DC-S347 | 181209-10-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: DC-S347
• 英文别名: 4-nitro-N'-[(E)-1H-pyrrol-2-ylmethylidene]benzohydrazide；4-nitro-N-(1H-pyrrol-2-ylmethylideneamino)benzamide
• CAS: 181209-10-9
• 化学式: C₁₂H₁₀N₄O₃
• mdl: MFCD00560562
• 分子量: 258.236
• InChiKey: POSRUYVVJMOFRO-UHFFFAOYSA-N

物化性质

• 密度：
  1.39±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  103
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  DC-S347 、 cadmium(II) chloride 以 乙醇 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Bivalent Metal Complexes of Pyrrole-2-Carboxaldehyde Aroylhydrazones

  摘要：

  The complexes of Co(II), Ni(II), Cu(II), Pd(II), Cd(II) and Zn(II) with hydrazones derived from benzoic, (p) under bar-methylbenzoic or (p) under bar-nitrobenzoic acid hydrazides and pyrrole-2-carboxaldehyde have been synthesized. The complexes have been characterized by elemental analyses, molar conductance, spectral (IR and visible) and magnetic studies. All the complexes are non-electrolytes. The IR spectral data show that the ligands act as neutral or monoanionic bidentates or as monoanionic tridentates. Spectral and magnetic studies suggest octahedral structures for all Co(II) and NI(II) complexes, square-planar structures for [Cu(PBH)(2)], [Cu(PMBH)(2)].H2O and all Pd(II) complexes and a tetragonally distorted octahedral structure for [Cu(PNBH)(2)].

  DOI：

  10.1080/00945719608004355

文献信息

• Synthesis and Characterization of Bivalent Metal Complexes of Pyrrole-2-Carboxaldehyde Aroylhydrazones
  作者：T. H. Rakha、K. M. Ibrahim、A. M. Abdallah、M. M. Hassanian

  DOI：10.1080/00945719608004355

  日期：1996.8

  The complexes of Co(II), Ni(II), Cu(II), Pd(II), Cd(II) and Zn(II) with hydrazones derived from benzoic, (p) under bar-methylbenzoic or (p) under bar-nitrobenzoic acid hydrazides and pyrrole-2-carboxaldehyde have been synthesized. The complexes have been characterized by elemental analyses, molar conductance, spectral (IR and visible) and magnetic studies. All the complexes are non-electrolytes. The IR spectral data show that the ligands act as neutral or monoanionic bidentates or as monoanionic tridentates. Spectral and magnetic studies suggest octahedral structures for all Co(II) and NI(II) complexes, square-planar structures for [Cu(PBH)(2)], [Cu(PMBH)(2)].H2O and all Pd(II) complexes and a tetragonally distorted octahedral structure for [Cu(PNBH)(2)].