(6-hydroxynaphthalen-2-yl)triphenylphosphonium bromide | 844468-44-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (6-hydroxynaphthalen-2-yl)triphenylphosphonium bromide
• 英文别名: (6-Hydroxynaphthalen-2-yl)(triphenyl)phosphanium bromide；(6-hydroxynaphthalen-2-yl)-triphenylphosphanium;bromide
• CAS: 844468-44-6
• 化学式: Br*C₂₈H₂₂OP
• 分子量: 485.36
• InChiKey: QMSZFRBVGISFKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.17
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (6-hydroxynaphthalen-2-yl)triphenylphosphonium bromide 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以99%的产率得到6-(triphenylphosphonio)naphthalen-2-olate
  参考文献：
  名称：

  Tetraarylphosphonium inner-salts (TAPIS) as both Lewis base catalyst and phase tag

  摘要：

  Tetraarylphosphonium inner-salts (TAPIS) have been designed, synthesized and verified as recyclable and reusable Lewis base catalysts. The resulted TAPIS catalyst has been successfully applied in Michael addition, cyanation and trifluoromethylation reactions. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2017.06.015
• 作为产物：
  描述：

  6-溴-2-萘酚 、 三苯基膦 在 nickel(II) chloride hexahydrate 作用下， 以 1,2-丙二醇 为溶剂， 反应 8.0h， 以79%的产率得到(6-hydroxynaphthalen-2-yl)triphenylphosphonium bromide
  参考文献：
  名称：

  Tetraarylphosphonium inner-salts (TAPIS) as both Lewis base catalyst and phase tag

  摘要：

  Tetraarylphosphonium inner-salts (TAPIS) have been designed, synthesized and verified as recyclable and reusable Lewis base catalysts. The resulted TAPIS catalyst has been successfully applied in Michael addition, cyanation and trifluoromethylation reactions. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2017.06.015

文献信息

• LATENT CATALYST FOR EPOXY RESIN, EPOXY RESIN COMPOSITION, AND SEMICONDUCTOR DEVICE
  申请人：Horimoto Akihiro

  公开号：US20090023840A1

  公开（公告）日：2009-01-22

  The present invention provides a latent catalyst for epoxy resin, comprising: a cation moiety having an activity of accelerating curing reaction of epoxy resin; and a silicate anion moiety of suppressing the curing reaction-accelerating activity. Also disclosed are an epoxy resin composition comprising the latent catalyst and a semiconductor device using the epoxy resin composition.

  本发明提供了一种环氧树脂的潜在催化剂，包括：具有加速环氧树脂固化反应活性的阳离子基团；以及抑制固化反应加速活性的硅酸盐阴离子基团。还公开了一种包含潜在催化剂的环氧树脂组合物以及使用该环氧树脂组合物的半导体器件。
• Latent catalyst for epoxy resin, epoxy resin composition, and semiconductor device
  申请人：Horimoto Akihiro

  公开号：US20050075474A1

  公开（公告）日：2005-04-07

  The present invention provides a latent catalyst for epoxy resin, comprising: a cation moiety having an activity of accelerating curing reaction of epoxy resin; and a silicate anion moiety of suppressing the curing reaction-accelerating activity. Also disclosed are an epoxy resin composition comprising the latent catalyst and a semiconductor device using the epoxy resin composition.

  本发明提供了一种环氧树脂的潜在催化剂，包括：具有加速环氧树脂固化反应活性的阳离子基团；以及抑制固化反应加速活性的硅酸盐阴离子基团。此外，还公开了一种包含潜在催化剂的环氧树脂组合物和使用该环氧树脂组合物的半导体器件。
• US8148831B2
  申请人：——

  公开号：US8148831B2

  公开（公告）日：2012-04-03
• Tetraarylphosphonium inner-salts (TAPIS) as both Lewis base catalyst and phase tag
  作者：Shuhui Guo、Xueling Mi

  DOI：10.1016/j.tetlet.2017.06.015

  日期：2017.7

  Tetraarylphosphonium inner-salts (TAPIS) have been designed, synthesized and verified as recyclable and reusable Lewis base catalysts. The resulted TAPIS catalyst has been successfully applied in Michael addition, cyanation and trifluoromethylation reactions. (C) 2017 Elsevier Ltd. All rights reserved.