2,3,4-Trichlorophenyl prop-2-enoate | 89670-65-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 2,3,4-Trichlorophenyl prop-2-enoate
• 英文别名: (2,3,4-trichlorophenyl) prop-2-enoate
• CAS: 89670-65-5
• 化学式: C₉H₅Cl₃O₂
• 分子量: 251.5
• InChiKey: JLOIRPJHPDQHHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Resin cross-linking
  申请人：Lovell Peter A.

  公开号：US20100010266A1

  公开（公告）日：2010-01-14

  A method of effecting cross-linking of a resin comprises generating vinyl sulfonyl moieties in situ with the resin, said sulfonyl moieties then undergoing a reaction which effects cross-linking of the resin. The vinyl sulfonyl moieties may be generated as a result of a loss of a liquid carrier for the resin to be cross-linked. The cross-linking reaction may result from reaction of the vinyl sulfonyl moieties with nucleophilic groups in the resin composition. The resin may be a co-polymer of a compound of formula (IV) with other olefinically unsaturated monomers.

  一种实现树脂交联的方法包括在树脂中原位生成乙烯磺酰基团，然后这些磺酰基团经历一种反应，从而实现树脂的交联。乙烯磺酰基团可能是由于树脂交联所需的液体载体的流失而生成的。交联反应可能是由乙烯磺酰基团与树脂组成中的亲核基团发生反应而导致的。树脂可以是化合物（IV）的共聚物与其他烯烃不饱和单体的共聚物。
• The use of a particulate polymer as a carrier for biological substances and the like and such substances supported on the carrier
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0095932A1

  公开（公告）日：1983-12-07

  A carrier particularly suitable for supporting biological substances is composed of a particulate polymer prepared by polymerizing at least one monomer of formula: (in which R1 and R2 are the same or different and each represents a hydrogen atom or an alkyl group, R3 represents a straight or branched chain alkylene group optionally having a hydroxy substituent, X represents a halogen atom, m is 0 or an integer from 1 to 10 and n is an integer from 1 to 5) optionally in admixture with at least one other copolymerizable monomer. Biological substances which may be supported by the carrier include immunoreactive substances, enzymes, cells and cell-discriminating substances.

  一种特别适用于支持生物物质的载体由至少一种式单体聚合制备的微粒聚合物组成： (其中 R1 和 R2 相同或不同，各自代表氢原子或烷基，R3 代表直链或支链亚烷基，可选择具有羟基取代基，X 代表卤素原子，m 为 0 或 1-10 的整数，n 为 1-5 的整数），可选择与至少一种其它可共聚单体混合。载体可支持的生物物质包括免疫活性物质、酶、细胞和细胞鉴别物质。
• Resin material for plastic lens and lens composed thereof
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0134861A1

  公开（公告）日：1985-03-27

  A polymer having a high refractive index is obtained by polymerizing a urethanized acrylic or methacrylic monomer obtained by reacting the hydroxyl group of an acrylic or methacrylic monomer having a nucleus-halogen-substituted aromatic ring and a hydroxyl group with the isocyanate group of a polyfunctional isocyanate. This polymer is valuable as a resin material for a plastic lens.

  一种具有高折射率的聚合物是通过聚合尿烷化丙烯酸或甲基丙烯酸单体而获得的，这种单体是由具有核-卤代芳香环和羟基的丙烯酸或甲基丙烯酸单体的羟基与多官能异氰酸酯的异氰酸酯基反应而获得的。这种聚合物可作为塑料镜片的树脂材料。
• Resin having high refractive index, process for producing said resin and optical materials composed of said resin
  申请人：Nippon Shokubai Kagaku Kogyo Co., Ltd

  公开号：EP0273710A2

  公开（公告）日：1988-07-06

  A process for producing a resin ahving a high refractive index which comprises radically polymerizing a material monomer, characterized in that said material monomer comprises [I] at least one polymerizable monomer selected from the group consisting of a polyfunctional thioacrylate and a polyfunctional thiomethacrylate (as an indispensable component), and optionally [II] at least one other polymerizable monomer which is radically polymeriz­able with said polymerizable monomer [I], a resin having a high refractive index produced by said process and optical materials, especially lenses and disk substrates prepared from said resin.

  一种生产高折射率树脂的工艺，包括对材料单体进行辐射聚合，其特征在于所述材料单体包括 [I] 至少一种可聚合单体，该单体选自由多官能团硫代丙烯酸酯和多官能团硫代甲基丙烯酸酯（作为不可或缺的组分）组成的组、以及[II]至少一种可与所述可聚合单体[I]进行辐射聚合的其他可聚合单体，通过所述工艺生产的具有高折射率的树脂，以及用所述树脂制备的光学材料，尤其是透镜和盘片基板。
• Transparent resin and transparent resin products
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0320954A2

  公开（公告）日：1989-06-21

  A transparent resin is obtained by polymerizing a feed starting material containing at least one monomer represented by the formula (I) wherein R₁- represents -CH=CH₂, CH₂-CH=CH₂, -COOC(CH₃)=CH₂, -COOCH₂-CH=CH₂,-OCOO-CH₂-CH=CH₂, -OCOO-CH₂-C(CH₃)=CH₂, -OCOCH=CH₂ or -OCOC(CH₃)=CH₂, R₂- represents -H, -OCH₃, -SCH₃, -CH₃, -C₂H₅ or -CH=CH₂, and A₁ and A₂ each represent O or S. A transparent optical article is constituted of the transparent resin obtained by polymerizing the monomer of the formula (I). A paint composition comprises the transparent resin obtained by polymerizing the monomer of the formula (I).

  一种透明树脂是通过聚合含有至少一种由式 (I) 表示的单体的原料起始材料而获得的 其中 R₁- 代表-CH=CH₂、CH₂-CH=CH₂、-COOC(CH₃)=CH₂、-COOCH₂-CH=CH₂、-OCOO-CH₂-CH=CH₂、-OCOO-CH₂-C(CH₃)=CH₂、-OCOCH=CH₂或-OCOC(CH₃)=CH₂，R₂-代表-H、-OCH₃、-SCH₃、-CH₃、-C₂H₅或-CH=CH₂，A₁和A₂各自代表O或S。透明光学制品由通过聚合式 (I) 单体得到的透明树脂构成。涂料组合物由通过聚合式（I）单体得到的透明树脂构成。