2,5-dimethyl-tetrahydro-cyclobuta[1,2-c;3,4-c']dipyrrole-1,3,4,6-tetraone | 35946-59-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酰胺类
• 英文名称: 2,5-dimethyl-tetrahydro-cyclobuta[1,2-c;3,4-c']dipyrrole-1,3,4,6-tetraone
• 英文别名: Cyclobutan-1,2,3,4-tetracarbonsaeure-di-methylimid；4,9-Dimethyl-4,9-diazatricyclo[5.3.0.02,6]decane-3,5,8,10-tetrone
• CAS: 35946-59-9
• 化学式: C₁₀H₁₀N₂O₄
• 分子量: 222.2
• InChiKey: QZQSTLPPSAJBCR-UHFFFAOYSA-N

物化性质

• 沸点：
  470.0±45.0 °C(Predicted)
• 密度：
  1.505±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,5-dimethyl-tetrahydro-cyclobuta[1,2-c;3,4-c']dipyrrole-1,3,4,6-tetraone 在 lithium aluminium tetrahydride 作用下， 以 甲醇 、 乙醚 为溶剂， 反应 152.0h， 生成 N,N,N',N'-tetramethyldecahydrocyclobuta[1,2-c;3,4-c']dipyrrolidinium
  参考文献：
  名称：

  Synthesis and Structure of the Bidimensional Zeolite ITQ-32 with Small and Large Pores

  摘要：

  A new bidimensional zeolite containing 8R and 12R pores, denoted as ITQ-32, has been synthesized and its structure solved from powder X-ray diffraction data. This zeolite presents a relatively large pore volume (0.16 cm3/g) and pore apertures of 3.5 x 4.3 A and can be prepared as a nearly pure silica zeolite and as aluminosilicate. In the latest case, acidic properties are developed.

  DOI：

  10.1021/ja053040h
• 作为产物：
  描述：

  N-甲基马来酰亚胺 在 9-噻吨酮 、 2-(phenylethynyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 作用下， 以 乙腈 为溶剂， 生成 2,5-dimethyl-tetrahydro-cyclobuta[1,2-c;3,4-c']dipyrrole-1,3,4,6-tetraone
  参考文献：
  名称：

  炔基硼酸酯的光化学[2+2]环加成反应

  摘要：

  炔基硼酸酯和马来酰亚胺的光化学[2+2]环加成被描述为合成具有多种官能团的多取代硼基化环丁烯的简便方法。所得产品的物理化学和结构特性为其作为邻苯二甲酰亚胺等排替代品（例如沙利度胺）的应用提供了理论依据。机理研究证实，[2+2]环加成是通过马来酰亚胺组分的初始激发进行的。

  DOI：

  10.1002/chem.202301650

文献信息

• METHOD FOR PREPARING A POLY(ETHER SULFONIMIDE OR -AMIDE) COPOLYMER USING CYCLIC OLIGOMERS
  申请人：Kim Yong Seok

  公开号：US20130053530A1

  公开（公告）日：2013-02-28

  Disclosed is a method for preparing a poly(ethersulfonimide or ethersulfonamide) copolymer using cyclic oligomers, and more particularly, to a method for preparing a poly(ethersulfonimide or ethersulfonamide) copolymer by preparing a cyclic ether sulfone oligomer and a cyclic imide or amide oligomer and subjecting the cyclic ether sulfone oligomer and the cyclic imide or amide oligomer to ring-opening copolymerization in the presence of an alkali metal fluoride catalyst.

  本发明公开了一种使用环状寡聚体制备聚醚砜亚胺或醚砜酰胺共聚物的方法，更具体地，本发明公开了一种通过制备环状醚砜酮寡聚体和环状亚胺或酰胺寡聚体，并在碱金属氟化物催化剂存在下将环状醚砜酮寡聚体和环状亚胺或酰胺寡聚体进行开环共聚合制备聚醚砜亚胺或醚砜酰胺共聚物的方法。
• Polymers for use as alignment layers in liquid crystal devices
  申请人：Komitov Lachezar

  公开号：US20070088125A1

  公开（公告）日：2007-04-19

  The invention relates to a polymer for use as a surface-director alignment layer in a liquid crystal device, the polymer comprising a polymeric backbone and side-chains attached thereto, wherein the polymeric backbone lacks directly coupled ring structures, and each side-chain of at least some of the side-chains comprises at least two unsubstituted and/or substituted phenyls coupled via a coupling selected from the group consisting of a carbon-carbon single bond (—), a carbon-carbon double bond containing unit (—CH═CH—), a carbon-carbon triple bond containing unit (—C≡C—), a methylene ether unit (—CH 2 O—), an ethylene ether unit (—CH 2 CH 2 O—), an ester unit (—COO—) and an azo unit (—N═N—), exhibits a permanent and/or induced dipole moment that in ordered phase provides dielectric anisotropy, and is attached to the polymeric backbone via at least two spacing atoms.

  本发明涉及一种用作液晶器件表面定向层的聚合物，该聚合物包括聚合骨架和连接在其上的侧链，其中聚合骨架缺乏直接耦合的环结构，至少某些侧链的每个侧链包括至少两个未取代和/或取代的苯基，通过从由碳-碳单键(—)、含有碳-碳双键单元(—CH═CH—)、含有碳-碳三键单元(—C≡C—)、甲基醚单元(—CH2O—)、乙烯醚单元(—CH2CH2O—)、酯单元(—COO—)和偶氮单元(—N═N—)组成的耦合中的一种与之耦合，在有序相中表现出永久和/或感应偶极矩，通过至少两个间隔原子连接到聚合骨架上。
• Liquid crystal display and manufacturing method thereof
  申请人：Samsung Display Co., Ltd.

  公开号：US10197865B2

  公开（公告）日：2019-02-05

  A manufacturing method of a liquid crystal display, including: applying a photoalignment agent on a substrate; baking the applied photoalignment agent; forming a photoalignment layer by irradiating the baked photoalignment agent with polarized light; baking the photoalignment layer; and removing at least one decomposed unit by cleaning the baked photoalignment layer using a cleaning solution including at least one of propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, or ethyl lactate.

  一种液晶显示器的制造方法，包括：在基板上涂敷光配位剂；烘烤涂敷的光配位剂；用偏振光照射烘烤的光配位剂形成光配位层；烘烤光配位层；使用包括丙二醇单甲醚、丙二醇单甲醚乙酸酯或乳酸乙酯中至少一种的清洗液清洗烘烤的光配位层，去除至少一个分解单元。
• Quantum rod layer, method of fabricating the same and display device including the same
  申请人：LG DISPLAY CO., LTD.

  公开号：US10795207B2

  公开（公告）日：2020-10-06

  An example of the present invention provides a quantum rod layer including: a photo-induced polymer including a base polymer aligned along a first direction and a photo-reactive group combined to the base polymer; and a quantum rod aligned along the first direction.

  本发明的一个实例提供了一种量子棒层，包括：光诱导聚合物，包括沿第一方向排列的基底聚合物和与基底聚合物结合的光反应基团；以及沿第一方向排列的量子棒。
• Photoalignment agent and liquid crystal display device including the same
  申请人：Samsung Display Co., Ltd.

  公开号：US11029568B2

  公开（公告）日：2021-06-08

  A photoalignment agent is provided. The photoalignment agent includes a copolymer of ii) at least one of a cyclobutanedianhydride (CBDA) and a cyclobutanedianhydride (CBDA) derivative, and ii) a diamine, and the diamine includes an electron donor group.

  提供了一种光配位剂。光配位剂包括以下物质的共聚物：ii) 环丁烷二酸酐（CBDA）和环丁烷二酸酐（CBDA）衍生物中的至少一种；ii) 二胺，二胺包括电子供体基团。