N-Styrylaniline | 5694-22-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Styrylaniline
• 英文别名: N-[(E)-2-phenylethenyl]aniline
• CAS: 5694-22-4
• 化学式: C₁₄H₁₃N
• 分子量: 195.26
• InChiKey: SBRDEWUKACUNPY-VAWYXSNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• RUBBER COMPOSITION
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0864606A1

  公开（公告）日：1998-09-16

  The present invention provides a rubber composition comprising 100 parts by weight of a diene rubber component, 10 to 200 parts by weight of a reinforcing agent, and 0.1 to 15 parts by weight of a fatty acid salt. For example, the diene rubber preferably comprises a diene rubber having a heteroatom-containing polar group, the reinforcing agent preferably comprises carbon black or silica, and the fatty acid salt preferably comprises a metal salt of a C1 to C36 fatty acid. This rubber composition yields a vulcanized rubber showing improvements in heat build-up, tensile strength, abrasion resistance and processability.

  本发明提供了一种橡胶组合物，其中包括 100 份（按重量计）二烯橡胶组分、 10 至 200 份（按重量计）补强剂和 0.1 至 15 份（按重量计）脂肪酸盐。例如，二烯橡胶最好包括具有含杂原子极性基团的二烯橡胶，补强剂最好包括炭黑或二氧化硅，脂肪酸盐最好包括 C1 至 C36 脂肪酸的金属盐。这种橡胶组合物产生的硫化橡胶在蓄热性、拉伸强度、耐磨性和加工性方面均有改善。
• CONJUGATED DIENE RUBBER, PROCESS FOR PRODUCING THE SAME, AND RUBBER COMPOSITION
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP1081162A1

  公开（公告）日：2001-03-07

  A rubber composition which comprises a rubber ingredient comprising a diene rubber and a reinforcing agent comprising silica; said diene rubber being a copolymer comprising (1) 30 to 85% by weight of conjugated diene monomer units, (2) 15 to 50% by weight of aromatic vinyl monomer units and (3) 0.05 to 20% by weight of units of a vinyl monomer having a polar group, and the diene rubber having in the molecule an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms.

  一种橡胶组合物，其橡胶成分包括二烯橡胶和由二氧化硅组成的补强剂；所述二烯橡胶是一种共聚物，包括 (1) 30 至 85% （重量百分比）共轭二烯单体单元、(2) 15 至 50% （重量百分比）芳香乙烯基单体单元和 (3) 0.05%至 20%（重量百分比）具有极性基团的乙烯基单体单元，二烯橡胶分子中具有 12 至 16 个碳原子的烷硫基，其中包括至少三个叔碳原子，并具有直接与至少一个叔碳原子结合的硫原子。
• Diene-based rubber/inorganic compound complexes, methods for producing the same and rubber compositions containing the same
  申请人：JSR Corporation

  公开号：EP1215226A2

  公开（公告）日：2002-06-19

  The object of the present invention is to provide a method for producing a diene-based rubber/inorganic compound complex capable of allowing a silicic acid compound including silica and the like to be dispersed uniformly and allowing a reinforcing effect to be exerted sufficiently, as well as a complex produced by said method and a rubber composition containing said complex. A latex comprising a diene-based rubber such as styrene-butadiene copolymeric rubber, butadienestyrene-isoprene copolymeric rubber and the like is mixed with an aqueous solution of a silicate in which an alkaline salt of silicic acid such as sodium silicate, potassium silicate and the like is dissolved, and then the resultant mixture is further mixed with an aqueous solution of electrolytes containing [1] a cationic substance which has an affinity to the diene-based rubber including a cationic polymer coagulating agent such as poly(meth)acrylic ester or the like and a cationic surfactant such as alkylamine acetate or the like and [2] a salt of an acid such as hydrochloric acid, nitric acid and the like with a multivalent metal such as calcium, magnesium and the like, to form a co-coagulated material, which is followed by a drying, whereby obtaining a diene-based rubber/inorganic compound complex.

  本发明的目的是提供一种生产二烯基橡胶/无机化合物复合物的方法，该复合物能使包括二氧化硅等在内的硅酸化合物均匀分散，并能充分发挥补强效果，同时还提供一种用上述方法生产的复合物和一种含有上述复合物的橡胶组合物。将包含二烯基橡胶（如苯乙烯-丁二烯共聚橡胶、丁二烯-异戊二烯共聚橡胶等）的胶乳与硅酸盐水溶液混合，硅酸盐水溶液中溶解有硅酸钠、硅酸钾等硅酸的碱性盐、然后将所得混合物与电解质水溶液进一步混合，电解质水溶液中含有 [1] 与二烯基橡胶有亲和力的阳离子物质，包括阳离子聚合物凝固剂，如聚（甲基）丙烯酸酯或类似物和阳离子表面活性剂，如乙酸烷基胺或类似物，以及 [2] 酸盐，如盐酸、硝酸等酸的盐与钙、镁等多价金属形成共凝物，然后进行干燥，从而得到二烯基橡胶/无机化合物复合物。
• Rubber composition
  申请人：BRIDGESTONE CORPORATION

  公开号：EP1219676A1

  公开（公告）日：2002-07-03

  A rubber composition comprises a polar group-containing diene polymer synthesized through an emulsion polymerization as a rubber component, and an inorganic filler represented by a formula of mM·xSiOy·zH2O wherein M is a metal selected from the group consisting of aluminum, magnesium, titanium and calcium, an oxide or a hydroxide of such a metal or an hydrate thereof, m is an integer of 1 to 5, x is an integer of 0 to 10, y is an integer of 2 to 5 and z is an integer of 0 to 10.

  一种橡胶组合物包括通过乳液聚合合成的含极性基团的二烯聚合物作为橡胶成分，以及由 mM-xSiOy-zH2O 式表示的无机填料，其中 M 是选自铝、镁、钛和钙组成的金属、此类金属的氧化物或氢氧化物或其水合物，m 是 1 至 5 的整数，x 是 0 至 10 的整数，y 是 2 至 5 的整数，z 是 0 至 10 的整数。
• DIENE RUBBER/INORGANIC COMPOUND COMPOSITE AND METHOD FOR PRODUCING THE SAME AND RUBBER COMPOSITION
  申请人：JSR Corporation

  公开号：EP1323775A1

  公开（公告）日：2003-07-02

  The invention provides a diene-based rubber-inorganic compound composite material comprising a diene-based rubber and at least one inorganic compound selected from silica and a compound represented by the following formula (I):         wM·xSiOy·zH2O     (I) (wherein M is at least one metal selected from the group consisting of Al, Mg, Ti and Ca or a metal oxide thereof or a metal hydroxide thereof, and w is a number of 1-5, x is a number of 0-10, y is a number of 2-5 and z is a number of 0-10), and a rubber composition comprising the composite material and a crosslinking agent.

  本发明提供了一种二烯基橡胶-无机化合物复合材料，包括二烯基橡胶和至少一种选自白炭黑的无机化合物以及下式（I）所代表的化合物： wM-xSiOy-zH2O (I) (其中，M 是选自 Al、Mg、Ti 和 Ca 组成的组中的至少一种金属或其金属氧化物或其金属氢氧化物，w 是 1-5 的数字，x 是 0-10 的数字，y 是 2-5 的数字，z 是 0-10 的数字），以及包含该复合材料和交联剂的橡胶组合物。