申请人:SHELL INTERNATIONALE RESEARCH
MAATSCHAPPIJ B.V.
公开号:EP0168876A2
公开(公告)日:1986-01-22
A process for the preparation of carboxylic acid esters of hydroxy sulfonates, characterized in that an olefinically unsaturated compound is carbonylated with carbon monoxide in the presence of an aromatic hydrocarbon reaction medium, a hydroxy sulfonate of the general formula (I) HO-R-SO3M, wherein R represents a divalent optionally substituted hydrocarbon group and M represents a metal of Group I and II of the Periodic Table of the Elements, a palladium catalyst, at least 5 mol of a phosphine of the general formula (II) PRIR2R3, wherein R1, R2 and R3 each represent an optionally substituted aryl group, per gram atom of palladium and as promotor an acid having a pKa < 2 except hydrohalogenic and carboxylic acids.
一种制备羟基磺酸盐羧酸酯的工艺,其特征在于在芳香烃反应介质、通式(Ⅰ)HO-R-SO3M的羟基磺酸盐(其中R代表二价任选取代的烃基,M代表元素周期表Ⅰ族和Ⅱ族金属)、钯催化剂、每克钯原子至少5摩尔通式(Ⅱ)PRIR2R3(其中R1、R2和R3各自代表任选取代的芳基)的膦、以及作为促进剂的pKa<2的酸的存在下,烯烃不饱和化合物被一氧化碳羰基化,但氢卤酸和羧酸除外。