N,N'-di-p-fluorophenylacetamidine | 101393-04-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-di-p-fluorophenylacetamidine
• 英文别名: N,N'-bis(4-fluorophenyl)ethanimidamide
• CAS: 101393-04-8
• 化学式: C₁₄H₁₂F₂N₂
• 分子量: 246.259
• InChiKey: RDBJQMPXVALQIE-UHFFFAOYSA-N

物化性质

• 沸点：
  366.8±42.0 °C(Predicted)
• 密度：
  1.14±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N'-di-p-fluorophenylacetamidine 、 三甲基镓 以 正己烷 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Synthesis and properties of some gallium amidine complexes [GaX_yL_3–y][X = Me, Et or Cl; L = RNCR′NR (R, R′= H, alkyl or aryl); y= 0–2]. Crystal structures of [GaMe₂(PhNCPhNPh)] and [GaMe(PhNCPhNPh)₂]

  摘要：

  The amidinato compounds [GaMe(2)L] [L = RNCR'NR (R, R' = H, alkyl or aryl)], [GaMe(PhNCPhNPh)(2)], [GaEt(PhNCMeNPh)(2)] and [Ga(PhNCRNPh)(3)](R = Me or Ph) have been isolated from the reaction of the appropriate gallium trialkyl with 1, 2 and 3 mol of amidine RNCR'N(H)R, respectively. The chloro derivatives [GaCl3 {RNCR'N(H)R}] (R = Ph or p-ClC6H4; R' = Me) and [GaCl2(p-ClC(6)H(4)NCMeNC(6)H(4)Cl-p)] have also been prepared. The compounds have been fully characterised, and mass spectrometric data indicate that the volatile dimethylgallium derivatives exist as either monomers or dimers in the gas phase. X-Ray crystallographic studies on [GaMe(2)(PhNCPhNPh)l and [GaMe(PhNCPhNPh)(2)] revealed monomeric structures and the presence of chelating amidinate ligands, with distorted tetrahedral and trigonal-bipyramidal co-ordination respectively at the metal centres. Cleavage of the Ga-Me bond occurs on photolysis in the. presence of a spin-trapping agent, and thermal decomposition of the solids leads to the formation of gallium nitride.

  DOI：

  10.1039/dt9960000431

文献信息

• ORGANOMETALLIC COMPLEXES OF ALUMINIUM, GALLIUM AND INDIUM
  申请人：THE ASSOCIATED OCTEL COMPANY LIMITED

  公开号：EP0712409A1

  公开（公告）日：1996-05-22
• US5834058A
  申请人：——

  公开号：US5834058A

  公开（公告）日：1998-11-10
• [EN] ORGANOMETALLIC COMPLEXES OF ALUMINIUM, GALLIUM AND INDIUM<br/>[FR] COMPLEXES ORGANOMETALLIQUES D'ALUMINIUM, DE GALLIUM ET D'INDIUM
  申请人：THE ASSOCIATED OCTEL COMPANY LIMITED

  公开号：WO1995004063A1

  公开（公告）日：1995-02-09

  (EN) Novel organometallic complexes of aluminium, gallium and indium are disclosed, having improved stability and volatility for use in CVD processes. These are donor ligand complexes of the formula MR2.L where M is the metal, R is an alkyl group and L is a ligand containing an amidine (R'N-^..B7-^..B7-^..B7C(R')-^..B7-^..B7-^..B7NR') group, where R' is H, alkyl etc.(FR) L'invention concerne de nouveaux complexes organométalliques d'aluminium, de gallium et d'indium qui ont une stabilité et une volatilité améliorées et qui sont utilisés dans des processus de déposition en phase gazeuse par procédé chimique. Ceux-ci sont des complexes de ligands provenant de donneurs, de la formule MR2.L, dans laquelle M représente le métal, R est un groupe alkyle et L est un ligand contenant une amidine du groupe (R'N-^..B7-^..B7-^..B7C(R')-^..B7-^..B7-^..B7NR') dans lequel R' représente H, alkyle, etc.
• Synthesis and properties of some gallium amidine complexes [GaX_yL_3–y][X = Me, Et or Cl; L = RNCR′NR (R, R′= H, alkyl or aryl); y= 0–2]. Crystal structures of [GaMe₂(PhNCPhNPh)] and [GaMe(PhNCPhNPh)₂]
  作者：James Barker、Nicholas C. Blacker、Paul R. Phillips、Nathaniel W. Alcock、William Errington、Malcolm G. H. Wallbridge

  DOI：10.1039/dt9960000431

  日期：——

  The amidinato compounds [GaMe(2)L] [L = RNCR'NR (R, R' = H, alkyl or aryl)], [GaMe(PhNCPhNPh)(2)], [GaEt(PhNCMeNPh)(2)] and [Ga(PhNCRNPh)(3)](R = Me or Ph) have been isolated from the reaction of the appropriate gallium trialkyl with 1, 2 and 3 mol of amidine RNCR'N(H)R, respectively. The chloro derivatives [GaCl3 RNCR'N(H)R}] (R = Ph or p-ClC6H4; R' = Me) and [GaCl2(p-ClC(6)H(4)NCMeNC(6)H(4)Cl-p)] have also been prepared. The compounds have been fully characterised, and mass spectrometric data indicate that the volatile dimethylgallium derivatives exist as either monomers or dimers in the gas phase. X-Ray crystallographic studies on [GaMe(2)(PhNCPhNPh)l and [GaMe(PhNCPhNPh)(2)] revealed monomeric structures and the presence of chelating amidinate ligands, with distorted tetrahedral and trigonal-bipyramidal co-ordination respectively at the metal centres. Cleavage of the Ga-Me bond occurs on photolysis in the. presence of a spin-trapping agent, and thermal decomposition of the solids leads to the formation of gallium nitride.