iminonitrogen | 36882-13-0

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• 英文名称: iminonitrogen
• 英文别名: Dinitrogen monohydride
• CAS: 36882-13-0
• 化学式: HN₂
• 分子量: 29.0213
• InChiKey: NALBLJLOBICXRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.8
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  NH2 radical 、 氧化亚氮 生成 iminonitrogen 、 大鼠1,25-二羟基维生素D(1,25(OH)2D)试剂盒
  参考文献：
  名称：

  Product Branching Ratios in the NH₂ + NO Reaction:  A Re-Evaluation

  摘要：

  DOI：

  10.1021/jp990954f

文献信息

• Kinetic measurements and product branching ratio for the reaction NH2+NO AT 294–1027 K
  作者：B. Atakan、A. Jacobs、M. Wahl、R. Weller、J. Wolfrum

  DOI：10.1016/0009-2614(89)87482-2

  日期：1989.3

  Absolute rate coefficients for the reaction NH2+NO were measured by following the OH radical formation at 294–1027 K in a heatable quartz reactor by means of the laser photolysis/laser-induced fluorescence technique. The data fit the expression k1 = (7.9±1.0) × 1015T−1.17±0.25 cm3 mol−1 s−1. In addition, the branching ratio β into the OH product c to be 0.1±0.025 at 300 K; β increases with increasing

  通过跟踪可加热石英反应器中294-1027 K处的OH自由基的形成，通过激光光解/激光诱导荧光技术测量NH 2 + NO反应的绝对速率系数。数据符合表达式k 1 =（7.9±1.0）×10 15 T -1.17±0.25 cm 3 mol -1 s -1。另外，在300K下，进入OH产物c的支化比β为0.1±0.025。β随着温度的升高而增加，并在1000 K时达到0.19±0.05的值。
• Pagsberg, Palle; Sztuba, Barbara; Ratajczak, Emil, Acta Chemica Scandinavica, 1991, vol. 45, # 4, p. 329 - 334
  作者：Pagsberg, Palle、Sztuba, Barbara、Ratajczak, Emil、Sillesen, Alfred

  DOI：——

  日期：——
• Sheldon, John C.; O'Hair, Richard A. J.; Downard, Kevin M., Australian Journal of Chemistry, 1995, vol. 48, # 2, p. 155 - 166
  作者：Sheldon, John C.、O'Hair, Richard A. J.、Downard, Kevin M.、Gronert, Scott、Krempp, Michele、et al.

  DOI：——

  日期：——
• A Shock Tube Study of the Product Branching Ratio for the Reaction NH₂ + NO Using Frequency-Modulation Detection of NH₂
  作者：M. Votsmeier、S. Song、R. K. Hanson、C. T. Bowman

  DOI：10.1021/jp983613v

  日期：1999.3.1

  The product branching ratio of [NH2 + NO --> N2H + OH]:[NH2 + NO --> N-2 + H2O] has been determined in the temperature range of 1340-1670 K in a shock tube study with laser photolytic generation of the NH2 radicals. Sensitive frequency-modulation detection of the NH radical enables experiments with very low initial radical concentrations and, hence, virtually no interference from secondary reactions or dependence on the overall rate coefficient of the reaction. The branching ratio, alpha, defined as alpha = k(1a)/(k(1a)+k(1b)), increases from 0.42 at 1340 K to 0.53 at 1670 K. Over this temperature range our results can be expressed as alpha = 0.5 + (3.36 x 10(-4))(T/K - 1600). A detailed error analysis yields an uncertainty in the values of alpha of +/-0.02 near 1500 K, increasing to +/-0.05 at the temperature extremes.
• Experimental determination of the hydroxyl product yield from amidogen + nitric oxide at 300 K
  作者：David A. Dolson

  DOI：10.1021/j100283a025

  日期：1986.12