POLYMER-(ORGANO)CLAY COMPLEX, COMPOSITION COMPRISING THE COMPLEX, SHEET-LIKE MATERIAL COMPRISING THE COMPLEX OR COMPOSITION, AND METHOD FOR PRODUCTION OF POLYMER-(ORGANO)CLAY COMPLEX
申请人:Asahi Kasei Chemicals Corporation
公开号:EP2113526A1
公开(公告)日:2009-11-04
Disclosed are: a high-performance polyphenylene ether-organoclay complex which is significantly improved in fire retardancy, durability (e.g., light resistance, chemical resistance, impact resistance), an ability of being extruded into a sheet and the like; and others. The polyphenylene ether-organoclay complex can be produced by: preparing a mixture comprising a solvent, a catalyst, a phenolic compound and an organoclay, wherein the organoclay is contained in an amount of 0.1 to 20 parts by mass relative to 100 parts by mass of the phenolic compound; contacting the mixture with an oxygen-containing gas to cause the oxidative polymerizationof the phenolic compound; and removing the solvent and the catalyst from the resulting polymerization mixture. This method is applicable to the production of a complex of an organoclay with other polymers such as an aromatic polycarbonate, a polyether imide and a polyacrylate.
本发明公开了一种高性能聚苯醚-有机土复合物,该复合物在阻燃性、耐久性(如耐光性、耐化学性、耐冲击性)、挤压成片材的能力等方面均有显著改善。聚苯醚-有机土复合物可通过以下方法生产:制备包含溶剂、催化剂、酚类化合物和有机土的混合物,其中有机土的含量相对于 100 份酚类化合物的质量为 0.1 至 20 份;将混合物与含氧气体接触以引起酚类化合物的氧化聚合;以及从生成的聚合混合物中除去溶剂和催化剂。该方法适用于生产有机土与其他聚合物(如芳香族聚碳酸酯、聚醚酰亚胺和聚丙烯酸酯)的复合物。