5-(2-Bromoethyl)bicyclo[2.2.1]hept-2-ene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 5-(2-Bromoethyl)bicyclo[2.2.1]hept-2-ene
• 化学式: C₉H₁₃Br
• 分子量: 201.1
• InChiKey: YXAGTBGHRQGFLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Process for forming perfluorinated-alkyl sulfonamide substituted norbornene-type monomers
  申请人：Bell Andrew

  公开号：US20080027246A1

  公开（公告）日：2008-01-31

  Embodiments in accordance with the present invention are directed to providing processes for forming fluorinated-alkyl and particularly perfluorinated-alkyl sulfonamide substituted norbornene-type monomers.

  本发明实施例涉及提供用于形成氟化烷基和特别是全氟烷基磺酰胺取代的诺博烯型单体的过程。
• [EN] METATHESIS POLYMERIZATION METHODS<br/>[FR] PROCÉDÉS DE POLYMÉRISATION PAR MÉTATHÈSE
  申请人：UNIV WASHINGTON

  公开号：WO2016036976A1

  公开（公告）日：2016-03-10

  The present disclosure is directed to methods of making a polymer, including exposing a reaction mixture including a strained cyclic unsaturated monomer and an organic initiator to a stimulus to provide an activated organic initiator, whereby the activated organic initiator is effective to polymerize the strained cyclic unsaturated monomer via a 4-membered carbocyclic intermediate to provide a polymer having constitutional units derived from the strained cyclic unsaturated monomer.

  本公开涉及制备聚合物的方法，包括将含有紧张的环状不饱和单体和有机引发剂的反应混合物暴露于刺激物中，以提供活性有机引发剂，通过4元环碳中间体，使活性有机引发剂有效地聚合紧张的环状不饱和单体，从而提供由紧张的环状不饱和单体导出的构成单元的聚合物。
• Functional norbornenes and polymeric derivatives and fabrication thereof
  申请人：Liaw Der-Jang

  公开号：US20070173609A1

  公开（公告）日：2007-07-26

  The present invention relates to novel functional norbornenes as initiators for radical polymerization, its polymer and a process for producing the same. More particularly, the novel functional norbornenes can be selectively polymerized by ring-opening metathesis polymerization or radical polymerization to obtain various polynorbornene derivatives or grafted copolymer materials. The polynorbornene derivatives and grafted copolymer materials not only exhibit excellent functional properties but also enhanced physical and chemical properties after modification. The polynorbornene derivatives and grafted copolymer materials disclosed in the present invention exhibit excellent heat resistance, transparency and water resistance. The present invention also deals with a process for producing such derivatives and materials having controllable molecular weight with narrow molecular weight distribution.

  本发明涉及一种新型的功能性诺伯烯作为自由基聚合引发剂，以及其聚合物和制备方法。更具体地说，这些新型的功能性诺伯烯可以通过开环重排聚合或自由基聚合选择性地聚合，以获得各种聚诺伯烯衍生物或接枝共聚物材料。这些聚诺伯烯衍生物和接枝共聚物材料不仅具有优异的功能性能，而且在改性后还具有增强的物理和化学性能。本发明所披露的聚诺伯烯衍生物和接枝共聚物材料具有优异的耐热性、透明度和耐水性。本发明还涉及一种制备具有可控分子量和窄分子量分布的这些衍生物和材料的方法。
• NORBORNENE-TYPE POLYMERS HAVING QUATERNARY AMMONIUM FUNCTIONALITY
  申请人：Bell Andrew

  公开号：US20110143260A1

  公开（公告）日：2011-06-16

  Embodiments of the present disclosure encompass vinyl addition and ROMP polymers having at least one type of repeating unit that encompasses a comprise N + (CH 3 ) 3 OH − moiety. Other embodiments in accordance with the disclosure include alkali anion-exchange membranes (AAEMs) made from one of such polymers, anion fuel cells (AFCs) that encompass such AAEMs and components of such AFCs, other than the AAEM, that encompass one of such polymers.

  本公开的实施例涵盖具有至少一种重复单元的乙烯加成和ROMP聚合物，该重复单元包括一个包含N+（CH3）3OH−基团的组分。根据本公开的其他实施例，还包括由此类聚合物之一制成的碱性阴离子交换膜（AAEMs），包括这样的AAEM的阴离子燃料电池（AFCs）以及包括这样的聚合物之一的AFC的组件，除了AAEM。
• NORBORNENYLHYDROCARBYLENE DIHYDROCARBYLBORANES AND METHODS OF MAKING THE SAME
  申请人：PROMERUS, LLC

  公开号：US20150353582A1

  公开（公告）日：2015-12-10

  Embodiments of norbornenylhydrocarbylene dihydrocarbylboranes represented by the Formula (I), and methods of forming such norbornenylhydrocarbylene dihydrocarbylboranes are provided, where its is 0, 1 or 2, A is a C 2 to C 12 hydrocarbylene group; R 1 and R 2 are independently selected from a substituted or unsubstituted C 1 to C 12 hydrocarbyl, substituted or unsubstituted, monocyclic or bicyclic C 5 to C 7 rings, and R 1 and R 2 , taken together with the boron atom to which they are attached, can form a monocyclic or bicyclic ring; wherein the norbornenylhydrocarbylene dihydrocarbylboranes of Formula (I) are subject to the proviso that 9-norbornenylethyl-9-borabicyclo[3.3.1]nonane is not included.

  本发明提供了由式（I）表示的诺博烯基羟基烷基二烷基硼烷的实施例，以及形成这种诺博烯基羟基烷基二烷基硼烷的方法，其中它为0、1或2，A是C2到C12的烃基亚基；R1和R2分别选择自取代或未取代的C1到C12烃基、取代或未取代的单环或双环C5到C7环，并且R1和R2与它们所连接的硼原子一起可以形成单环或双环；其中式（I）的诺博烯基羟基烷基二烷基硼烷受到以下限制，即不包括9-诺博烯基乙基-9-硼杂双环[3.3.1]壬烷。