S-(Thiobenzoyl)-thioglycolsaeure-ethylester | 129841-38-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-(Thiobenzoyl)-thioglycolsaeure-ethylester
• 英文别名: Ethyl 2-(benzenecarbonothioylsulfanyl)acetate
• CAS: 129841-38-9
• 化学式: C₁₁H₁₂O₂S₂
• 分子量: 240.347
• InChiKey: ZGKHIABFSFTKRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  83.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  S-(Thiobenzoyl)-thioglycolsaeure-ethylester 、 硫代异氰酸苯酯 、 碘甲烷 生成 4-Methylthio-2-oxo-1-phenyl-3-thiobenzoylthio-1,2-dihydroazete
  参考文献：
  名称：

  Doelling, Wolfgang; Vogt, Almut; Sperk, Katrin, Synthesis, 1990, # 7, p. 621 - 623

  摘要：

  DOI：

文献信息

• Vicinal difunctionalization of alkenes by four-component radical cascade reaction of xanthogenates, alkenes, CO, and sulfonyl oxime ethers
  作者：Shuhei Sumino、Takahide Fukuyama、Mika Sasano、Ilhyong Ryu、Antoine Jacquet、Frédéric Robert、Yannick Landais

  DOI：10.3762/bjoc.15.176

  日期：——

  Four-component coupling reactions between xanthogenates, alkenes, CO, and sulfonyl oxime ethers were studied. In the presence of hexabutylditin, working as a propagating radical reagent, the chain reaction proceeds, as expected, taking into account reagents polarities, affording the corresponding functionalized α-keto oximes. Although yields are modest, this rare one-pot four-component process is easy

  研究了黄原酸酯，烯烃，CO和磺酰肟醚之间的四组分偶联反应。在六丁基二锡的作用下，作为繁殖的自由基试剂，考虑到试剂的极性，按预期进行链式反应，得到相应的官能化的α-酮肟。尽管收率不高，但是这种罕见的一锅四组分工艺很容易进行，所得到的具有多种功能的化合物具有进一步加工的潜力。
• Process for the preparation of graft copolymers by Reversible Addition Fragmentation Chain Transfer (RAFT) and Ring Opening Polymerisation (ROP)
  申请人：Polymers Australia PTY Limited

  公开号：EP1950232A1

  公开（公告）日：2008-07-30

  A combined RAFT/ROP process for the preparation of a graft co-polymer having a backbone built-up from repeating units derived by polymerization of free-radically polymerizable monomers comprising vinylic monomers, and polyester side chains grafted to said backbone derived by ring-opening polymerisation of cyclic ester compounds; said process comprising reacting a mixture of (a) one or more vinylic monomers, optionally in combination with other monomers susceptible to free-radical polymerization, wherein at least one of said vinylic monomers comprises a (free) hydroxyl group; (b) a thiocarbonylthio compound as chain transfer agent; (c) one or more cyclic esters, which is/are susceptible to a ring-opening polymerization; and (d) a compound effective for initiating the ring-opening polymerization of the one or more cyclic esters; and reacting said mixture in an inert solvent at a temperature of more than 90°C under exclusion of oxygen to form the graft copolymer.

  一种结合了RAFT/ROP过程的方法，用于制备一种接枝共聚物，其骨架由通过自由基聚合获得的重复单元构建，包括乙烯单体，并且由环酯化合物的环开聚合衍生的聚酯侧链嫁接到该骨架上；该方法包括反应以下混合物：(a) 一种或多种乙烯单体，可选地与其他易于自由基聚合的单体组合在一起，其中至少一种乙烯单体包含一个（自由）羟基；(b) 一种硫代羰基硫化合物作为链转移剂；(c) 一种或多种易于环开聚合的环酯；以及(d) 一种有效于启动一种或多种环酯的环开聚合的化合物；并在惰性溶剂中，在排除氧气的条件下，以高于90°C的温度反应该混合物，以形成接枝共聚物。
• RESIST COMPOSITION AND PATTERN-FORMING METHOD USING SAME
  申请人：Kamimura Sou

  公开号：US20080241737A1

  公开（公告）日：2008-10-02

  A resist composition comprises (A) at least two kinds of resins each of which decomposes by the action of an acid to undergo an increase in its solubility for an alkali developer, wherein at least one kind of the resins (A) is a resin synthesized by living radical polymerization using a chain transfer agent represented by formula (I): wherein: A represents an organic group not containing hetero atoms; and Y represents an organic group capable of releasing a radical.

  一种抗蚀性组合物包括（A）至少两种树脂，每种树脂通过酸的作用分解，以增加其对碱性显影剂的溶解度，其中至少一种树脂（A）是通过使用由式（I）表示的链转移剂合成的活性自由基聚合树脂：其中：A代表不含杂原子的有机基团；Y代表能够释放自由基的有机基团。
• Resist composition and pattern-forming method using same
  申请人：FUJIFILM Corporation

  公开号：EP1972641A2

  公开（公告）日：2008-09-24

  A resist composition comprises (A) at least two kinds of resins each of which decomposes by the action of an acid to undergo an increase in its solubility for an alkali developer, wherein at least one kind of the resins (A) is a resin synthesized by living radical polymerization using a chain transfer agent represented by formula (I): wherein: A represents an organic group not containing hetero atoms; and Y represents an organic group capable of releasing a radical.

  一种抗蚀剂组合物包括 (A) 至少两种树脂，每种树脂在酸的作用下分解，对碱显影剂的溶解度增加，其中至少一种树脂 (A) 是使用由式 (I) 表示的链转移剂通过活自由基聚合合成的树脂： 其中 A 代表不含杂原子的有机基团；以及 Y 代表能够释放自由基的有机基团。
• DOLLING, WOLFGANG;VOGT, ALMUT;SPERK, KATRIN;AUGUSTIN, MANFRED, SYNTHESIS (BRD),(1990) N, C. 621-623
  作者：DOLLING, WOLFGANG、VOGT, ALMUT、SPERK, KATRIN、AUGUSTIN, MANFRED

  DOI：——

  日期：——