sodium 2,6-dinitrophenolate | 32581-06-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium 2,6-dinitrophenolate
• 英文别名: Sodium;2,6-dinitrophenolate；sodium;2,6-dinitrophenolate
• CAS: 32581-06-9
• 化学式: C₆H₃N₂O₅*Na
• 分子量: 206.09
• InChiKey: UJUDRTXLMKTXOL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.42
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  115
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  sodium 2,6-dinitrophenolate 以45%的产率得到
  参考文献：
  名称：

  RYZHOVA G. A.; POGALEEVA A. M.; BORTOVOJ I. M., V SB. VOPR. XIMII. VYP. 12 TOMSK, TOMSK. YH-T, 1977 34-39

  摘要：

  DOI：
• 作为产物：
  描述：

  2,6-二硝基苯酚 在 甲醇 、 sodium 作用下， 生成 sodium 2,6-dinitrophenolate
  参考文献：
  名称：

  Sammes, Peter G.; Thetford, Dean; Voyle, Martyn, Journal of the Chemical Society. Perkin transactions I, 1988, p. 3229 - 3232

  摘要：

  DOI：

文献信息

• Synthesis and Characterization of Organotin(IV) 2,4‐Dinitrophenoxides
  作者：N. Sharma、A. Kaistha、S. S. Bhatt、S. C. Chaudhry

  DOI：10.1081/sim-120020001

  日期：2003.1.6

  Complexes of the composition [R3Sn(DNP)] and [n-Bu2SnCl2-x (DNP)(x)] (R = Ph and Me; x = 1 and 2; DNP = anion of 2,4-dinitrophenol) have been synthesized by the silver metathesis method, involving the reaction of Ph3SnCl, Me3SnCl and n-Bu2SnCl2 with the silver salt of 2,4-dinitrophenol in tetrahydrofuran at room temperature and were characterized by elemental analyses, conductivity measurements, IR, and H-1 NMR studies. The IR spectral studies suggest a bidentate mode of coordination of phenol in these complexes. Double phenoxides of the type M-2[R3Sn(DNP)(3)] (M=Na and K) have also been obtained by reacting the parent triorganotin(IV) phenoxides with alkali metal derivatives of the phenol in 1:2 molar ratio. Thermal investigations of these complexes depicted quite interesting behaviour, as the decomposition did not yield any residue, contrary to previous reports. The thermal behaviour of these complexes has shown their ability as high-energy materials.
• Titskii, G. D.; Mitchenko, E. S., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 10, p. 1949 - 1954
  作者：Titskii, G. D.、Mitchenko, E. S.

  DOI：——

  日期：——
• TITSKIJ, G. D.;MITCHENKO, E. S., ZH. ORGAN. XIMII, 24,(1988) N 10, S. 2161-2166
  作者：TITSKIJ, G. D.、MITCHENKO, E. S.

  DOI：——

  日期：——
• Sammes, Peter G.; Thetford, Dean; Voyle, Martyn, Journal of the Chemical Society. Perkin transactions I, 1988, p. 3229 - 3232
  作者：Sammes, Peter G.、Thetford, Dean、Voyle, Martyn

  DOI：——

  日期：——
• RYZHOVA G. A.; POGALEEVA A. M.; BORTOVOJ I. M., V SB. VOPR. XIMII. VYP. 12 TOMSK, TOMSK. YH-T, 1977 34-39
  作者：RYZHOVA G. A.、 POGALEEVA A. M.、 BORTOVOJ I. M.

  DOI：——

  日期：——