1-Chlor-1-ethylcyclopentan | 19873-00-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-Chlor-1-ethylcyclopentan
• 英文别名: 1-ethyl-1-chloro-cyclopentane；1-Aethyl-1-chlor-cyclopentan；1-ethyl-cyclopentyl chloride；1-Chlor-1-aethyl-cyclopentan；1-Chloro-1-ethylcyclopentane
• CAS: 19873-00-8
• 化学式: C₇H₁₃Cl
• 分子量: 132.633
• InChiKey: KEZXKYAMQFOXQE-UHFFFAOYSA-N

物化性质

• 沸点：
  52 °C(Press: 33 Torr)
• 密度：
  0.9540 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-Chlor-1-ethylcyclopentan 在 甲基碘化镁 、 二丁醚 作用下， 生成 1-乙基-1-甲基环戊烷
  参考文献：
  名称：

  Plate; Ssabeshenskaja, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1946, p. 651,653

  摘要：

  DOI：
• 作为产物：
  描述：

  1-乙基环戊醇 在 盐酸 作用下， 生成 1-Chlor-1-ethylcyclopentan
  参考文献：
  名称：

  Plate; Ssabeshenskaja, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1946, p. 651,653

  摘要：

  DOI：

文献信息

• Trimethylsilyl cyanide promoted cyanation of tertiary alkyl chlorides and other SN1 active compounds
  作者：Manfred T. Reetz、Ioannis Chatziiosifidis、Hermann Künzer、Hans Müller-Starke

  DOI：10.1016/s0040-4020(01)88594-x

  日期：1983.1

  Tertiary chlorides are readily cyanated in a one-pot procedure using trimethylsilyl cyanide in the presence of SnCl4. The mechanism of this novel and synthetically useful reaction involves initial isonitrile formation followed by rearrangement to the tertiary nitrile. Other SN1 active componds also undergo smooth cyanation.

  在存在SnCl 4的情况下，使用三甲基甲硅烷基氰化物可以在一锅法中轻易地将氯化叔氰化。这种新颖的，合成上有用的反应的机理包括最初形成异腈，然后重排成叔腈。其他s Ñ 1活性componds也经历平滑氰化。
• Novel alkylcycloalkyl triazolylmethyl ketones as fungicide intermediates
  申请人：Bayer Aktiengesellschaft

  公开号：US05010208A1

  公开（公告）日：1991-04-23

  New alkylcycloalkyl triazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group and n is 3, 4, 5, 6 and 7, are produced as described and find use as intermediate products for the preparation of cycloalkyl (.alpha.-triazolyl-.beta.-hydroxy)-ketones, which possess fungicidal and plant growth-regulating properties.

  新的烷基环烷基三唑甲基酮的一般式为##STR1## 其中，R表示烷基，n为3、4、5、6和7，按照所述制备，并用作环烷基（α-三唑基-β-羟基）酮的中间体，该酮具有杀菌和植物生长调节性能。
• Alkylcycloalkyl imidazolylmethyl ketones as fungicide intermediates
  申请人：Bayer Aktiengesellschaft

  公开号：US04492795A1

  公开（公告）日：1985-01-08

  New alkylcycloalkyl imidazolylmethyl ketones of the general formula ##STR1## in which R represents an alkyl group and n is 3, 4, 5, 6 or 7, are produced as described and find use as intermediate products for the preparation of imidazolyl-vinyl-dithioacetals, which possess fungicidal properties.

  通式为##STR1##的新烷基环烷基咪唑甲基酮，其中R代表烷基，n为3、4、5、6或7，根据描述被制备，并用作咪唑基-乙烯-二硫代乙酸酯的中间体，该化合物具有杀真菌作用。
• AMIDE COMPOUND AND USE THEREOF
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2151431A1

  公开（公告）日：2010-02-10

  Disclosed is an amide compound represented by the formula (1) below, which has excellent plant disease controlling activity. In the formula, X1 represents a fluorine atom or a methoxy group; X2 represents a chlorine atom, a bromine atom, an iodine atom, a C1-C4 alkyl group or the like; Z represents an oxygen atom or a sulfur atom; and A represents an A1-CR11R12R13 group or A2-Cy group, wherein A1 and A2 each represents a single bond or the like, R11 and R12 independently represent a C1-C4 alkyl group, R13 represents H, a C1-C4 alkyl group or the like, and Cy represents a C3-C6 cycloalkyl group or the like.

  本发明公开了一种酰胺化合物，其化学式如下（1），具有出色的植物病害控制活性。在该式中，X1代表氟原子或甲氧基；X2代表氯原子、溴原子、碘原子、C1-C4烷基或类似物；Z代表氧原子或硫原子；A代表A1-CR11R12R13基团或A2-Cy基团，其中A1和A2各代表单键或类似物，R11和R12分别独立地代表C1-C4烷基，R13代表H、C1-C4烷基或类似物，Cy代表C3-C6环烷基或类似物。
• Top Coating Composition
  申请人：Maeda Kazuhiko

  公开号：US20120040294A1

  公开（公告）日：2012-02-16

  Disclosed is a top coating composition formed on a resist film, for protecting the resist film, the top coating composition being a top coating composition for photoresist, characterized by containing a fluorine-containing polymer having a repeating unit represented by the following general formula (1). This composition is capable of controlling developing solution solubility and has a high water repellency. [In the formula, R 1 represents a hydrogen atom, fluorine atom, methyl group or trifluoromethyl group, R 2 represents a heat-labile protecting group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W is a bivalent linking group.]

  本发明公开了一种用于保护光阻膜的顶层涂层组合物，该顶层涂层组合物是一种用于光刻胶的顶层涂层组合物，其特征在于包含具有以下一般式（1）所表示的重复单元的含氟聚合物。该组合物能够控制显影液的溶解性，并具有高度的防水性。[在公式中，R1表示氢原子、氟原子、甲基基团或三氟甲基基团，R2表示热敏保护基团，R3表示氟原子或含氟烷基团，W是双价连接基团。]