2,3,4-Trichlorophenyl 2-methylprop-2-enoate | 83172-44-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 2,3,4-Trichlorophenyl 2-methylprop-2-enoate
• 英文别名: (2,3,4-trichlorophenyl) 2-methylprop-2-enoate
• CAS: 83172-44-5
• 化学式: C₁₀H₇Cl₃O₂
• 分子量: 265.5
• InChiKey: IGWMFERXHIUPRD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Resin material for plastic lens and lens composed thereof
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0134861A1

  公开（公告）日：1985-03-27

  A polymer having a high refractive index is obtained by polymerizing a urethanized acrylic or methacrylic monomer obtained by reacting the hydroxyl group of an acrylic or methacrylic monomer having a nucleus-halogen-substituted aromatic ring and a hydroxyl group with the isocyanate group of a polyfunctional isocyanate. This polymer is valuable as a resin material for a plastic lens.

  一种具有高折射率的聚合物是通过聚合尿烷化丙烯酸或甲基丙烯酸单体而获得的，这种单体是由具有核-卤代芳香环和羟基的丙烯酸或甲基丙烯酸单体的羟基与多官能异氰酸酯的异氰酸酯基反应而获得的。这种聚合物可作为塑料镜片的树脂材料。
• Resin having high refractive index, process for producing said resin and optical materials composed of said resin
  申请人：Nippon Shokubai Kagaku Kogyo Co., Ltd

  公开号：EP0273710A2

  公开（公告）日：1988-07-06

  A process for producing a resin ahving a high refractive index which comprises radically polymerizing a material monomer, characterized in that said material monomer comprises [I] at least one polymerizable monomer selected from the group consisting of a polyfunctional thioacrylate and a polyfunctional thiomethacrylate (as an indispensable component), and optionally [II] at least one other polymerizable monomer which is radically polymeriz­able with said polymerizable monomer [I], a resin having a high refractive index produced by said process and optical materials, especially lenses and disk substrates prepared from said resin.

  一种生产高折射率树脂的工艺，包括对材料单体进行辐射聚合，其特征在于所述材料单体包括 [I] 至少一种可聚合单体，该单体选自由多官能团硫代丙烯酸酯和多官能团硫代甲基丙烯酸酯（作为不可或缺的组分）组成的组、以及[II]至少一种可与所述可聚合单体[I]进行辐射聚合的其他可聚合单体，通过所述工艺生产的具有高折射率的树脂，以及用所述树脂制备的光学材料，尤其是透镜和盘片基板。
• Transparent resin and transparent resin products
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0320954A2

  公开（公告）日：1989-06-21

  A transparent resin is obtained by polymerizing a feed starting material containing at least one monomer represented by the formula (I) wherein R₁- represents -CH=CH₂, CH₂-CH=CH₂, -COOC(CH₃)=CH₂, -COOCH₂-CH=CH₂,-OCOO-CH₂-CH=CH₂, -OCOO-CH₂-C(CH₃)=CH₂, -OCOCH=CH₂ or -OCOC(CH₃)=CH₂, R₂- represents -H, -OCH₃, -SCH₃, -CH₃, -C₂H₅ or -CH=CH₂, and A₁ and A₂ each represent O or S. A transparent optical article is constituted of the transparent resin obtained by polymerizing the monomer of the formula (I). A paint composition comprises the transparent resin obtained by polymerizing the monomer of the formula (I).

  一种透明树脂是通过聚合含有至少一种由式 (I) 表示的单体的原料起始材料而获得的 其中 R₁- 代表-CH=CH₂、CH₂-CH=CH₂、-COOC(CH₃)=CH₂、-COOCH₂-CH=CH₂、-OCOO-CH₂-CH=CH₂、-OCOO-CH₂-C(CH₃)=CH₂、-OCOCH=CH₂或-OCOC(CH₃)=CH₂，R₂-代表-H、-OCH₃、-SCH₃、-CH₃、-C₂H₅或-CH=CH₂，A₁和A₂各自代表O或S。透明光学制品由通过聚合式 (I) 单体得到的透明树脂构成。涂料组合物由通过聚合式（I）单体得到的透明树脂构成。
• Process for producing vinyl polymer or vinylidene polymer
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0454462A1

  公开（公告）日：1991-10-30

  An improved process for producing a vinyl or vinylidene polymer comprising polymerizing a monomer having a vinyl or vinylidene group in the presence of (a) a radical polymerization initiator, (b) an organic phosphorus compound of the formula: wherein R¹, R² and R³ are independently hydrogen atom, chlorine atom, bromine atom, an alkyl, an aralkyl, or an aryl, (c) an amine hydrohalide or a quaternary ammonium halide, and (d) a copper-containing compound, which can be carried out rapidly and can give the vinyl or vinylidene polymer having excellent mechanical strength without coloring.

  一种生产乙烯基或亚乙烯基聚合物的改进工艺，包括在以下条件下聚合具有乙烯基或亚乙烯基的单体 (a) 自由基聚合引发剂、 (b) 式中的有机磷化合物： 其中 R¹、R² 和 R³ 独立地为氢原子、氯原子、溴原子、烷基、芳烷基或芳基、 (c) 胺氢卤化物或季铵卤化物，以及 (d) 一种含铜化合物，该工艺可快速进行，并可得到具有优异机械强度的乙烯基或亚乙烯基聚合物，且不会着色。
• Holographic recording medium
  申请人：Kabushiki Kaisha Toshiba

  公开号：EP1939686A1

  公开（公告）日：2008-07-02

  A holographic recording medium (12) is provided, which includes a recording layer (19) comprising a three-dimensional cross-linking polymer matrix, a radical polymeric compound, and a photo-radical polymerization initiator. The three-dimensional cross-linking polymer matrix is represented by the following general formula (1): where m is an integer ranging from 3 to 16.

  提供了一种全息记录介质（12），它包括一个记录层（19），记录层由三维交联聚合物基体、自由基聚合物化合物和光致发光聚合引发剂组成。三维交联聚合物基质由以下通式（1）表示： 其中 m 为 3 至 16 的整数。