trans-1,2-diphenylethylenediamine | 5763-83-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: trans-1,2-diphenylethylenediamine
• 英文别名: meso-stilbenediamine；1,2-Ethenediamine, 1,2-diphenyl-；(E)-1,2-diphenylethene-1,2-diamine
• CAS: 5763-83-7
• 化学式: C₁₄H₁₄N₂
• 分子量: 210.279
• InChiKey: TXVWTOBHDDIASC-BUHFOSPRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trans-1,2-diphenylethylenediamine 以 甲醇 、 氢氧化钾 、 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, characterization, electrochemical studies and catecholase-like activity of a series of mononuclear Cu(II), homodinuclear Cu(II)Cu(II) and heterodinuclear Cu(II)Ni(II) complexes of a phenol-based compartmental ligand

  摘要：

  A series of previously reported mononuclear Cu(II) and homodinuclear Cu(II)Cu(II) complexes, as well as, novel mononuclear Cu(II), homodinuclear Cu(II)Cu(II), and heterodinuclear Cu(II)Ni(II) complexes of a phenol-based dinucleating ligand with two different N(amine)(2)O-2 and N(imine)(2)O-2 coordination sites, were synthesized and characterized by elemental analyses, infrared and electronic absorption spectroscopies and conductivity measurements. The electrochemical behavior and catecholase-like activity of the complexes were also studied using cyclic voltammetry and UV-vis spectrophotometry, respectively. Our results show that the dinuclear complexes are more effective catalysts in the oxidation of catechol to the corresponding quinone than the mononuclear complexes. Furthermore, the homodinuclear Cu(II)Cu(II) complexes show greater catalytic activity compared to the corresponding heterodinuclear Cu(II)Ni(H) complexes. (c) 2005 Elsevier B.V All rights reserved.

  DOI：

  10.1016/j.molcata.2005.06.064
• 作为试剂：
  描述：

  N-[苯基-(甲苯-4-磺酰基)甲基]甲酰胺 、 diethylzinc 在 trans-1,2-diphenylethylenediamine 、 (S)-(-)-3-3′-双(3,5-双(三氟甲基)苯基)-1,1′-二-2-萘酚 作用下， 以 正己烷 、 1,2-二氯乙烷 为溶剂， 反应 36.0h， 生成 (S)-N-(1-phenylpropyl)formamide 、 (R)-N-(1-phenylpropyl)formamide
  参考文献：
  名称：

  高对映选择性二乙基锌加成亚胺的不对称活化手性催化剂的开发

  摘要：

  基于不对称活化概念，在不对称加成中评估了由衍生自手性 1,2-二苯基-乙烷-1,2-二胺、BINOL 衍生物和二乙基锌的二亚胺组合形成的原位手性锌配合物库二乙基锌转化为 N-酰基亚胺。在 10 mol% L3ZnAl 存在下，在 -25 °C 下，1,2-二氯乙烷中的多种芳族亚胺均具有高对映选择性和产率。

  DOI：

  10.1055/s-2005-863709

文献信息

• NAPHTHALENE-BASED INHIBITORS OF ANTI-APOPTOTIC PROTEINS
  申请人：Pellechia Maurizio

  公开号：US20100267781A1

  公开（公告）日：2010-10-21

  Methods of using apogossypol and its derivatives for treating inflammation is disclosed. Also, there is described a group of compounds having structure A, or a pharmaceutically acceptable salt, hydrate, N-oxide, or solvate thereof are provided: wherein each R is independently H, C(O)X, C(O)NHX, NH(CO)X, SO 2 NHX, or NHSO 2 X, wherein X is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, alkylaryl, substituted alkylaryl, heterocycle, or substituted heterocycle. Compounds of group A may be used for treating various diseases or disorders, such as cancer.

  使用阿波戈朴和其衍生物治疗炎症的方法被披露。此外，还描述了一组具有结构A的化合物，或其药学上可接受的盐、水合物、N-氧化物或溶剂化合物： 其中每个R独立地是H、C(O)X、C(O)NHX、NH(CO)X、SO2NHX或NHSO2X，其中X是氢、烷基、取代烷基、芳基、取代芳基、烷基芳基、取代烷基芳基、杂环或取代杂环。A组化合物可用于治疗各种疾病或疾病，如癌症。
• LEUCO COMPOUNDS
  申请人：Milliken & Company

  公开号：US20190112488A1

  公开（公告）日：2019-04-18

  A compound comprises at least one fluorescent moiety covalently bound to at least one second moiety selected from the group consisting of leuco moieties and chromophore moieties.

  一个化合物至少包括一个共价结合至来自亮色基团和色团基团组成的羟基团中的至少一个第二基团的荧光基团。
• PERFUME SYSTEMS
  申请人：Smets Johan

  公开号：US20110308556A1

  公开（公告）日：2011-12-22

  The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.

  本申请涉及香水原料、香水传递系统和包含这种香水原料和/或这种香水传递系统的消费者产品，以及制造和使用这种香水原料、香水传递系统和消费者产品的过程。本文所披露的香水原料和配方，包括传递系统，在香水社区的选择方面提供了更多选项，因为这些香水原料可以提供不同的特性变化，这些配方可以提供所需的气味特征。
• Macrolide antiinfective agents
  申请人：——

  公开号：US20020055472A1

  公开（公告）日：2002-05-09

  The invention is directed towards antibacterial compounds. The invention concerns macrolide antibiotics useful as antiinfective agents.

  这项发明是针对抗菌化合物的。该发明涉及可用作抗感染剂的大环内酯抗生素。
• Storage stable solutions of optical brighteners
  申请人：CLARIANT INTERNATIONAL LTD.

  公开号：EP1752453A1

  公开（公告）日：2007-02-14

  The instant invention relates to storage stable solutions of optical brighteners based on certain salt forms of anilino-substituted bistriazinyl derivatives of 4,4'-diaminostilbene-2,2'-disulphonic acid which do not need extra solubilising additives.

  这项瞬间发明涉及基于苯胺取代的4,4'-二氨基苯基-2,2'-二磺酸联吡唑基衍生物的某些盐形式的光学增白剂的储存稳定溶液，无需额外的增溶添加剂。