Bis[2-(diethylamino)phenyl]methanone | 34077-98-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis[2-(diethylamino)phenyl]methanone
• CAS: 34077-98-0
• 化学式: C₂₁H₂₈N₂O
• 分子量: 324.5
• InChiKey: DFNPQAXDMQTWAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] POLYMERIZABLE COMPOSITION COMPRISING AN OXIME SULFONATE AS THERMAL CURING AGENT<br/>[FR] COMPOSITION POLYMÉRISABLE COMPRENANT UN SULFONATE D'OXIME EN TANT QU'AGENT DE DURCISSEMENT THERMIQUE
  申请人：BASF SE

  公开号：WO2012101245A1

  公开（公告）日：2012-08-02

  The present invention relates to a polymerizable composition comprising at least one ethylenically unsaturated, polymerizable compound and at least one oxime sulfonate compound of the formula (I) QAaBbCc where a is 0, 1, 2, 3, 4 or 6, b is 0, 1, 2, 3, 4 or 6, and c is 0, 1, 2, 3, 4 or 6, where the sum of a + b + c is 1, 2, 3, 4 or 6 where (A) is a group (B) is a group (C) is a group where # denotes the point of attachment to Q; X is S or NR14 and Q, R1, R2, R3 and R14 are as defined in claim 1 and in the description. The present invention also relates to the use of the this composition, to novel oxime sulfonates and the use of the oxime sulfonates as thermal curing promoter.

  本发明涉及一种可聚合的组成，包括至少一种乙炔基不饱和的可聚合化合物和至少一种具有公式（I）QAaBbCc的亚硝基亚磺酸酯化合物，其中a为0、1、2、3、4或6，b为0、1、2、3、4或6，c为0、1、2、3、4或6，其中a+b+c的总和为1、2、3、4或6，其中（A）是一个基团，（B）是一个基团，（C）是一个基团，其中#表示与Q连接的点；X是S或NR14，Q、R1、R2、R3和R14如权利要求1和说明书中所定义。本发明还涉及使用这种组成物，新型亚硝基亚磺酸酯及其作为热固化促进剂的应用。
• [EN] PROCESS AND INTERMEDIADES FOR THE PREPARATION OF 7-ALKYLATED STEROIDS<br/>[FR] PROCÉDÉ ET INTERMÉDIAIRES POUR LA PRÉPARATION DE STÉROÏDES 7-ALKYLÉS
  申请人：CRYSTAL PHARMA SAU

  公开号：WO2015181116A1

  公开（公告）日：2015-12-03

  A process for preparing compounds of formula (I), or a salt, solvate or stereoisomer thereof, including Fulvestrant, which process comprises free radical to a compound of formula (III), or a salt, solvate or stereoisomer thereof. The invention also refers to intermediates of said process.

  一种制备式(I)化合物的方法，或者其盐、溶剂合物或立体异构体，包括富马酸苯甲酸酯（Fulvestrant）的方法，该方法包括自由基向式(III)化合物转化的步骤，或者其盐、溶剂合物或立体异构体。该发明还涉及所述方法的中间体。
• [EN] 3D IN VITRO MODELS OF LUNG TISSUE<br/>[FR] MODÈLES IN VITRO EN 3D DE TISSU PULMONAIRE
  申请人：UNIV COLORADO REGENTS

  公开号：WO2019136453A1

  公开（公告）日：2019-07-11

  The invention relates to the discovery of tissue mimicking constructs and compositions that can be used to study the growth and development of cells in vitro. In certain embodiments, the invention provides methods of culturing cells on the tissue mimicking polymer microspheres. In other embodiments, the invention provides methods of treating a disease or disorder using the compositions and constructs of the invention.

  该发明涉及发现可以用于体外研究细胞生长和发育的组织模拟构造物和组合物。在某些实施例中，该发明提供了在组织模拟聚合物微球上培养细胞的方法。在其他实施例中，该发明提供了使用该发明的组合物和构造物治疗疾病或疾患的方法。
• [EN] OXIME SULFONATE DERIVATIVES<br/>[FR] DÉRIVÉS DE SULFONATE D'OXIME
  申请人：BASF SE

  公开号：WO2016030790A1

  公开（公告）日：2016-03-03

  Oxime sulfonate compounds of the formula (I), wherein R 1 is O(CO)R 4, COOR 5 or CONR 6R 7; n is 1 or 2; R 2 for example is C 1-C 8alkyl, C 3-C 6cycloalkyl or benzyl; R 3 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 4 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 5 is for example C 3-C 20alkyl, C 3-C 14cycloalkyl, C 2-C 8alkenyl, C 1-C 12alkyl which is substituted for example by one or more halogen; or R 5 is phenyl or naphthyl, which are unsubstituted; R 6 and R 7 each independently of one another for example are hydrogen, C 1-C 12alkyl, C 1-C 4haloalkyl, phenyl-C 1-C 4alkyl, C 2-C 8alkenyl or C 3-C 6cycloalkyl, phenyl or naphthyl; or R 6 and R 7, together with the N-atom to which they are attached, form a 5- or 6-membered ring; are suitable as thermal radical initiators.

  化合物的氧肟磺酸盐，其化学式为（I），其中R1为O（CO）R4，COOR5或CONR6R7; n为1或2; R2例如为C1-C8烷基，C3-C6环烷基或苄基; R3例如为C1-C8烷基，C3-C6环烷基，C1-C8卤代烷基，C2-C8烯基，苄基，苯基或萘基，可以选择性地被取代; R4例如为C1-C8烷基，C3-C6环烷基，C1-C8卤代烷基，C2-C8烯基，苄基，苯基或萘基，可以选择性地被取代; R5例如为C3-C20烷基，C3-C14环烷基，C2-C8烯基，C1-C12烷基，例如被一个或多个卤素取代; 或者R5是未被取代的苯基或萘基; R6和R7各自独立地例如为氢，C1-C12烷基，C1-C4卤代烷基，苯基-C1-C4烷基，C2-C8烯基或C3-C6环烷基，苯基或萘基; 或者R6和R7与它们所连接的N原子一起形成一个5-或6-成员环; 适用于热引发自由基反应剂。
• [EN] HEXAARYLBIIMIDAZOLE COMPOUNDS AND PHOTOPOLYMERIZATION INITIATOR COMPOSITIONS CONTAINING THE SAME<br/>[FR] COMPOSES A BASE D'HEXAARYL-BIIMIDAZOLE, ET COMPOSITIONS INITIATRICES DE PHOTOPOLYMERISATION CONTENANT CE COMPOSE
  申请人：SHOWA DENKO KK

  公开号：WO2004035546A1

  公开（公告）日：2004-04-29

  The present invention provides a novel hexaarylbiimidazole compound of the following formula (1): wherein each R1 represents a halogen, and each R2 represents an optionally substituted C1-4 alkyl group. The hexaarylbiimidazole compound of the present invention is useful as photoradical generators in photopolymerizable compositions used as resists and is characterized by low sublimating thermal decomposition products. The photopolymerizable compositions may be suitably used as resists or as color filters for color liquid crystal display elements, cameras and the like.

  本发明提供了一种新型的六芳基联双咪唑化合物，其化学式为（1），其中每个R1代表卤素，每个R2代表可选取代的C1-4烷基基团。本发明的六芳基联双咪唑化合物可用作光致自由基发生剂，用于光聚合组合物中作为抗蚀剂，并具有低升华热分解产物的特点。光聚合组合物可适当地用作抗蚀剂或彩色液晶显示元件、相机等的彩色滤光片。