3-[3-(3-Aminophenoxy)-4-(trifluoromethyl)phenoxy]aniline | 154733-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[3-(3-Aminophenoxy)-4-(trifluoromethyl)phenoxy]aniline
• CAS: 154733-97-8
• 化学式: C₁₉H₁₅F₃N₂O₂
• 分子量: 360.3
• InChiKey: WFBKIKKAUTUAHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  7

文献信息

• TERMINALLY MODIFIED POLYBRANCHED POLYIMIDE, METAL-PLATED TERMINALLY MODIFIED POLYBRANCHED POLYIMIDE, AND METHOD FOR PRODUCING THE SAME
  申请人：Ataka Kikuo

  公开号：US20100009206A1

  公开（公告）日：2010-01-14

  A terminally-modified polybranched polyimide which can be efficiently complexed with an inorganic material is obtained by reacting a component (a): tetracarboxylic dianhydride; a component (b): as an amine component, a mixture of a triamine and a diamine (which may be composed of a triamine only); and a component (c): as a terminal component, a compound selected from general formulae (1-1) to (1-4). H 2 N—X—R 1 (1-1) (In the formula, X represents a single bond or an alkylene group having 1 to 3 carbon atoms, and R 1 represents a nitrogen-containing heterocyclic group). H 2 N—X—R 1 (1-2) (In the formula, X is as defined above, and R 1 represents a sulfur-containing heterocyclic group or an aryl group having a thiol or thioether group in the molecule). (In the formula, R represents a nitrogen-containing heterocyclic group). (In the formula, R represents a monovalent residue).

  通过反应组分(a):四羧酸二酐;组分(b):作为胺组分，三胺和二胺的混合物(可以仅由三胺组成);以及组分(c):作为末端组分，从通式(1-1)到(1-4)中选择的化合物，可以获得与无机材料高效络合的终止修饰的多支化聚酰亚胺。 H2N-X-R1(1-1)(式中，X表示单键或具有1到3个碳原子的烷基基团，R1表示含氮杂环基团)。 H2N-X-R1(1-2)(式中，X如上定义，R1表示含硫杂环基团或分子中具有巯基或硫醚基团的芳基基团)。 (式中，R表示含氮杂环基团)。 (式中，R表示单价残基)。
• Aromatic diamine and polyimde, and preparation process of same
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0565352A2

  公开（公告）日：1993-10-13

  This invention relates to fluorine containing polyimide, a novel aromatic diamine which has a perfluoroalkyl radical and can be used as a raw material monomer of the polyimide, and a process for preparing the same. The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula : such as the structural units of the formula Further, the present invention relates to a novel aromatic diamine which has a perfluoro radical and can be used as a raw material monomer of the polyimide, and a process for preparing the same. The present invention can provide polyimide which has an extremely low dielectric constant and is colorless, transparent and excellent in processability and heat resistance, and also provides an aromatic diamine which is useful as a raw material monomer of the polyimide or a raw material of other various engineering plastics.

  本发明涉及含氟聚酰亚胺、一种具有全氟烷基且可用作聚酰亚胺原料单体的新型芳香族二胺，以及制备该聚酰亚胺的工艺。 该聚酰亚胺由必要的结构单元组成，该结构单元具有一个或多个式......的重复结构单元： 例如式中的结构单元 此外，本发明还涉及一种具有全氟基并可用作聚酰亚胺原料单体的新型芳香族二胺，以及制备该单体的工艺。 本发明可提供介电常数极低、无色透明、加工性和耐热性优异的聚酰亚胺，还提供了一种可用作聚酰亚胺原料单体或其他各种工程塑料原料的芳香族二胺。
• Polyimide resin compositions for optical filters
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0695955A2

  公开（公告）日：1996-02-07

  Disclosed herein are a polyimide resin composition for an optical filter, comprising a colorless transparent polyimide resin containing at least one perfluoroalkyl group in each recurring structural unit and having excellent solvent solubility, and at least one dyestuff soluble in said resin, said dyestuff having absorption in the visible range and/or the near infrared range; a printing ink for an optical filter, comprising the polyimide resin composition and a solvent; and an optical filter comprising a transparent base material and the polyimide resin composition.

  本文公开了一种用于光学滤光片的聚酰亚胺树脂组合物，该组合物包括一种无色透明的聚酰亚胺树脂，其每个循环结构单元中至少含有一个全氟烷基，并具有极佳的溶剂溶解性，以及至少一种可溶于所述树脂的染料，所述染料在可见光范围和/或近红外范围内具有吸收性；一种用于光学滤光片的印刷油墨，该油墨包括聚酰亚胺树脂组合物和溶剂；以及一种光学滤光片，该滤光片包括透明基底材料和聚酰亚胺树脂组合物。
• An organic optical component
  申请人：MITSUI TOATSU CHEMICALS, INCORPORATED

  公开号：EP0826717A1

  公开（公告）日：1998-03-04

  There is disclosed an organic optical component prepared from a resin essentially comprising one or more repetitive structural units selected from the group consisting of structures represented by general formula (1);    wherein A is either of the groups below. This invention provides an organic optical component with excellent transparency, heat resistance and mechanical strength as well as a low birefringence. This invention also provides a novel aromatic polyamide with a low permitivity and excellent transparency, processability and thermal stability, besides excellent heat resistance inherent in an aromatic polyamide.

  本发明公开了一种有机光学元件，由基本上包含一个或多个重复结构单元的树脂制备而成，这些重复结构单元选自由通式(1)所代表的结构组成的组； 其中 A 为以下任一基团。 本发明提供了一种具有优异透明度、耐热性和机械强度以及低双折射的有机光学元件。本发明还提供了一种新型的芳香族聚酰胺，除了具有芳香族聚酰胺固有的优异耐热性外，还具有较低的容许率和优异的透明度、加工性和热稳定性。
• OPTICAL MEMBERS MADE OF POLYIMIDE RESINS
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1237015A1

  公开（公告）日：2002-09-04

  For providing a polyimide optical component exhibiting good physical properties inherent to a polyimide, i.e., heat resistance, mechanical properties, electric properties, thermal oxidation stability and chemical resistance, as well as good transparency and a high refractive index, this invention, this invention essentially uses a particular diamine and a particular tetracarboxylic dianhydride to give an optical component made of a polyimide having a motif represented by general formula (1):    wherein in general formula (1), A represents general formula (2), (3) or (4); X represents a direct bond, -O-, -SO2- or -C(CF3)2-; in general formula (2), R1 and R2 represent H, Cl, Br, CH3 or CF3; in general formula (3), A1 represents -O-, -S-, -CO-, -CH2-, -SO2-, -C(CH3)2- or -C(CF3)2-; in general formula (4), A2 represents a direct bond, -O-, -S-, -CO-, -SO2-, -C(CH3)2- or -C(CF3)2-.

  为了提供一种聚酰亚胺光学元件，使其具有聚酰亚胺固有的良好物理性能，即耐热性、机械性能、电性能、热氧化稳定性和耐化学性，以及良好的透明度和高折射率，本发明主要使用一种特定的二胺和一种特定的四羧酸二酐，以得到一种由具有通式（1）表示的图案的聚酰亚胺制成的光学元件： 其中，在通式（1）中，A 代表通式（2）、（3）或（4）；X 代表直接键、-O-、-SO2- 或-C(CF3)2-； 通式（2）中，R1 和 R2 代表 H、Cl、Br、CH3 或 CF3； 通式（3）中，A1 代表-O-、-S-、-CO-、-CH2-、-SO2-、-C(CH3)2- 或-C(CF3)2-； 通式（4）中，A2 代表直接键、-O-、-S-、-CO-、-SO2-、-C(CH3)2- 或 -C(CF3)2-。