O-methyl O-octyl thiocarbonate | 1051374-75-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 英文名称: O-methyl O-octyl thiocarbonate
• 英文别名: Methoxy(octoxy)methanethione
• CAS: 1051374-75-4
• 化学式: C₁₀H₂₀O₂S
• 分子量: 204.334
• InChiKey: GOCFCSXCSNLKMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  O-methyl O-octyl thiocarbonate 在 三氟化溴 作用下， 以 氯仿 为溶剂， 生成 1-[二氟(甲氧基)甲氧基]辛烷 、 碳酸甲基辛酯
  参考文献：
  名称：

  Constructing the OCF₂O Moiety Using BrF₃

  摘要：

  A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF(3). The fluorination step is complete in seconds with moderate to high yields under mild conditions.

  DOI：

  10.1021/jo801116n
• 作为产物：
  描述：

  甲醇 、 硫代氯甲酸-O-辛酯 在 三乙胺 作用下， 反应 1.0h， 以80%的产率得到O-methyl O-octyl thiocarbonate
  参考文献：
  名称：

  Constructing the OCF₂O Moiety Using BrF₃

  摘要：

  A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF(3). The fluorination step is complete in seconds with moderate to high yields under mild conditions.

  DOI：

  10.1021/jo801116n

文献信息

• Composition, article and their production method, and film and its production method
  申请人：Fujifilm Corporation

  公开号：EP2025711A1

  公开（公告）日：2009-02-18

  A composition comprising an organic crystal having a minor axis length of from 3 to 100 nm and a major axis length of from 10 to 2, 000 nm and a matrix material, wherein the organic crystal satisfies that (1) a surfactant is adsorbed on the organic crystal, (2) an inorganic ion is adsorbed on the organic crystal, (3) silicon oxide, titanium oxide, aluminum oxide, zirconium oxide, barium oxide or hydroxyapatite is bonded with the organic crystal, or (4) the organic crystal is modified with a group represented by the following formula (1): wherein L1 represents -O-, -S-, -CO- or others, n is 0 to 4, and R1 represents an organic group.

  一种组合物，包括小轴长度为3至100纳米、大轴长度为10至2000纳米的有机晶体和基体材料，其中有机晶体满足以下条件：(1) 有机晶体上吸附有表面活性剂；(2) 有机晶体上吸附有无机离子；(3) 氧化硅、氧化钛、氧化铝、氧化锆、氧化钡或羟基磷灰石与基体材料结合、(2) 有机晶体上吸附了无机离子； (3) 有机晶体上粘结了氧化硅、氧化钛、氧化铝、氧化锆、氧化钡或羟基磷灰石；或 (4) 有机晶体被下式(1)所代表的基团修饰： 其中 L1 代表-O-、-S-、-CO-或其他，n 为 0 至 4，R1 代表有机基团。
• COMPOSITION, ARTICLE AND THEIR PRODUCTION METHOD, AND FILM AND ITS PRODUCTION METHOD
  申请人：Takamoto Tetsufumi

  公开号：US20090029169A1

  公开（公告）日：2009-01-29

  A composition comprising an organic crystal having a minor axis length of from 3 to 100 nm and a major axis length of from 10 to 2,000 nm and a matrix material, wherein the organic crystal satisfies that (1) a surfactant is adsorbed on the organic crystal, (2) an inorganic ion is adsorbed on the organic crystal, (3) silicon oxide, titanium oxide, aluminum oxide, zirconium oxide, barium oxide or hydroxyapatite is bonded with the organic crystal, or (4) the organic crystal is modified with a group represented by the following formula (1): wherein L 1 represents —O—, —S—, —CO— or others, n is 0 to 4, and R 1 represents an organic group.
• US7829609B2
  申请人：——

  公开号：US7829609B2

  公开（公告）日：2010-11-09