N,N-diallyl-2-naphthylamine | 30438-98-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N-diallyl-2-naphthylamine
• 英文别名: N,N-bis(prop-2-enyl)naphthalen-2-amine
• CAS: 30438-98-3
• 化学式: C₁₆H₁₇N
• 分子量: 223.318
• InChiKey: ZZURQXMOTMKKTI-UHFFFAOYSA-N

物化性质

• 沸点：
  362.3±31.0 °C(Predicted)
• 密度：
  1.025±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-diallyl-2-naphthylamine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 乙腈 为溶剂， 以85%的产率得到N,N-diallyl-1-bromonaphthalen-2-amine
  参考文献：
  名称：

  10.1055/3-0028-1083311

  摘要：

  DOI：

  10.1055/3-0028-1083311
• 作为产物：
  描述：

  对甲苯磺酸烯丙酯 、 2-萘胺 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 生成 N,N-diallyl-2-naphthylamine
  参考文献：
  名称：

  Vizgert,R.V. et al., Soviet progress in chemistry, 1970, vol. 36, # 8, p. 57 - 59

  摘要：

  DOI：

文献信息

• Direct palladium(0)-catalyzed amination of allylic alcohols with aminonaphthalenes
  作者：Yi-Jen Shue、Shyh-Chyun Yang、Hwe-Chen Lai

  DOI：10.1016/s0040-4039(02)02861-7

  日期：2003.2

  The direct activation of CO bonds in allylic alcohols by palladium complexes has been accelerated by carrying out the reactions in the presence of titanium reagents. The palladium-catalyzed amination of allylic alcohols using aminonaphthalenes gave N-allylic naphthylamines in good yields. The monoallylation products are formed in the main.

  通过在钛试剂的存在下进行反应，已经加速了钯配合物在烯丙基醇中对CO键的直接活化。使用氨基萘的钯催化的烯丙基醇的胺化以良好的收率得到了N-烯丙基萘胺。单烯丙基化产物在主体中形成。
• PEG-4000-promoted palladium-catalyzed <i>N</i> -allylation in water: aminonaphthalene as an example
  作者：Chun-Jen Shih、Yi-Jen Shue、Shiang-Yu Yang、Shyh-Chyun Yang

  DOI：10.1002/aoc.2899

  日期：2012.10

  process using palladium associated with ligands in a PEG4000–water system leading to N‐allylation was described in this study. PEG‐4000 was found to improve the palladium‐catalyzed allylic amination of allylic acetates with aminonaphthalenes and gave overall good to high yields of the corresponding N‐allylic aminonaphthalenes. Copyright © 2012 John Wiley & Sons, Ltd.

  在这项研究中描述了一种环境友好，高效的催化过程，该过程使用钯与PEG4000-水系统中的配体缔合，从而导致N-烯丙基化。发现PEG-4000可以改善钯催化的烯丙基乙酸酯与氨基萘的烯丙基胺化反应，并且可以使相应的N-烯丙基氨基萘的收率总体提高。版权所有©2012 John Wiley＆Sons，Ltd.
• Cobalt-Catalyzed Cycloisomerization of N,N-Diallylanilines
  作者：Jun Liu、Zhanhui Yang、Minfang Zheng、Hongfei Wu、Ning Chen、Jiaxi Xu

  DOI：10.1055/s-0037-1611832

  日期：2019.9

  efficient bench-stable catalysts for the oligomerization of ethylenes. Herein, their further application was developed in the catalytic transformation of N,N-diallylanilines to pyrrolidines through a cycloisomerization process. In this protocol, chlorobenzene is a vital additive to promote reaction efficiency. Cobalt catalysts bearing 2-imino-1,10-phenanthroline ligands are quite efficient bench-stable catalysts

  抽象的 带有2-亚氨基-1，10-菲咯啉配体的钴催化剂是用于乙烯低聚的非常有效的台稳催化剂。在本文中，它们的进一步应用被开发为通过环异构化过程将N，N-二烯丙基苯胺催化转化为吡咯烷。在该协议中，氯苯是提高反应效率的重要添加剂。 带有2-亚氨基-1，10-菲咯啉配体的钴催化剂是用于乙烯低聚的非常有效的台稳催化剂。在本文中，它们的进一步应用被开发为通过环异构化过程将N，N-二烯丙基苯胺催化转化为吡咯烷。在该协议中，氯苯是提高反应效率的重要添加剂。
• Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates
  作者：Shyh-Chyun Yang、Wei-Hao Feng、Kim-Hong Gan

  DOI：10.1016/j.tet.2006.01.023

  日期：2006.4

  The activation of C-O bonds in allylic acetates has been accelerated by carrying out the reactions in the presence of platinum complexes associated with ligands. Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates leads to N-allylic aminonaphthalenes in good yields. (c) 2006 Elsevier Ltd. All rights reserved.
• Platinum-catalyzed allylation of aminonaphthalenes with allylic acetates in water
  作者：Kim-Hong Gan、Ciou-Jyu Jhong、Yi-Jen Shue、Shyh-Chyun Yang

  DOI：10.1016/j.tet.2008.07.037

  日期：2008.9

  The activation of C-O bonds in allylic acetates in water as a suspension medium has been accelerated by carrying out the reactions in the presence of platinum complexes associated with ligands. The platinum-catalyzed allylation of aminonaphthalenes using allylic acetates gave the corresponding N-allylic aminonaphthalenes in good yields. (C) 2008 Elsevier Ltd. All rights reserved.