2,2',2''-triethoxy-triethylamine | 112299-51-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,2',2''-triethoxy-triethylamine
• 英文别名: tris-(2-ethoxy-ethyl)-amine；Tris-(2-aethoxy-aethyl)-amin；2.2'.2''-Triaethoxy-triaethylamin；tris-(3-oxapentyl)amine；Tris(2-ethoxyethyl)amine；2-ethoxy-N,N-bis(2-ethoxyethyl)ethanamine
• CAS: 112299-51-1
• 化学式: C₁₂H₂₇NO₃
• 分子量: 233.351
• InChiKey: PULSDMVBVHVNNG-UHFFFAOYSA-N

物化性质

• 保留指数：
  1442

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三(2-氯乙基)胺 在 氢氧化钾 作用下， 生成 2,2',2''-triethoxy-triethylamine
  参考文献：
  名称：

  New Compounds. β',β'',β'''-Triethoxytriethylamine

  摘要：

  DOI：

  10.1021/ja01228a601

文献信息

• Novel onium salts, photoacid generators, resist compositions, and patterning process
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20020076643A1

  公开（公告）日：2002-06-20

  Onium salts of arylsulfonyloxynaphthalenesulfonate anions with iodonium or sulfonium cations are novel. A chemically amplified resist composition comprising the onium salt as a photoacid generator is suited for microfabrication, especially by deep UV lithography because of many advantages including improved resolution, improved focal latitude, minimized line width variation or shape degradation even on long-term PED, minimized debris after coating, development and peeling, and improved pattern profile after development.

  芳基磺酸氧基萘磺酸盐的离子（离子包括碘离子或亚磺酸盐阳离子）是新颖的。 化学增感抗蚀剂组合物包括该离子盐作为光酸发生剂，适用于微细加工，特别是深紫外光刻，因为具有许多优点，包括提高分辨率，提高焦距范围，即使在长期PED上也能最小化线宽变化或形状退化，涂层、显影和剥离后最小化残留物，并在显影后改善图案轮廓。
• Ethanolysis of nitrogen mustards: A novel strategy for nitrogen mustard identification in environmental matrices by liquid chromatography–electrospray ionization–tandem mass spectrometry
  作者：Chen Belay、Avital Shifrovitch、Hagit Prihed、Moran Madmon、Merav Blanca、Tamar Shamai Yamin、Avi Weissberg

  DOI：10.1002/rcm.9701

  日期：2024.3.15

  Nitrogen mustards (NMs) are blistering chemical warfare agents. The ability to detect NMs in environmental samples is very important for obtaining forensic evidence. The most common analytical techniques for NM detection are gas chromatography–mass spectrometry, which detects NMs in their intact form but is disadvantaged by high limits of detection (LODs), and liquid chromatography–electrospray ionization–tandem

  氮芥子气 (NM) 是起泡的化学战剂。检测环境样本中的 NM 的能力对于获取法医证据非常重要。 NM 检测最常见的分析技术是气相色谱-质谱法，它可以检测完整形式的 NM，但其缺点是检测限 (LOD) 高，以及液相色谱-电喷雾电离-串联质谱法 (LC/ESI-MS) /MS）他们的水解产物，这没有提供强有力的证据来支持 NM 的使用。
• Photosensitive compositions containing carbonylic halides as activators
  申请人：Dynachem Corporation

  公开号：EP0005379A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component. a photoinitiator, a colorformer capable of changing color upon contact with a suitable activator and a latent activator containing an organic halide will become insoluble and change color under the influence of actinic radiation. The organic halide is a carbonylic compound such as an aliphatic or cycloaliphatic ketone or an ester or amide of a dicarboxylic acid. The compositions are useful to make resists used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、与适当活化剂接触后能变色的着色剂和含有有机卤化物的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并变色。 有机卤化物是一种羰基化合物，如脂肪族或环脂族酮或二羧酸的酯或酰胺。 这些组合物可用于制造电子工业中用于制造印刷电路的抗蚀剂。
• Phototropic photosensitive compositions containing a fluoran colorformer
  申请人：Dynachem Corporation

  公开号：EP0005380A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component, a photoinitiator, a fluoran colorformer and a latent activator that releases or promotes the release of a Lewis acid, will become insoluble and change color under the influence of actinic radiation. These compositions are particularly useful to make dry film photoresists, which are widely used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、荧光显色剂和可释放或促进释放路易斯酸的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并改变颜色。这些成分特别适用于制造干膜光阻，干膜光阻在电子工业中广泛用于制造印刷电路。
• Photoactivated polymerization of vinyl monomer in the presence of polysilanes and amines
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0154519A2

  公开（公告）日：1985-09-11

  This invention relates to photoactivatable polysilanes and processes involving the use thereof. It is frequently desirable to employ photopolymerization techniques to conduct the polymerization of vinyl (ethylenically unsaturated) monomers and prepolymers. The invention comprises subjecting a mixture of (1) a vinyl monomer or prepolymer, and (2) a polysilane having a chain of catenated silicon atoms (which may appear in an open chain or in a ring configuration) and a molecular weight of from about 5 x 102 to 5 x 106 to electromagnetic energy having wavelengths in the absorption range of from about 250 to 400 nanometers (nm) until the degree of polymerization of the monomer or prepolymer has increased. In another aspect, an organic amine can be included in the aforementioned mixture, in which case the amine acts as an activator. The process of the invention is particularly useful where it is desired to provide protective films or coatings on substrates since it has a number of advantages (such as speed, economy, efficiency and the like) over conventional polymerization techniques. The compositions of the invention can be conveniently applied as liquids to substrates then polymerized by means of electromagnetic energy, alone or together with elevated temperature, to form hard coatings.

  本发明涉及可光激活的聚硅烷及其使用工艺。 乙烯基（乙烯基不饱和）单体和预聚物的聚合通常需要采用光聚合技术。 本发明包括将乙烯基（乙烯基不饱和）单体和预聚物的混合物 (1) 乙烯基单体或预聚物，和 (2) 聚硅烷，该聚硅烷具有一条由硅原子组成的链，硅原子可呈开放链或环状结构，分子量约为 5 x 102 至 5 x 106，将其置于波长在约 250 至 400 纳米（nm）吸收范围内的电磁能中，直至单体或预聚物的聚合度增加。另一方面，上述混合物中可加入有机胺，在这种情况下，胺可作为活化剂。 与传统聚合技术相比，本发明的工艺具有许多优点（如速度快、经济、高效等），因此在需要在基材上提供保护膜或涂层时特别有用。本发明的组合物可以作为液体方便地涂在基底上，然后通过电磁能单独或与升高的温度一起聚合，形成坚硬的涂层。