3,3',3''-[Benzene-1,3,5-triyltris(oxy)]trianiline | 143966-27-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3',3''-[Benzene-1,3,5-triyltris(oxy)]trianiline
• 英文别名: 3-[3,5-bis(3-aminophenoxy)phenoxy]aniline
• CAS: 143966-27-2
• 化学式: C₂₄H₂₁N₃O₃
• 分子量: 399.4
• InChiKey: JHYZHLNKNMVBSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106
• 氢给体数：
  3
• 氢受体数：
  6

文献信息

• Process for preparing polycondensation polymers
  申请人：MITSUI TOATSU CHEMICALS, INC.

  公开号：EP0769512A2

  公开（公告）日：1997-04-23

  The invention provides a novel preparation process of a polycondensation type polymer, an excellent polymer which is represented by lactic acid and the preparation process of the polymer, a polycondensation agent used for the preparation process, and an intermediate. Specifically, the invention provides a preparation process of the polycondensation type polymer, for example, polyamide, polyimide, polythioester and polyester, comprising bonding a carboxyl group comprising compound with an active hydrogen group comprising compound in the presence of haloiminium salt. The invention provides excellent polylactic acid having a controlled D/L-isomer ratio in the repeating structural units and preparation process of polylactic acid, and further provides a haloiminium salt compound used for the preparation process and an intermediate compound of acid chloride.

  本发明提供了一种新型缩聚型聚合物的制备工艺、一种以乳酸为代表的优良聚合物及其制备工艺、一种用于制备工艺的缩聚剂和一种中间体。具体而言，本发明提供了一种缩聚型聚合物（例如聚酰胺、聚酰亚胺、聚硫酯和聚酯）的制备工艺，包括在卤化亚胺盐存在下，将包含羧基的化合物与包含活性氢基的化合物键合。本发明提供了在聚乳酸的重复结构单元和制备工艺中具有可控 D/L 异构体比率的优良聚乳酸，并进一步提供了用于制备工艺的卤化亚胺盐化合物和氯化酸的中间化合物。
• MULTIBRANCHED POLYIMIDE HYBRID MATERIAL
  申请人：NATIONAL UNIVERSITY CORPORATION NAGOYA INSTITUTE OF TECHNOLOGY

  公开号：EP1792928A1

  公开（公告）日：2007-06-06

  It is an object of the present invention to provide a polyimide-based hybrid material which is industrially and advantageously utilized because of having better gas permeability, electric characteristics, heat resistance, mechanical strength, and the like as compared with the conventional polyimide-based hybrid materials, while keeping chemical resistance, forming characteristics (process characteristics), and the like inherently possessed by polyimide. Provided is a hyperbranched polyimide-based hybrid material constituted of an organic-inorganic polymer hybrid, wherein the organic-inorganic polymer hybrid has a hyperbranched polyimide moiety and an inorganic oxide moiety which are combining each other via covalent bond and constituting a composite structure.

  本发明的目的是提供一种聚酰亚胺基杂化材料，与传统的聚酰亚胺基杂化材料相比，该材料具有更好的气体渗透性、电特性、耐热性、机械强度等，同时保持了聚酰亚胺固有的耐化学性、成型特性（工艺特性）等，因此可在工业上得到有利利用。本发明提供了一种由有机-无机聚合物杂化物构成的超支化聚酰亚胺基杂化物材料，其中有机-无机聚合物杂化物具有超支化聚酰亚胺分子和无机氧化物分子，它们通过共价键相互结合并构成复合结构。
• GAS SEPARATION MEMBRANE
  申请人：Ibiden Co., Ltd.

  公开号：EP2471592A1

  公开（公告）日：2012-07-04

  A gas separation membrane is provided which has both excellent gas permeability and gas separation characteristics, particularly permeability of carbon dioxide (CO2) and separation characteristics of carbon dioxide and methane (CH4), at such a high level that has not hitherto been achieved. The gas separation membrane was obtained by heat treating a membrane composed of a hyperbranched polyimide-based material in a non-oxidizing atmosphere.

  提供了一种气体分离膜，它具有优异的气体渗透性和气体分离特性，特别是二氧化碳（CO2）的渗透性和二氧化碳与甲烷（CH4）的分离特性，其水平之高是迄今为止尚未达到的。这种气体分离膜是在非氧化气氛中对由超支化聚酰亚胺材料构成的膜进行热处理而得到的。
• POLYAMIDE ACID AND RESIN COMPOSITION CONTAINING SAME
  申请人：Toray Industries, Inc.

  公开号：EP2832769A1

  公开（公告）日：2015-02-04

  The invention aims to provide polyamic acid that can form a varnish with a low viscosity and serves to produce, through curing, coat film with good mechanical characteristics and further aims to produce cured coat film with good mechanical characteristics regardless of whether the molar concentration of the acid anhydride group in the acid dianhydride monomer and that of the amino group in the multivalent amine compound or diamine compound are identical to or different from each other. This objective is met by polyamic acid including a structure as represented by chemical formula (1) given below: (In chemical formula (1), δ represents an oxygen or sulfur atom and W represents an electron-withdrawing group, and R11 and R12 represent independently a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.

  本发明旨在提供可形成低粘度清漆的聚酰胺酸，通过固化可生产出具有良好机械特性的 涂膜，并进一步旨在生产出具有良好机械特性的固化涂膜，无论酸酐单体中酸酐基团的摩尔 浓度与多价胺化合物或二胺化合物中氨基的摩尔浓度是相同还是不同。包括如下化学式（1）所示结构的聚酰胺可以达到这一目的：(在化学式（1）中，δ 代表氧原子或硫原子，W 代表抽电子基团，R11 和 R12 分别独立地代表氢原子或具有 1 至 10 个碳原子的烃基。
• POLYAMIDE ACID RESIN COMPOSITION, POLYIMIDE FILM USING SAME, AND METHOD FOR PRODUCING SAID POLYIMIDE FILM
  申请人：Toray Industries, Inc.

  公开号：EP2881417A1

  公开（公告）日：2015-06-10

  An object is to provide a polyamic acid resin composition that can form a varnish with a low viscosity and serves to produce, through curing, coat film with good mechanical characteristics. Another object is to provide a polyamic acid resin composition in which the acid anhydride terminal group is low in reactivity with diamine and which can give a varnish that does not suffer significant precipitation of diamine. These objects can be met by a polyamic acid resin composition that contains: (a) polyamic acid and (b) a compound as represented by chemical formula (1). (In Chemical formula (1), Z is a di- or higher-valent organic group containing 2 or more carbon atoms, V is a structure as represented by chemical formula (2), and k is an integer of 2 or more.) (In In Chemical formula (2), δ represents oxygen or sulfur atom and W represents an electron-withdrawing group, and R11 and R12 represent independently a hydrogen atom or a hydrocarbon group containing 1 to 10 carbon atoms.

  一个目的是提供一种聚酰胺酸树脂组合物，它能形成一种低粘度清漆，并能通过 固化产生具有良好机械特性的涂膜。另一个目的是提供一种聚氨基甲酸酯树脂组合物，其中的酸酐端基与二胺的反应活性较低，并能产生一种二胺不会明显析出的清漆。含有以下成分的聚酰胺树脂组合物可以达到上述目的：(a) 聚酰胺和 (b) 化学式（1）所表示的化合物。(在化学式（1）中，Z 是含有 2 个或 2 个以上碳原子的二价或高价有机基团，V 是化学式（2）所代表的结构，k 是 2 个或 2 个以上的整数）。(在化学式（2）中，δ代表氧原子或硫原子，W代表抽电子基团，R11 和 R12 独立地代表氢原子或含有 1 至 10 个碳原子的烃基。