(carbamoylmethyl)diphenylphosphine sulfide | 151680-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (carbamoylmethyl)diphenylphosphine sulfide
• 英文别名: 2-diphenylphosphinothioylacetamide
• CAS: 151680-57-8
• 化学式: C₁₄H₁₄NOPS
• 分子量: 275.311
• InChiKey: ZYNPHEVXKGINBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  75.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  silver nitrate 、 (carbamoylmethyl)diphenylphosphine sulfide 以 乙腈 为溶剂， 以65%的产率得到Ag⁽¹⁺⁾*C₁₄H₁₄NOPS*NO₃^(1-) = Ag((C₆H₅)2P(S)CH₂CONH₂)(NO₃)
  参考文献：
  名称：

  Complexation of (carbamoylmethyl)diphenylphosphine sulfide with silver nitrate. The structure of the polymeric complex [Ag2{Ph2P(S)CH2C(O)NH2}2(NO3)2] n

  摘要：

  The reaction of (carbamoylmethyl)diphenylphosphine sulfide with AgNO3 yields the polymeric complex [Ag-2(Ph2P(S)CH2C(O)NH2}(2)(NO3)(2)](n). Its structure was established by X-ray diffraction analysis. The coordination environments about both Ag+ cations are formed by five donor atoms, two of which are bonded to the metal atom substantially more weakly than the remaining three atoms. The compositions of the coordination polyhedra are different: ({AgSO'(C)O(N)O-2(N')} and (AgS'SO(C)O-2(N)}). The coordinated ligands differ in their functions: one ligand chelates the metal cation and its sulfur atom is additionally bonded to the second cation, while the second ligand acts as a bridge between the two different cations. The structure of the complex and the character of the interaction between the ligand and AgNO3 are substantially affected by the network of hydrogen bonds.

  DOI：

  10.1007/bf02495218
• 作为产物：
  描述：

  diphenylphosphane sulfide 、 氯乙酰胺 在 sodium hydroxide 、 苄基三乙基氯化铵 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以85%的产率得到(carbamoylmethyl)diphenylphosphine sulfide
  参考文献：
  名称：

  Aladzheva, I. M.; Odinets, I. L.; Petrovskii, P. V., Russian Journal of General Chemistry, 1993, vol. 63, # 3.2, p. 431 - 437

  摘要：

  DOI：

文献信息

• Aladzheva, I. M.; Odinets, I. L.; Petrovskii, P. V., Russian Journal of General Chemistry, 1993, vol. 63, # 3.2, p. 431 - 437
  作者：Aladzheva, I. M.、Odinets, I. L.、Petrovskii, P. V.、Mastryukova, T. A.、Kabachnik, M. I.

  DOI：——

  日期：——
• Complexation of (carbamoylmethyl)diphenylphosphine sulfide with silver nitrate. The structure of the polymeric complex [Ag2{Ph2P(S)CH2C(O)NH2}2(NO3)2] n
  作者：M. P. Pasechnik、Z. A. Starikova、A. I. Yanovsky、I. M. Aladzheva、E. I. Matrosov、T. A. Mastryukova、M. I. Kabachnik

  DOI：10.1007/bf02495218

  日期：1997.4

  The reaction of (carbamoylmethyl)diphenylphosphine sulfide with AgNO3 yields the polymeric complex [Ag-2(Ph2P(S)CH2C(O)NH2}(2)(NO3)(2)](n). Its structure was established by X-ray diffraction analysis. The coordination environments about both Ag+ cations are formed by five donor atoms, two of which are bonded to the metal atom substantially more weakly than the remaining three atoms. The compositions of the coordination polyhedra are different: (AgSO'(C)O(N)O-2(N')} and (AgS'SO(C)O-2(N)}). The coordinated ligands differ in their functions: one ligand chelates the metal cation and its sulfur atom is additionally bonded to the second cation, while the second ligand acts as a bridge between the two different cations. The structure of the complex and the character of the interaction between the ligand and AgNO3 are substantially affected by the network of hydrogen bonds.