1,2-bis-(4-methylphenoxy)benzene | 153287-98-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis-(4-methylphenoxy)benzene
• 英文别名: 1,2-Bis(4-methylphenoxy)benzene
• CAS: 153287-98-0
• 化学式: C₂₀H₁₈O₂
• 分子量: 290.362
• InChiKey: WOFYTBVMDWHXHV-UHFFFAOYSA-N

物化性质

• 沸点：
  378.3±30.0 °C(predicted)
• 密度：
  1.103±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,2-bis((η6-4-methylphenoxy-η5-cyclopentadienyl)iron)benzene hexafluorophosphate 以 二氯甲烷 、 乙腈 为溶剂， 以96%的产率得到1,2-bis-(4-methylphenoxy)benzene
  参考文献：
  名称：

  双（环戊二烯基铁）芳烃配合物：合成和官能化聚芳醚的新途径

  摘要：

  A new development in the chemistry of arenes activated toward S(N)Ar reactions by the cyclopentadienyliron (FeCp+) moiety is presented in this work. A class of diiron complexes of diphenoxybenzenes was prepared in a highly efficient and very mild fashion. Dihydroxyaromatic compounds served as dinucleophiles, allowing for the formation of the diiron complexes. This could be achieved in either a one or two step procedure. A wide variety of dinucleophiles were incorporated into this study, as well as a number of FeCp+ activated arenes. It is shown that these reactions are not inhibited by bulky substituents on either the dinucleophiles or activated arenes. The diiron complexes themselves could also undergo S(N)Ar reactions, provided that the complexed arenes contained a chlorine substituent. This allowed for the functionalization of the complexes with species that could not be introduced directly in their syntheses. The carbon nucleophiles generated from ethyl cyanoacetate or (phenylsulfonyl)acetonitrile could be attached to the complexed ethers in this manner. The FeCp+ moieties were removed easily by photolytic demetalation which allowed for the recovery of a wide range of functionalized diphenoxybenzenes. This methodology is advantageous over all those previously reported and should be a practical route to the synthesis of aromatic ethers.

  DOI：

  10.1021/om00013a055

文献信息

• Ligand-free highly effective iron/copper co-catalyzed formation of dimeric aryl ethers or sulfides
  作者：Xiaoming Qu、Tingyi Li、Yan Zhu、Peng Sun、Hailong Yang、Jincheng Mao

  DOI：10.1039/c1ob05155e

  日期：——

  Highly selective coupling of diiodoarenes with phenols or phenthiols can be performed by using a low-cost, benign character and readily available Fe/Cu catalytic system in the absence of ligands. It is noteworthy that the desired dimeric aryl ethers or sulfides could be obtained in high yields by coupling between diiodoarenes and phenols, or diphenols with aryl iodides.

  可以使用一种低成本、温和且易得的Fe/Cu催化体系，在无配体的条件下，选择性地将二碘芳烃与酚类或硫酚进行偶联。值得注意的是，通过二碘芳烃与酚类或二酚与芳基碘化物之间的偶联，能够以高产率获得所需的二聚芳醚或硫化物。
• HYGROMORPHIC POLYMERS AND COPOLYMERS HAVING HUMIDITY-DRIVEN MOTILITY
  申请人：Government of the United States, as represented by the Secretary of the Air Force

  公开号：US20170260334A1

  公开（公告）日：2017-09-14

  New diamine monomers bearing sulfone terminated pendant groups, as well as methods for making the same, are provided. The diamine monomers are useful toward making polyamide, polyimide, and poly(amide-imide) polymers and copolymers, which possess hygromorphic properties and demonstrate humidity driven motility.

  提供了带有磺酸终端偏基团的新二胺单体及其制备方法。这些二胺单体可用于制备具有湿敏性能和表现出湿度驱动运动的聚酰胺、聚酰亚胺和聚（酰胺-亚胺）聚合物和共聚物。
• Polyimide polymer and polyimide film
  申请人：TAIFLEX Scientific Co., Ltd.

  公开号：US10246556B2

  公开（公告）日：2019-04-02

  A polyimide polymer is provided. The polyimide polymer includes a repeating unit represented by formula 1. In formula 1, Ar is a tetravalent organic group derived from a tetracarboxylic dianhydride containing an aliphatic structure, and A includes and at least one divalent organic group derived from an aromatic group-containing diamine other than

  提供一种聚酰亚胺聚合物。该聚酰亚胺聚合物包括由式 1 表示的重复单元。 在式 1 中，Ar 是衍生自含有脂肪族结构的四羧酸二酐的四价有机基团，A 包括 和至少一个衍生自含芳香族基团二胺的二价有机基团，但不包括
• Bis(azobenzene) diamines and photomechanical polymers made therefrom
  申请人：The United States of America, as represented by the Secretary of the Air Force

  公开号：US10301430B2

  公开（公告）日：2019-05-28

  Bis(azo-benzene) diamine monomers and a method of synthesizing the monomers are provided. The bis(azo-benzene) diamine monomers, in combination with amine reactive monomers, form polymers, such as polyimides and copolyimides, having photomechanical and thermomechanical properties.

  本发明提供了双（偶氮苯）二胺单体及其合成方法。双（偶氮苯）二胺单体与胺反应性单体结合可形成具有光机械和热机械特性的聚合物，如聚酰亚胺和共聚酰亚胺。
• Hygromorphic polymers and copolymers having humidity-driven motility
  申请人：Government of the United States, as represented by the Secretary of the Air Force

  公开号：US10457780B2

  公开（公告）日：2019-10-29

  New diamine monomers bearing sulfone terminated pendant groups, as well as methods for making the same, are provided. The diamine monomers are useful toward making polyamide, polyimide, and poly(amide-imide) polymers and copolymers, which possess hygromorphic properties and demonstrate humidity driven motility.

  本发明提供了带有砜基末端悬垂基团的新型二胺单体及其制造方法。这种二胺单体可用于制造聚酰胺、聚酰亚胺和聚（酰胺-酰亚胺）聚合物和共聚物，它们具有吸湿性能，并表现出湿度驱动的运动性。