9,10-bis(phenylamino)anthracene | 2233-88-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-bis(phenylamino)anthracene
• 英文别名: N,N'-diphenyl-anthracene-9,10-diyldiamine；N,N'-Diphenyl-anthracen-9,10-diyldiamin；9.10-Dianilino-anthracen；9,10-bis(N-phenylamino)anthracene；9,10-Dianilinoanthracen；9-N,10-N-diphenylanthracene-9,10-diamine
• CAS: 2233-88-7
• 化学式: C₂₆H₂₀N₂
• mdl: MFCD00356445
• 分子量: 360.458
• InChiKey: VIFUTGPSFHEVLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  9,10-bis(phenylamino)anthracene 生成 N,N'-di-m-tolyl-anthracene-9,10-diyldiamine
  参考文献：
  名称：

  Shewandrow; Lewschin; Mosgowa, Izvestiya Akademii Nauk. Ser. Fizicheskaya, 1949, vol. 13, p. 49,54, 58

  摘要：

  DOI：
• 作为产物：
  描述：

  9-N,10-N-diphenylanthracene-9,10-diimine 在 sodium hydroxide 、 锌 作用下， 生成 9,10-bis(phenylamino)anthracene
  参考文献：
  名称：

  9.10 diamino anthracene and its nu-substitution products

  摘要：

  公开号：

  US01917801A1

文献信息

• Lithium–Bromide Exchange versus Nucleophilic Addition of Schiff's base: Unprecedented Tandem Cyclisation Pathways
  作者：Samantha A. Orr、Emily C. Border、Philip C. Andrews、Victoria L. Blair

  DOI：10.1002/chem.201902140

  日期：2019.9.12

  tert-butyllithium (tBuLi), we have revealed unprecedented competitive intermolecular and intramolecular cascade annulation pathways, leading to valuable compounds, such as iso-indolinones and N-substituted anthracene derivatives. A series of reaction parameters were probed, including solvent, stoichiometry, sterics and organolithium reagent choice, in order to understand the influences that limit such ring-closing

  通过探索芳族席夫碱与叔丁基锂（tBuLi）的溴化锂交换反应性，我们发现了前所未有的竞争性分子间和分子内级联环氧化途径，从而产生了有价值的化合物，例如异吲哚啉酮和N-取代的蒽衍生物。探索了一系列反应参数，包括溶剂，化学计量，空间位阻和有机锂试剂的选择，以了解限制此类闭环途径的影响。对于亚胺上的有机锂有两个可行的反应性选项；即亲核加成或溴化锂交换，观察到令人惊讶的竞争性质，即使在低温条件下，亲核加成仍占主导。考虑到最常用的溴化锂交换溶剂，
• Isolable Triradical Trication of Hexaaza[1₆]paracyclophane with Embedded 9,10-Anthrylenes: A Frustrated Three-Spin System
  作者：Ryohei Kurata、Daisuke Sakamaki、Masashi Uebe、Mariko Kinoshita、Tetsuo Iwanaga、Takashi Matsumoto、Akihiro Ito

  DOI：10.1021/acs.orglett.7b02088

  日期：2017.8.18

  macrocycle. The charge and spin distribution for one-electron and three-electron oxidation of the macrocycle was elucidated by means of electrochemical, spectroelectrochemical, EPR spectroscopic, and SQUID magnetometric methods. In particular, the triradical trication was successfully isolated as an air-stable salt, and moreover, its structure was disclosed by X-ray analysis. The triradical trication was characterized

  制备了一种新的六氮杂[1 6 ]对环环烷烃衍生物，其中对苯撑被9,10-蒽交替取代，以研究其对整体π偶联以及大环构象变化的影响。通过电化学，光谱电化学，EPR光谱和SQUID磁力分析方法阐明了大环的单电子和三电子氧化的电荷和自旋分布。特别地，成功地分离出三价三阳离子为空气稳定的盐，并且通过X射线分析公开了其结构。三自由基三阳离子的特征是具有反铁磁交换相互作用的自旋受阻三自旋系统（J / k B ≃– 74 K）。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE EMPLOYING THE SAME
  申请人：Funahashi Masakazu

  公开号：US20070114917A1

  公开（公告）日：2007-05-24

  An aromatic amine derivative with a special structure bonding to a fused polycyclic hydrocarbon group having silyl group. An organic electroluminescence device which comprises one or more organic thin film layers comprising at least a light emitting layer sandwiched between a cathode and an anode, wherein at least one of the organic thin film layer comprises the above aromatic amine derivative singly or as its mixture component. An organic electroluminescence device having a long lifetime and an enhanced efficiency of light emission together with the aromatic amine derivatives realizing the device are provided.

  一种具有硅基的融合多环碳基团的特殊结构连接的芳香胺衍生物。一种有机电致发光器件，其包括至少一个有机薄膜层，包括至少一个发光层，夹在阴极和阳极之间，其中至少一个有机薄膜层单独或作为其混合组分包含上述芳香胺衍生物。提供了具有长寿命和增强发光效率的有机电致发光器件以及实现该器件的芳香胺衍生物。
• Dopant material and organic electroluminescent device using said dopant material
  申请人：Lai Chun-Liang

  公开号：US20070122654A1

  公开（公告）日：2007-05-31

  The present invention relates to an organic electroluminescent device consisting of a substrate, an anode, a hole-injecting layer, a hole-transporting layer, at least one light-emitting layer, an electron-transporting layer, an electron-injecting layer and a cathode. Said at least one light-emitting layer contains a compound of formula (1) represented by: wherein R 1 , R 2 and R 3 are an alkyl group containing 1 to 4 carbon atoms; a, b and c are integers ranging from 0 to 3.

  本发明涉及一种有机电致发光器件，包括基板、阳极、注孔层、输孔层、至少一个发光层、输电子层、注电子层和阴极。所述至少一个发光层包含化学式（1）表示的化合物，其中R1、R2和R3是含有1至4个碳原子的烷基；a、b和c是介于0至3之间的整数。
• NOVEL TRIARYLAMINE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：Tosoh Corporation

  公开号：EP1528074A1

  公开（公告）日：2005-05-04

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：