methyl-2 phenyl-3 pentane | 19219-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl-2 phenyl-3 pentane
• 英文别名: (1-ethyl-2-methyl-propyl)-benzene；(1-Aethyl-2-methyl-propyl)-benzol；2-Methyl-3-phenyl-pentan；2-Methyl-3-phenylpentan；(1-Ethyl-2-methylpropyl)benzene；2-methylpentan-3-ylbenzene
• CAS: 19219-86-4
• 化学式: C₁₂H₁₈
• 分子量: 162.275
• InChiKey: KXKQNZYTNYNPED-UHFFFAOYSA-N

物化性质

• 保留指数：
  1367

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (4-methylpent-2-en-3-yl)benzene 在 乙醇 、 铂 作用下， 生成 methyl-2 phenyl-3 pentane
  参考文献：
  名称：

  Factors Affecting Heavy-Duty Diesel Vehicle Emissions

  摘要：

  Societal and governmental pressures to reduce diesel exhaust emissions are reflected in the existing and projected future heavy-duty certification standards of these emissions. Various factors affect the amount of emissions produced by a heterogeneous charge diesel engine in any given situation, but these are poorly quantified in the existing literature. The parameters that most heavily affect the emissions from compression ignition engine-powered vehicles include vehicle class and weight, driving cycle, vehicle vocation, fuel type, engine exhaust aftertreatment, vehicle age, and the terrain traveled. In addition, engine control effects (such as injection timing strategies) on measured emissions can be significant. Knowing the effect of each aspect of engine and vehicle operation on the emissions from diesel engines is useful in determining methods for reducing these emissions and in assessing the need for improvement in inventory models. The effects of each of these aspects have been quantified in this paper to provide an estimate of the impact each one has on the emissions of diesel engines.

  DOI：

  10.1080/10473289.2002.10470755

文献信息

• Cobalt-catalyzed cross-coupling of Umpolung carbonyls with alkyl halides under mild conditions
  作者：Ruofei Cheng、Graham de Ruiter、Chao-Jun Li

  DOI：10.1039/d2cc04302e

  日期：——

  dominated by palladium and nickel catalysts, cobalt-based catalysts have shown unique advantages for such cross-coupling reactions in terms of higher catalytic activity and lower toxicity. Herein, we describe a novel cobalt-catalyzed alkyl–alkyl cross-coupling reaction of hydrazone with alkyl halides under mild reaction conditions, where the use of a PNP-type pincer ligand is essential for catalysis

  虽然经典的交叉偶联以钯和镍催化剂为主，但钴基催化剂在这种交叉偶联反应中表现出独特的优势，即更高的催化活性和更低的毒性。在此，我们描述了一种新型钴催化的腙与卤代烷在温和反应条件下的烷基-烷基交叉偶联反应，其中使用 PNP 型钳形配体对催化至关重要。醛和酮腙都与该反应相容，以中等至良好的产率产生一系列 C(sp 3 )–C(sp 3 ) 偶联产物。
• Albesco, Annales de Chimie (Cachan, France), 1922, vol. <9> 18, p. 221
  作者：Albesco

  DOI：——

  日期：——
• Isomerization Accompanying Alkylation. IX.¹ The Reaction of Benzene with n- and Isopropylcyclopropane. The Synthesis of n- and Isopropylcyclopropane²
  作者：Herman Pines、William D. Huntsman、V. N. Ipatieff

  DOI：10.1021/ja01106a007

  日期：1953.5
• Condensation of Secondary Alcohols with Phenol in the Presence of Aluminum Chloride
  作者：R. C. Huston、R. L. Guile、D. L. Bailey、R. J. Curtis、M. T. Esterdahl

  DOI：10.1021/ja01222a005

  日期：1945.6
• Iraqi, A.; Gallo, R.; Phan Tan Luu, R., Bulletin de la Societe Chimique de France, 1988, # 3, p. 548 - 554
  作者：Iraqi, A.、Gallo, R.、Phan Tan Luu, R.

  DOI：——

  日期：——