[amino(diphenyl)-λ5-phosphanyl]benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [amino(diphenyl)-λ5-phosphanyl]benzene
• 化学式: C₁₈H₁₈NP
• 分子量: 279.3
• InChiKey: XPADSAQJRICUAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• [EN] METAL-LIGAND COMPLEXES AND CATALYSTS<br/>[FR] COMPLEXES MÉTAL-LIGAND ET CATALYSEURS
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2011102989A1

  公开（公告）日：2011-08-25

  The present invention generally relates to metal-ligand complexes, catalysts comprising or prepared from the metal-ligand complexes, processes of catalyzing olefin polymerization reactions with the catalysts to prepare polyolefins, polyolefins prepared thereby, processes of making the metal-ligand complexes and catalysts, and intermediate compounds useful therefor.

  本发明通常涉及金属配体络合物，包含或由金属配体络合物制备的催化剂，使用这些催化剂催化烯烃聚合反应以制备聚烯烃的过程，由此制备的聚烯烃，制备金属配体络合物和催化剂的过程，以及有用的中间化合物。
• [EN] CHIRAL IMIDODIPHOSPHATES AND DERIVATIVES THEREOF<br/>[FR] IMIDODIPHOSPHATES CHIRAUX ET DÉRIVÉS ASSOCIÉS
  申请人：STUDIENGESELLSCHAFT KOHLE MBH

  公开号：WO2013104604A1

  公开（公告）日：2013-07-18

  The invention relates to chiral imidodiphosphates and derivatives thereof having the general formula I, The compounds are suitable as chiral Brønsted acid catalysts, phase-transfer catalysts, chiral anions for organic salts, metal salts or metal complexes for catalysis.

  该发明涉及具有一般式I的手性咪唑二磷酸酯及其衍生物。这些化合物适用作为手性Brønsted酸催化剂、相转移催化剂、有机盐、金属盐或金属络合物的手性阴离子，用于催化。
• METAL-LIGAND COMPLEXES AND CATALYSTS
  申请人：Klosin Jerzy

  公开号：US20110207902A1

  公开（公告）日：2011-08-25

  The present invention generally relates to metal-ligand complexes, catalysts comprising or prepared from the metal-ligand complexes, processes of catalyzing olefin polymerization reactions with the catalysts to prepare polyolefins, polyolefins prepared thereby, processes of making the metal-ligand complexes and catalysts, and intermediate compounds useful therefor.

  本发明一般涉及金属配体络合物，包括或由金属配体络合物制备的催化剂，使用这些催化剂催化烯烃聚合反应制备聚烯烃的过程，由此制备的聚烯烃，制备金属配体络合物和催化剂的过程，以及用于此目的的中间化合物。
• DERIVATIVES OF HYPOCRELLIN WITH PERI-POSITION AND 2-POSITION SIMULTANEOUSLY SUBSTITUTED BY AMINO GROUPS
  申请人：Technical Institute of Physics and Chemistry of the Chinese Academy of Sciences

  公开号：EP3680230A1

  公开（公告）日：2020-07-15

  The present invention discloses a hypocrellin derivative substituted both in a peri-position and in a 2-position by an amino, and a preparation method and use thereof. A general structural formula of the derivative is as represented by formulas I-a to I-d: The hypocrellin derivative substituted both in a peri-position and in a 2-position by an amino prepared in the present invention has a maximum absorption wavelength of 600-650 nm and a molar extinction coefficient reaching about 20000-40000 M-1cm-1. Compared with unmodified hypocrellin or hypocrellin having only a 2-position modified, an absorption spectrum of the derivative is significantly red-shifted and the molar extinction coefficient is greatly improved, and the derivative can efficiently produce reactive oxygen species such as singlet oxygen in a photosensitive condition. In the same condition, the hypocrellin derivative substituted both in a peri-position and in a 2-position by an amino involved in the present invention, when used as a photosensitizer, has a stronger ability to photo-dynamically inactivate tumor cells than the first and second generation commercial photosensitizers.

  本发明公开了一种在周位和 2 位均被氨基取代的次黄嘌呤衍生物及其制备方法和用途。该衍生物的一般结构式如式 I-a 至 I-d 所示： 本发明制备的在周位和 2 位被氨基取代的次黄嘌呤衍生物的最大吸收波长为 600-650 nm，摩尔消光系数约为 20000-40000 M-1cm-1。与未修饰的次黄嘌呤或仅修饰了 2 位的次黄嘌呤相比，该衍生物的吸收光谱明显红移，摩尔消光系数大大提高，在光敏条件下能有效地产生活性氧，如单线态氧。在相同的条件下，本发明中被氨基取代了周位和 2 位的次黄嘌呤衍生物在用作光敏剂时，与第一代和第二代商业光敏剂相比，具有更强的光动力灭活肿瘤细胞的能力。
• Conjugated alkadiene telomerization to organo-oxyalkadienes
  申请人：QUANTUM CHEMICAL CORPORATION (a Virginia corp.)

  公开号：EP0218100B1

  公开（公告）日：1989-11-29