nitrosyl hypofluorite | 96607-23-7

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 非金属氧阴离子化合物
• 英文名称: nitrosyl hypofluorite
• 英文别名: Fono；fluoro nitrite
• CAS: 96607-23-7
• 化学式: FNO₂
• 分子量: 65.0039
• InChiKey: KIKPURRCWNPDFV-UHFFFAOYSA-N

物化性质

• 密度：
  1.51±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  nitrosyl hypofluorite 、 镍 生成 nickel(II) oxide 、 nickel(II) fluoride
  参考文献：
  名称：

  硝酰氟的制备及一些反应

  摘要：

  DOI：

  10.1039/jr9540001119
• 作为产物：
  描述：

  二氧化氮 、 氢氟酸 以 gaseous matrix 为溶剂， 生成 硝酰氟 、 nitrosyl hypofluorite
  参考文献：
  名称：

  Real‐time kinetic study of the reaction F+NO₂

  摘要：

  The title reaction was studied in real time by observing infrared fluorescence resulting from the competitive reaction F+H2. With N2 as a collision partner, the limiting rate constants were found to be k0=9.8±1.6×10−31 cm6 molecule−2 s−1 and k∞=3.2±0.8×10−11 cm3 molecule−1 s−1, as determined by fitting the experimental data to Kassel, and modified Lindemann–Hinshelwood models. Measurments with argon showed it to be slightly less effective as stabilizing the reaction complex. Calculations indicate that both FNO2 and FONO are formed in the reaction, with a product ratio of FONO/FNO2≊7.

  DOI：

  10.1063/1.444668

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.AII2, 12, page 879 - 934
  作者：

  DOI：——

  日期：——
• The preparation and some reactions of nitryl fluoride
  作者：E. E. Aynsley、G. Hetherington、P. L. Robinson

  DOI：10.1039/jr9540001119

  日期：——
• Real‐time kinetic study of the reaction F+NO₂
  作者：D. M. Fasano、N. S. Nogar

  DOI：10.1063/1.444668

  日期：1983.6

  The title reaction was studied in real time by observing infrared fluorescence resulting from the competitive reaction F+H2. With N2 as a collision partner, the limiting rate constants were found to be k0=9.8±1.6×10−31 cm6 molecule−2 s−1 and k∞=3.2±0.8×10−11 cm3 molecule−1 s−1, as determined by fitting the experimental data to Kassel, and modified Lindemann–Hinshelwood models. Measurments with argon showed it to be slightly less effective as stabilizing the reaction complex. Calculations indicate that both FNO2 and FONO are formed in the reaction, with a product ratio of FONO/FNO2≊7.