2-[5-acetamido-N-(2-acetyloxyethyl)-4-[(2-bromo-4,6-dinitrophenyl)diazenyl]-2-methoxyanilino]ethyl acetate | 3618-72-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 2-[5-acetamido-N-(2-acetyloxyethyl)-4-[(2-bromo-4,6-dinitrophenyl)diazenyl]-2-methoxyanilino]ethyl acetate
• 英文别名: Disperse Blue 79
• CAS: 3618-72-2
• 化学式: C₂₃H₂₅BrN₆O₁₀
• 分子量: 625.39
• InChiKey: JSRUDOBCTLPTFO-CYYJNZCTSA-N

物化性质

• 熔点：
  149-151 °C
• 沸点：
  796.7±60.0 °C(Predicted)
• 密度：
  1.55
• LogP：
  1.63 at 20℃

计算性质

• 辛醇/水分配系数(LogP)：
  4.58
• 重原子数：
  40.0
• 可旋转键数：
  13.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  205.17
• 氢给体数：
  1.0
• 氢受体数：
  13.0

反应信息

• 作为反应物：
  描述：

  2-[5-acetamido-N-(2-acetyloxyethyl)-4-[(2-bromo-4,6-dinitrophenyl)diazenyl]-2-methoxyanilino]ethyl acetate 在 sodium dithionite 、 三氯化铁 、 铁粉 作用下， 以 甲醇 为溶剂， 反应 3.25h， 生成 3-bromo-5-nitrobenzene-1,2-diamine
  参考文献：
  名称：

  Chemical- and Sediment-Mediated Reduction of the Azo Dye Disperse Blue 79

  摘要：

  Disperse Blue 79, a large volume disperse azo dye, and 2-bromo-4,6-dinitroaniline (BDNA), an important intermediate in the preparation of Disperse Blue 79, were readily reduced chemically and in three anoxic sediment-water systems studied; half-lives were on the order of minutes to hours. No reduction of Disperse Blue 79 or BDNA was observed however in a sediment-water system containing sediment with low organic carbon. The reaction kinetics of Disperse Blue 79 in the reducing Sediments are biphasic, that is, the initial rapid loss of dye is followed by a much slower rate of transformation. The reaction pathways for the chemical and sediment-mediated reduction of Disperse Blue 79 were quite similar, suggesting that the chemical reduction of such complex chemicals can provide valuable insight into their reaction pathways in environmental systems. For Disperse Blue 79, a number of reaction products resulting from the reduction of both the azo linkage and aromatic nitro groups were formed. The sediment-mediated reduction of BDNA was regioselective resulting in the formation of a 3-bromo-5-nitro-1,2-diaminobenzene, which was further reduced at a much slower rate to B-bromo-1,2,4-triaminobenzene. These results suggest that Disperse Blue 79 and BDNA may undergo reduction in some natural anoxic sediments, resulting in the subsequent release of potentially hazardous aromatic amines to the water column.

  DOI：

  10.1021/es00005a005
• 作为产物：
  描述：

  N-[3-[双(2-羟乙基)氨基]-4-甲氧基苯基]乙酰胺 在 吡啶 、 盐酸 、 硫酸 、 氨基磺酸 、 sodium nitrite 作用下， 以 溶剂黄146 为溶剂， 反应 8.5h， 生成 2-[5-acetamido-N-(2-acetyloxyethyl)-4-[(2-bromo-4,6-dinitrophenyl)diazenyl]-2-methoxyanilino]ethyl acetate
  参考文献：
  名称：

  Thiel, W.; Mayer, R.; Jauer, E.-A., Journal fur praktische Chemie (Leipzig 1954), 1986, vol. 328, # 4, p. 497 - 514

  摘要：

  DOI：

文献信息

• Shading dye and catalyst combination
  申请人：Unilever PLC

  公开号：EP2228429A1

  公开（公告）日：2010-09-15

  The present invention concerns the selection of appropriate conditions in order to permit bleaching of fabric stains whist permitting fabric shading with a dye. The invention provides a laundry detergent composition comprising a peroxyl species, a transition metal complex, a shading dye and a surfactant.

  本发明涉及选择适当的条件，以便既能漂白织物上的污渍，又能用染料使织物着色。本发明提供了一种洗衣粉组合物，其中包括一种过氧物、一种过渡金属络合物、一种遮光染料和一种表面活性剂。
• Optical film, polarizing plate including the same, and liquid crystal display including the same
  申请人：Samsung SDI Co., Ltd.

  公开号：US10824003B2

  公开（公告）日：2020-11-03

  An optical film, a polarizing plate including the same, and a liquid crystal display including the same are provided. The optical film includes a protective layer and a contrast improving layer, wherein the contrast improving layer includes a second resin layer that is stacked from the protective layer, and a first resin layer facing the second resin layer.

  本发明提供了一种光学薄膜、包括该光学薄膜的偏光板以及包括该光学薄膜的液晶显示器。光学薄膜包括保护层和对比度改善层，其中对比度改善层包括从保护层堆叠而成的第二树脂层和面向第二树脂层的第一树脂层。
• Optical film, polarizing plate including the optical film, and liquid crystal display apparatus including the polarizing plate
  申请人：Samsung SDI Co., Ltd.

  公开号：US11493678B2

  公开（公告）日：2022-11-08

  An optical film includes: a protective layer; and a contrast ratio improvement layer including a first resin layer and a second resin layer facing the first resin layer, the second resin layer and the first resin layer being sequentially stacked from a lower surface of the protective layer, wherein the second resin layer has a refractive index greater than that of the first resin layer. The first resin layer has a patterned portion with at least two embossed optical patterns and flat sections immediately adjacent to and between the embossed optical patterns. The patterned section is in at least a portion thereof facing the second resin layer. A polarizing plate including the optical film and a liquid crystal display apparatus including the polarizing plate are also provided.

  一种光学薄膜包括：保护层；以及对比度改进层，包括第一树脂层和与第一树脂层相对的第二树脂层，第二树脂层和第一树脂层从保护层的下表面依次叠加，其中第二树脂层的折射率大于第一树脂层的折射率。第一树脂层有一个带图案的部分，至少有两个压花光学图案，以及紧邻压花光学图案和压花光学图案之间的平面部分。图案部分至少有一部分朝向第二树脂层。此外，还提供了包括该光学薄膜的偏光板和包括该偏光板的液晶显示装置。
• LIN, FUQIN;JIAN, DUNLONG, CHIN. J. APPL. CHEM., 4,(1987) N 5, 62-64
  作者：LIN, FUQIN、JIAN, DUNLONG

  DOI：——

  日期：——
• THIEL W.; MAYER R.; JAUER E.-A.,MODROW H.; DOST H., J. PRAKT. CHEM., 1986, 328, N 4, 497-514
  作者：THIEL W.、 MAYER R.、 JAUER E.-A.,MODROW H.、 DOST H.

  DOI：——

  日期：——