An object of the present invention is to provide a solid polymer electrolyte membrane in which a polyazole-based compound is uniformly mixed with a perfluorocarbonsulfonic acid resin. Thus, the present invention provides a solid polymer electrolyte membrane for solid polymer electrolyte fuel cell, which has high durability, as well as a membrane electrode assembly and a solid polymer electrolyte fuel cell, each containing the same.
The inventive solid polymer electrolyte membrane is produced by a method which comprises a polymer electrolyte-containing solution preparation step of dissolving a perfluorocarbonsulfonic acid resin (component A) having an ion-exchange capacity of 0.5 to 3.0 meq/g, a polyazole-based compound (component B) and an alkali metal hydroxide in a protic solvent to prepare a polymer electrolyte-containing solution in which a weight ratio of the component A to component B, (A/B), is from 2.3 to 199 and a total weight of the component A and the component B is from 0.5 to 30% by weight; and a membrane formation step of forming a membrane from the polymer electrolyte-containing solution.
本发明的目的是提供一种固体聚合物电解质膜,其中将聚唑基化合物与
全氟碳
磺酸树脂均匀混合。因此,本发明提供了一种用于固体聚合物电解质燃料电池、具有高耐久性的固体聚合物电解质膜,以及一种膜电极组件和一种固体聚合物电解质燃料电池,每一种都含有相同的膜电极组件和固体聚合物电解质燃料电池。
本发明的固体聚合物电解质膜的生产方法包括含聚合物电解质溶液的制备步骤:将离子交换容量为 0.5 至 3.0 meq/g的
全氟羧基
磺酸树脂(组分A)、聚唑基化合物(组分B)和碱
金属氢氧化物溶解在质子溶剂中,制备含聚合物电解质的溶液,其中组分A和组分B的重量比(A/B)为2.3至199,组分A和组分B的总重量为0.5至30%(重量比);以及膜形成步骤,从含聚合物电解质的溶液中形成膜。