and wherein the at least one emissive compound is preferably capable of a triplet-triplet annihilation, and b) at least one compound capable of reacting with singlet oxygen, wherein the at least one compound capable of reacting with singlet oxygen comprises at least one terminal unsaturated carbon-carbon bond and is selected from the group consisting of compounds having anyone of the general formulae (I) to (X).