2-isopropylidene-1,3-benzodithiole | 54030-60-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-isopropylidene-1,3-benzodithiole
• 英文别名: 2-Isopropyliden-1,3-benzodithiol；2-Propan-2-ylidene-1,3-benzodithiole
• CAS: 54030-60-3
• 化学式: C₁₀H₁₀S₂
• 分子量: 194.321
• InChiKey: JIHQIPNJFFBMQH-UHFFFAOYSA-N

物化性质

• 熔点：
  97.5-99.0 °C
• 沸点：
  285.0±40.0 °C(Predicted)
• 密度：
  1.219±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-isopropylidene-1,3-benzodithiole 在 三氟乙酸 、 锌 作用下， 以 乙腈 为溶剂， 反应 0.17h， 生成 2-isopropyl-1,3-benzodithiole
  参考文献：
  名称：

  Barbero, Margherita; Cadamuro, Silvano; Ceruti, Maurizio, Gazzetta Chimica Italiana, 1987, vol. 117, # 4, p. 227 - 236

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(1-Chloro-1-methyl-ethyl)-benzo[1,3]dithiole 在 氢氧化钾 作用下， 以 苯 为溶剂， 反应 1.0h， 以91%的产率得到2-isopropylidene-1,3-benzodithiole
  参考文献：
  名称：

  Bellesia, Franco; Boni, Monica; Ghelfi, Franco, Journal of Heterocyclic Chemistry, 1994, vol. 31, # 6, p. 1721 - 1724

  摘要：

  DOI：

文献信息

• 1,4-Dithiafulvene aus der Umsetzung von 4,4-disubstituierten 1,3-Thiazol-5(4H)-thionen mit Acetylenderivaten
  作者：Christjohannes Jenny、Heinz Heimgartner

  DOI：10.1002/hlca.19860690223

  日期：1986.3.19

  1,4-Dithiafulvenes, Products of the Reaction of 4,4-Disubstituted 1,3-Thiazol-5(4H)-thiones and Acetylenic Compounds

  1,4-二硫富烯类化合物，4,4-二取代的1,3-噻唑-5（4 H）-硫酮与乙炔化合物的反应产物
• JENNY, CH.;HEIMGARTNER, H., HELV. CHIM. ACTA, 1986, 69, N 2, 419-429
  作者：JENNY, CH.、HEIMGARTNER, H.

  DOI：——

  日期：——
• BARBERO M.; CADAMURO S.; CERUTI M.; DEGANI I.; FOCHI R.; REGONDI V., GAZZ. CHIM. ITAL., 117,(1987) N 4, 227-235
  作者：BARBERO M.、 CADAMURO S.、 CERUTI M.、 DEGANI I.、 FOCHI R.、 REGONDI V.

  DOI：——

  日期：——
• POLYMERIZABLE COMPOSITION, FILM, AND HALF MIRROR FOR DISPLAYING PROJECTION IMAGE
  申请人：FUJIFILM Corporation

  公开号：US20170349828A1

  公开（公告）日：2017-12-07

  The present invention provides a polymerizable composition containing a polymerizable liquid crystal compound represented by Formula (I) and an oxime compound, in the formula, A 1 and A 2 each represent a phenylene group or a trans-1,4-cyclohexylene group, L 1 and L 2 each represent single bond, —C(═O)O—, or —OC(═O)—, Q 1 and Q 2 each represent a polymerizable group or the like, m and n represent an integer of 0 to 2, X may represent —X 3 -Sp 3 -Q 3 or two X's may be bonded to each other to form a fused ring, X 3 represents —C(═O)O—, Sp 1 , Sp 2 , and Sp 3 each represent single bond, an alkylene group, or the like, Q 3 represents hydrogen atom, a cycloalkyl group, a polymerizable group, or the like, and l represents an integer of 0 to 4. The polymerizable composition hardly causes yellowing after curing and is useful for manufacturing a film and a half mirror for displaying a projection image.
• COMPOSITION FOR FORMING PATTERN, KIT, CURED FILM, LAMINATE, PATTERN PRODUCING METHOD, AND METHOD FOR MANUFACTURING SEMICONDUCTOR ELEMENT
  申请人：FUJIFILM Corporation

  公开号：US20220009153A1

  公开（公告）日：2022-01-13

  Provided are: a composition for forming a pattern, which contains a polymerizable compound, a photopolymerization initiator, and a sensitizer containing two or more of at least one kind of atom selected from the group consisting of a nitrogen atom and a sulfur atom, in which a length of a specific atom chain from one atom to another atom among the two or more atoms is 2 or 3 in terms of the number of atoms; a kit to which the composition for forming a pattern is applied; a cured film; a laminate; a pattern producing method; and a method for manufacturing a semiconductor element.