申请人:NIPPON PETROCHEMICALS COMPANY, LIMITED
公开号:EP0119065A1
公开(公告)日:1984-09-19
A process for preparing a diaryl or a mixture of diaryls represented by any or a combination of the following formulae (II), (III), and (IV), characterized in that a diaryliodonium salt represented by the following formula (1) is reacted in a solvent in the presence of a transition metal catalyst and a reducing metal at a temperature in the range of room temperature to 100°C:
wherein Ar1 and Ar2, which may be alike or different, are each an aryl group which may have a substituent group or groups and X⊖ is a counter ion which is inert to said reaction.
一种制备由下式(II)、(III)和(IV)中任何一种或其组合代表的二芳基或二芳基混合物的工艺,其特征在于由下式(1)代表的二芳基碘鎓盐在溶剂中,在过渡金属催化剂和还原金属存在下,于室温至100℃范围内进行反应:
其中 Ar1 和 Ar2(可以相同或不同)各自为芳基,可带有一个或多个取代基,X⊖ 为对所述反应惰性的反离子。