METHOD FOR PREPARING CONJUGATED DIENE-BASED POLYMER, COMPOSITION CONTAINING POLYMER, AND TIRE COMPRISING COMPOSITION
申请人:LG Chem, Ltd.
公开号:EP2826793A1
公开(公告)日:2015-01-21
Disclosed are a method for preparing a conjugated diene polymer including synthesizing an initiator having an anionic end containing an amine and a cationic end containing an alkali metal, polymerizing a combination of an aromatic vinyl monomer using the initiator to synthesize a polymer having a modified end, coupling or reacting the polymer with a compound having at least one silyl group substituted by an alkoxy group and a nitrogen atom to prepare a modified conjugated diene polymer having one end containing amine and the other end containing silyl group substituted by one or more alkoxy group and a nitrogen atom, and a rubber composition comprising the conjugated diene polymer and silica as a reinforcing agent and thus exhibiting superior heat generation, tensile strength, abrasion resistance and wet skid resistance.
本发明公开了一种制备共轭二烯聚合物的方法,包括合成一种具有含胺阴离子端和含碱金属阳离子端的引发剂,使用该引发剂聚合芳香族乙烯基单体的组合,合成一种具有改性端聚合物、将聚合物与具有至少一个被烷氧基和氮原子取代的硅烷基的化合物偶联或反应,制备出一端含有胺、另一端含有被一个或多个烷氧基和氮原子取代的硅烷基的改性共轭二烯聚合物,以及由共轭二烯聚合物和作为补强剂的白炭黑组成的橡胶组合物,从而表现出优异的发热性、拉伸强度、耐磨性和防滑性。