(6-Pentylpyridin-2-yl)methanamine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (6-Pentylpyridin-2-yl)methanamine
• 化学式: C₁₁H₁₈N₂
• 分子量: 178.27
• InChiKey: RULWLRUCUWPJGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  38.9
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• LIGANDS OF THE BENZO [H] QUINOLINE CLASS AND TRANSITION METAL COMPLEXES CONTAINING THEM AND USE OF SAID COMPLEXES AS CATALYSTS
  申请人：Rigo Pierluigi

  公开号：US20100152448A1

  公开（公告）日：2010-06-17

  A new class of ligands derived from benzo[h]quinoline are described and these ligands are used to prepare several novel transition metal complexes. The complexes are preferably of the group VIII transition metals iron, ruthenium or osmium, with the benzo[h]quinoline ligands acting as tridentate ligands. The complexes described are proved to be very active catalysts for the reduction of ketones and aldehydes to alcohols, via hydrogen transfer and hydrogenation reactions. These compounds hence can be usefully employed as catalysts in said reduction reactions.

  描述了一类源自苯并[h]喹啉的新型配体，并利用这些配体制备了几种新型过渡金属配合物。这些配合物优选为第VIII族过渡金属铁、钌或锇，其中苯并[h]喹啉配体作为三齿配体。所描述的配合物证明是非常有效的催化剂，用于通过氢转移和氢化反应将酮和醛还原为醇。因此，这些化合物可以有效地用作上述还原反应的催化剂。
• NEW LIGANDS OF THE BENZO[H]QUINOLINE CLASS AND TRANSITION METAL COMPLEXES CONTAINING THEM AND USE OF SAID COMPLEXES AS CATALYSTS
  申请人：Rigo Pierluigi

  公开号：US20140179923A1

  公开（公告）日：2014-06-26

  A new class of ligands derived from benzo[h]quinoline are described and these ligands are used to prepare several novel transition metal complexes. The complexes are preferably of the group VIII transition metals iron, ruthenium or osmium, with the benzo[h]quinoline ligands acting as tridentate ligands. The complexes described are proved to be very active catalysts for the reduction of ketones and aldehydes to alcohols, via hydrogen transfer and hydrogenation reactions. These compounds hence can be usefully employed as catalysts in said reduction reactions.

  本文描述了一种新型的苯并[h]喹啉配体，并利用这些配体制备了几种新型的过渡金属配合物。这些配合物通常由VIII族过渡金属铁、钌或锇组成，其中苯并[h]喹啉配体作为三齿配体。所述的配合物被证明是催化酮和醛还原为醇的非常活跃的催化剂，通过氢转移和氢化反应实现。因此，这些化合物可以作为还原反应中有用的催化剂。
• Ligands of the benzo [H] quinoline class and transition metal complexes containing them and use of said complexes as catalysts
  申请人：UNIVERSITA' DEGLI STUDI DI UDINE

  公开号：US10010880B2

  公开（公告）日：2018-07-03

  A new class of ligands derived from benzo[h]quinoline are described and these ligands are used to prepare several novel transition metal complexes. The complexes are preferably of the group VIII transition metals iron, ruthenium or osmium, with the benzo[h]quinolone ligands acting as tridentate ligands. The complexes described are proved to be very active catalysts for the reduction of ketones and aldehydes to alcohols, via hydrogen transfer and hydrogenation reactions. These compounds hence can be usefully employed as catalysts in said reduction reactions.

  本文描述了一类由苯并[h]喹啉衍生的新配体，并利用这些配体制备了几种新型过渡金属配合物。这些配合物最好是第八族过渡金属铁、钌或锇的配合物，苯并[h]喹啉配体作为三叉配体。事实证明，所述配合物是非常活跃的催化剂，可通过氢转移和氢化反应将酮和醛还原成醇。因此，这些化合物可在上述还原反应中用作催化剂。
• NEW LIGANDS OF THE BENZO[H]QUINOLINE CLASS AND TRANSITION METAL COMPLEXES CONTAINING THEM AND USE OF SAID COMPLEXES AS CATALYST
  申请人：Universita' Degli Studi di Udine

  公开号：EP2178843B1

  公开（公告）日：2013-12-11
• US8614322B2
  申请人：——

  公开号：US8614322B2

  公开（公告）日：2013-12-24