N-propylidene-(cyclohexylidene-methylamine) | 69882-91-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-propylidene-(cyclohexylidene-methylamine)
• 英文别名: propylidene-(cyclohexylidene-methylamine)；propylidene(cyclohexylidene-methylamine)；N-(cyclohexylidenemethyl)propan-1-imine
• CAS: 69882-91-3
• 化学式: C₁₀H₁₇N
• 分子量: 151.252
• InChiKey: KVWNCESUUZYUNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (E)-N-allyl-1-cyclohexylmethanimine 以 四氢呋喃 、 potassium tert-butylate 为溶剂， 以83%的产率得到N-propylidene-(cyclohexylidene-methylamine)
  参考文献：
  名称：

  2-Aza-1,3-dienes

  摘要：

  描述了化合物的公式为##STR1##其中R.sub.1和R.sub.2分别独立地表示具有1-8个C原子的烷基，或者与C原子的键结合形成具有4-8个C原子的环脂肪环，R.sub.3表示乙基; 或者其中R.sub.1表示具有1-8个C原子的烷基，R.sub.2表示氢，或者具有1-8个C原子的烷基，R.sub.3表示具有4-8个C原子的三级烷基。公式I的化合物可以通过在惰性有机溶剂中和催化剂的存在下适当取代的烯丙胺异构化而简单地制备，并且收率良好至非常好。公式I的化合物是生产用于对抗植物害虫的活性物质的有价值的中间体。

  公开号：

  US04289905A1

文献信息

• Substituted 11-aminoundecanols
  申请人：Ciba-Geigy Corporation

  公开号：US04332969A1

  公开（公告）日：1982-06-01

  Novel substituted 11-aminoundecanols of the formula ##STR1## and a process for their preparation are described; in the formula, R.sub.1 and R.sub.3 independently of one another are hydrogen or alkyl having 1-8 C atoms and R.sub.2 and R.sub.4 independently of one another are alkyl having 1-8 C atoms, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together with the bonding C atom form a cycloaliphatic ring having 4-8 C atoms, and R.sub.5 and R.sub.6 independently of one another are hydrogen or alkyl having 1-4 C atoms. The compounds of the formula I are valuable active compounds for combating plant pests.

  描述了一种新颖的替代品，其为式##STR1##的11-氨基十一醇，以及其制备方法；在该式中，R.sub.1和R.sub.3彼此独立地是氢或具有1-8个碳原子的烷基，R.sub.2和R.sub.4彼此独立地是具有1-8个碳原子的烷基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4与连接碳原子一起形成具有4-8个碳原子的环脂环，R.sub.5和R.sub.6彼此独立地是氢或具有1-4个碳原子的烷基。式I的化合物是用于对抗植物害虫的有价值的活性化合物。
• 1-Aza-1,5,9-cyclododecatrienes
  申请人：Ciba-Geigy Corporation

  公开号：US04213901A1

  公开（公告）日：1980-07-22

  Compounds of the formula ##STR1## and a process for their preparation by reacting azabutadienes with dienes, especially 1,3-butadiene, in the presence of catalysts are described. In the formula I, R.sub.1 and R.sub.3 independently of one another are hydrogen or alkyl having 1-8 C atoms and R.sub.2 and R.sub.4 independently of one another are alkyl having 1-8 C atoms, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together with the bonding C atom form a cycloaliphatic ring having 4-8 C atoms, and R.sub.5 and R.sub.6 independently of one another are hydrogen or alkyl having 1-4 C atoms. The compounds of the formula I are valuable intermediates for the preparation of active compounds for combating plant pests.

  描述了公式##STR1##的化合物及其制备方法，方法是通过在催化剂存在下将氮丁二烯与二烯反应，特别是1,3-丁二烯。在公式I中，R.sub.1和R.sub.3彼此独立地是氢或具有1-8个碳原子的烷基，R.sub.2和R.sub.4彼此独立地是具有1-8个碳原子的烷基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4与连接的碳原子一起形成具有4-8个碳原子的环脂环，R.sub.5和R.sub.6彼此独立地是氢或具有1-4个碳原子的烷基。公式I的化合物是用于制备用于对抗植物害虫的活性化合物的有价值的中间体。
• 2-Aza-1,3-dienes
  申请人：Ciba-Geigy Corporation

  公开号：US04289905A1

  公开（公告）日：1981-09-15

  There are described compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another represent alkyl having 1-8 C atoms, or together with the bond C atom they represent a cycloaliphatic ring having 4-8 C atoms, and R.sub.3 represents ethyl; or wherein R.sub.1 represents alkyl having 1-8 C atoms, R.sub.2 represents hydrogen, or alkyl having 1-8 C atoms, and R.sub.3 represents tertiary alkyl having 4-8 C atoms. The compounds of the formula I can be produced in a simple manner, in good to very good yields, by isomerisation of suitably substituted allylamines in an inert organic solvent and in the presence of a catalyst. The compounds of the formula I constitute valuable intermediates for producing active substances for combating plant pests.

  描述了化合物的公式为##STR1##其中R.sub.1和R.sub.2分别独立地表示具有1-8个C原子的烷基，或者与C原子的键结合形成具有4-8个C原子的环脂肪环，R.sub.3表示乙基; 或者其中R.sub.1表示具有1-8个C原子的烷基，R.sub.2表示氢，或者具有1-8个C原子的烷基，R.sub.3表示具有4-8个C原子的三级烷基。公式I的化合物可以通过在惰性有机溶剂中和催化剂的存在下适当取代的烯丙胺异构化而简单地制备，并且收率良好至非常好。公式I的化合物是生产用于对抗植物害虫的活性物质的有价值的中间体。