1,1,1,2,2,3,3,4,4,5,6,6,6-Tridecafluorohexane | 1998-54-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1,1,1,2,2,3,3,4,4,5,6,6,6-Tridecafluorohexane
• CAS: 1998-54-5
• 化学式: C₆HF₁₃
• 分子量: 320.05
• InChiKey: UIJKENUZXJTGFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  13

文献信息

• Acid- and radical-generating agent and method for generating acid and radical
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10451967B2

  公开（公告）日：2019-10-22

  It is a subject of the present invention to provide an acid- and radical-generating agent which has high sensitivity to an active energy ray having a wavelength of around 300 to 450 nm, and can exert both high acid-generating performance and high radical-generating performance, and has heat resistance; and a method for generating an acid and a radical. The present invention relates to a compound represented by the general formula (A); an acid- and radical-generating agent comprising the compound; and a method for generating an acid and a radical: wherein n pieces of R1 each independently represent an alkyl group, which may have a specific functional group in the chain, or in which a hydrogen atom may be substituted by a halogen atom; an alkoxy group, in which a hydrogen atom may be substituted by a halogen atom; an aryl group or an aryloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; or an arylalkyl group or an arylalkyloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; n pieces of R2 and R3 each independently represent a hydrogen atom, an alkyl group or an alkoxycarbonyl group; R4 to R7 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkenyl group, an aryl group, an alkoxycarbonyl group, a dialkylamino group or a nitro group; Y represents an oxygen atom, a sulfur atom, or a carbonyl group; n pieces of Z each independently represent a sulfonyl group or an alkoxyphosphoryl group; n represents 1 or 2.

  本发明的一个目的是提供一种对波长约为300至450纳米的活性能量射线具有高灵敏度的酸和自由基生成剂，能够发挥高酸生成性能和高自由基生成性能，并具有耐热性；以及一种生成酸和自由基的方法。本发明涉及一种由通式（A）表示的化合物；包括该化合物的酸和自由基生成剂；以及生成酸和自由基的方法：其中n个R1分别独立表示一种烷基基团，该烷基基团可能在链中具有特定的功能基团，或者氢原子可能被卤原子取代；一种烷氧基团，其中氢原子可能被卤原子取代；一种芳基或芳氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；或一种芳基烷基或芳基氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；n个R2和R3分别独立表示氢原子，烷基基团或烷氧羰基团；R4到R7分别独立表示氢原子，卤原子，烷基基团，烷氧基团，烯基基团，芳基，烷氧羰基团，二烷基氨基团或硝基；Y表示氧原子，硫原子或羰基；n个Z分别独立表示磺酰基或烷氧基磷酰基；n表示1或2。
• Magnesium-containing electrolytic solution
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10367231B2

  公开（公告）日：2019-07-30

  It is an object of the present invention to provide an electrolytic solution having high oxidation decomposition potential, where dissolution and deposition of magnesium proceed repeatedly and stably, using a non-nucleophilic alkoxide-type magnesium salt. The present invention relates to (1) an electrolytic solution for a magnesium battery comprising a mixture of a compound represented by the following general formula (I), a Lewis acid and a solvent: (2) an electrochemical device comprising the electrolytic solution, a positive electrode and a negative electrode, and (3) a compound represented by the following general formula (I′):

  本发明的目的是提供一种具有高氧化分解电位的电解液，使用非亲核烷氧基型镁盐，使镁的溶解和沉积能够重复和稳定地进行。本发明涉及(1)一种用于镁电池的电解液，包括以下通式(I)所代表的化合物、路易斯酸和溶剂的混合物：(2)一种电化学装置，包括上述电解液、正极和负极；以及(3)以下通式(I')所代表的化合物。
• A method of desiccating articles
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0516029A1

  公开（公告）日：1992-12-02

  A desiccant composition is disclosed comprising an alcohol and a fluorinated aliphatic hydrocarbon compound of the general formula         CnFmH2n+2-m wherein m and n each is a positive integer satisfying the relations: 4≦n≦6 and 2n-2≦m<2n+2, and a method of desiccating an article with said desiccant composition.

  本发明公开了一种干燥剂组合物，该组合物包含一种醇和一种通式如下的氟化脂族烃化合物 CnFmH2n+2-m 其中 m 和 n 均为满足以下关系的正整数：4≦n≦6和2n-2≦m<2n+2，以及用所述干燥剂组合物干燥物品的方法。
• CLEANING SOLVENT COMPOSITION AND CLEANING METHOD
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP0610507A1

  公开（公告）日：1994-08-17

  A cleaning solvent composition comprising an aliphatic fluorohydrocarbon represented by the general formula CnFmH2n+2-m (wherein n and m represent each a positive integer provided that 4 ≦ n ≦ 6 and 2n-3 ≦ m < 2n+2) or a mixture thereof with a C₁-C₄ alcohol and, further added thereto, a lactam and/or a carboxamide, a tertiary amine or an alcohol having an ether linkage and/or an amino linkage in its molecule. A cleaning method comprising removing dirty components by dipping in the above composition, conducting rinsing with the above mixture and thereafter, if necessary, conducting steam cleaning with the mixture. It is possible to obtain a cleaned article free from stain and dirt in a simplified drying step, because rinsing and steam cleaning can be conducted in a nonaqueous system with a cleaning solvent composition which does not destruct ozone, is nonflammable and has a potent detergency.

  一种清洁溶剂组合物，包含由通式 CnFmH2n+2-m 所代表的脂肪族氟烃 （其中 n 和 m 各代表一个正整数，条件是 4 ≦ n ≦ 6 和 2n-3 ≦ m < 2n+2）或其与 C₁-C₄ 醇的混合物，以及、内酰胺和/或羧酰胺、叔胺或分子中具有醚键和/或氨基键的醇的混合物。一种清洗方法，包括通过浸泡在上述组合物中去除脏污成分，用上述混合物进行冲洗，然后在必要时用混合物进行蒸汽清洗。由于冲洗和蒸汽清洗可在非水体系中进行，且清洗溶剂组合物不会破坏臭氧，不易燃且具有强力去污力，因此可简化干燥步骤，获得无污渍和污垢的清洗物品。
• Solid polymer electrolyte material, liquid composition, solid polymer fuel cell and fluorpolymer
  申请人：Asahi Glass Co., Ltd.

  公开号：EP1220344A2

  公开（公告）日：2002-07-03

  A solid polymer electrolyte material made of a copolymer comprising a repeating unit based on a fluoromonomer A which gives a polymer having an alicyclic structure in its main chain by radical polymerization, and a repeating unit based on a fluoromonomer B of the following formula (1):         CF2=CF(Rf)jSO2X     (1) wherein j is 0 or 1, X is a fluorine atom, a chlorine atom or OM wherein M is a hydrogen atom, an alkali metal atom or a group of NR1R2R3R4 (wherein each of R1, R2, R3 and R4 which may be the same or different, is a hydrogen atom or a monovalent organic group)}, and Rf is a C1-20 polyfluoroalkylene group having a straight chain or branched structure which may contain ether oxygen atoms.

  一种固体聚合物电解质材料，由以含氟单体 A 为基础的重复单元和以含氟单体 B 为基础的重复单元组成的共聚物制成，其中含氟单体 A 通过自由基聚合得到主链具有脂环结构的聚合物，含氟单体 B 为下式（1）的重复单元： CF2=CF(Rf)jSO2X (1) 其中 j 为 0 或 1，X 为氟原子、氯原子或 OM其中 M 为氢原子、碱金属原子或 NR1R2R3R4 基团（其中 R1、R2、R3 和 R4 可以相同或不同，各为氢原子或一价有机基团）}，Rf 为具有直链或支链结构的 C1-20 聚氟亚烷基，可含有醚氧原子。