1-(4-Bromobutyl)-2-ethenylbenzene | 83729-54-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-Bromobutyl)-2-ethenylbenzene
• CAS: 83729-54-8
• 化学式: C₁₂H₁₅Br
• 分子量: 239.15
• InChiKey: CCRVLYVLOUAXNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Method of demineralizing water or an aqueous solution
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0670184A2

  公开（公告）日：1995-09-06

  A method for demineralizing water or an aqueous solution, which comprises contacting the water or the aqueous solution to be treated to a strongly basic anion exchanger made of a crosslinked polymer having a constituting unit of the following formula (I): wherein A is a C1-2 linear alkylene group B is a C4-8 linear alkylene group, each of R1, R2 and R3 which may be the same or different, is a C1-4 alkyl group or a C2-4 alkanol group, X is a counter ion coordinated on the ammonium group, and the benzene ring D may have an alkyl group or a halogen atom as a substituent.

  一种使水或水溶液脱盐的方法，它包括将待处理的水或水溶液与由具有下式(I)构成单元的交联聚合物制成的强碱性阴离子交换剂接触： 其中 A 是 C1-2 直链亚烷基 B 是 C4-8 直链亚烷基，R1、R2 和 R3 中的每一个可以相同或不同，是 C1-4 烷基或 C2-4 烷醇基，X 是配位在铵基上的反离子，苯环 D 可以有一个烷基或一个卤素原子作为取代基。
• CATION EXCHANGERS OR CHELATING AGENTS AND PROCESS FOR THE PREPARATION THEREOF
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0919570A1

  公开（公告）日：1999-06-02

  A cation exchanger or a chelating agent having at least structural units represented by the following formula (I), the structural units being derived from a crosslinkable monomer containing an unsaturated hydrocarbon group: wherein A represents a C3-C8 alkylene group or a C4-C9 alkoxymethylene group; L represents SO3-X+, where X+ is a counter ion coordinated with the SO3- group, or a chelate-forming functional group; and the benzene ring may be substituted with an alkyl group or a halogen atom. This cation exchanger or chelating agent has excellent heat resistance and chemical stability, and is minimized in elution from the resins and also high in reaction rate.

  一种阳离子交换剂或螯合剂，至少具有下式(I)所代表的结构单元，这些结构单元来自含有不饱和烃基的可交联单体： 其中 A 代表 C3-C8 亚烷基或 C4-C9 亚烷氧基亚甲基；L 代表 SO3-X+，其中 X+ 是与 SO3- 基团配位的反离子或螯合官能团；苯环可被烷基或卤原子取代。 这种阳离子交换剂或螯合剂具有极佳的耐热性和化学稳定性，从树脂中洗脱的可能性极小，反应速度也很高。
• Process for producing hydroxyalkyl (meth)acrylates
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1029847A1

  公开（公告）日：2000-08-23

  In a process for producing hydroxyalkyl (meth)acrylates by the reaction of (meth)acrylic acid with an alkylene oxide, a thermally and chemically stable anion exchange resin is used as a catalyst, which resin contains a repeating unit represented by the following formula (1) as a component: wherein A is a straight chain alkylene group having 3 to 8 carbon atoms, each of R1, R2, and R3 is a hydrocarbon group or an alkanol group having 1 to 4 carbon atoms, which may be substituted with a hydroxyl group, X- is a counter ion coordinated with an ammonium group, where the substituent A with the ammonium group may be substituted at any position of a benzene ring, and the benzene ring may be substituted with an alkyl group or a halogen atom. The process can economically efficiently produce hydroxyalkyl (meth)acrylates without disadvantages such as deterioration in properties of a distillation residue.

  在通过(甲基)丙烯酸与环氧亚烷基反应生产羟烷基(甲基)丙烯酸酯的工艺中，使用热稳定性和化学稳定性好的阴离子交换树脂作为催化剂，该树脂含有下式(1)所代表的重复单元作为组分： 其中 A 是具有 3 至 8 个碳原子的直链亚烷基，R1、R2 和 R3 各为烃基或具有 1 至 4 个碳原子的烷醇基，可被羟基取代，X- 是与铵基配位的反离子，其中与铵基配位的取代基 A 可在苯环的任何位置被取代，苯环可被烷基或卤素原子取代。该工艺可以经济高效地生产羟基烷基（甲基）丙烯酸酯，而不会出现蒸馏残渣性质恶化等缺点。
• IONOMER RESIN AND IONOMER SOLUTION CONTAINING SAME, LAMINATE, MEMBER, ELECTROCHEMICAL ELEMENT, AND ELECTROCHEMICAL DEVICE
  申请人：Nitto Denko Corporation

  公开号：EP3269743A1

  公开（公告）日：2018-01-17

  Provided is an ionomer resin including a copolymer containing the following first structural unit. L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is -Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.

  本发明提供了一种离子聚合物树脂，包括一种含有以下第一结构单元的共聚物。 L1 至 L5 各自独立地为氢原子、具有 1 至 4 个碳原子的烷基、具有 1 至 4 个碳原子的烷醇基或包括阴离子交换基在内的特定官能团，官能团的一个例子是 -Z2-M1-Z1(R1)(R2)(R3)。R1 至 R3 直接与 Z1 键合，各自独立地为具有 1 至 8 个碳原子的烷基或具有 1 至 8 个碳原子的烷醇基。M1 是具有 3 至 8 个碳原子的线性烃链，Z1 是氮原子或磷原子，Z2 是与一个氢原子、氧原子或硫原子键合的氮原子。L6 是氢原子、甲基或乙基。
• Ionomer resin, and ionomer solution, multilayer body, member, electrochemical element, and electrochemical device that include the same
  申请人：NITTO DENKO CORPORATION

  公开号：US10593980B2

  公开（公告）日：2020-03-17

  Provided is an ionomer resin including a copolymer containing the following first structural unit. L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is —Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.

  本发明提供了一种离子聚合物树脂，包括一种含有以下第一结构单元的共聚物。 L1 至 L5 各自独立地为氢原子、具有 1 至 4 个碳原子的烷基、具有 1 至 4 个碳原子的烷醇基或包括阴离子交换基在内的特定官能团，官能团的一个例子是 -Z2-M1-Z1(R1)(R2)(R3)。R1 至 R3 直接与 Z1 键合，各自独立地为具有 1 至 8 个碳原子的烷基或具有 1 至 8 个碳原子的烷醇基。M1 是具有 3 至 8 个碳原子的线性烃链，Z1 是氮原子或磷原子，Z2 是与一个氢原子、氧原子或硫原子键合的氮原子。L6 是氢原子、甲基或乙基。