N-(p-phenylbenzoyl)phenylhydroxylamine | 168634-01-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(p-phenylbenzoyl)phenylhydroxylamine
• 英文别名: N-Hydroxy-N-phenyl[1,1'-biphenylyl]-4-carboxamide；N-hydroxy-N,4-diphenylbenzamide
• CAS: 168634-01-3
• 化学式: C₁₉H₁₅NO₂
• 分子量: 289.334
• InChiKey: DDLZXQVJKXUEPK-UHFFFAOYSA-N

物化性质

• 沸点：
  486.9±38.0 °C(Predicted)
• 密度：
  1.241±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  联苯-4-甲酰氯 、 苯基羟胺 在 碳酸氢钠 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 2.0h， 以61%的产率得到N-(p-phenylbenzoyl)phenylhydroxylamine
  参考文献：
  名称：

  Solid-phase extraction of plutonium(IV) an americium(III) using N-benzoylphenylhydroxylamine and its derivatives

  摘要：

  The recovery and separation of plutonium(IV) and americium(III) by solid-phase extraction (SPE) on alkylated silica gel S16 modified with N-benzoylphenylhydroxylamine (BPHA) and with its derivatives was studied. BPHA was modified by introducing into the p-position of the phenyl ring of electronactive substituents that differ in their hydrophobicity: CH(3), Ph, Cl, F, and NO(2). The SPE of plutonium(IV) and americium(III) was studied in the range of acidities from pH 8 to 1 M HNO(3). The recovery and separation of these elements was shown to depend on the nature of the substituent, aqueous acidity, and the preparation of S16 to SPE experiments.

  DOI：

  10.1134/s0036023611110192

文献信息

• Solid-phase extraction of plutonium(IV) an americium(III) using N-benzoylphenylhydroxylamine and its derivatives
  作者：O. M. Petrukhin、B. Ya. Spivakov、V. P. Morgalyuk、G. I. Malofeeva、E. V. Kuzovkina、A. P. Novikov

  DOI：10.1134/s0036023611110192

  日期：2011.11

  The recovery and separation of plutonium(IV) and americium(III) by solid-phase extraction (SPE) on alkylated silica gel S16 modified with N-benzoylphenylhydroxylamine (BPHA) and with its derivatives was studied. BPHA was modified by introducing into the p-position of the phenyl ring of electronactive substituents that differ in their hydrophobicity: CH(3), Ph, Cl, F, and NO(2). The SPE of plutonium(IV) and americium(III) was studied in the range of acidities from pH 8 to 1 M HNO(3). The recovery and separation of these elements was shown to depend on the nature of the substituent, aqueous acidity, and the preparation of S16 to SPE experiments.