triphenyl(tetradecyl)-λ5-phosphane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenyl(tetradecyl)-λ5-phosphane
• 化学式: C₃₂H₄₅P
• 分子量: 460.7
• InChiKey: GYIVAOLGOHPDJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  33
• 可旋转键数：
  16
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Bicyclische Peroxide
  申请人：F. HOFFMANN-LA ROCHE AG

  公开号：EP0311955A2

  公开（公告）日：1989-04-19

  Die neuen bicyclischen Perioxide der allgemeinen Formel worin R eine gesättigte oder partiell ungesättigte Kohlenwasserstoffgruppe mit bis zu 15 Kohlenstoffatomen oder eine über eine Alkyl- oder Alkenylgruppe mit bis zu 7 Kohlenstoffatomen gebundene Aryl-, Heteroaryl-, Aryl­carbonyl- oder Heteroarylcarbonylgruppe bedeutet, besitzen wertvolle pharmakologische Eigenschaften. Sie zeigen insbesondere eine ausgeprägte Wirkung gegen die Erreger der Malaria und können zur Verhütung und Bekämpfung der Malaria verwendet werden.

  通式如下的新型双环过氧化物 其中 R 是最多含有 15 个碳原子的饱和或部分不饱和烃基，或通过最多含有 7 个碳原子的烷基或烯基键合的芳基、杂芳基、芳羰基或杂芳基羰基、 具有重要的药理特性。特别是，它们对疟疾病原体有明显的抑制作用，可用于预防和抗击疟疾。
• Organic solvent-soluble mucopolysaccharide, antibacterial antithrombogenic composition and medical material
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP0781566A2

  公开（公告）日：1997-07-02

  The present invention relates to an organic solvent-soluble mucopolysaccharide consisting of an ionic complex of at least one mucopolysaccharide (preferably heparin or heparin derivative) and a quaternary phosphonium, an antibacterial antithrombogenic composition comprising said organic solvent-soluble mucopolysaccharide and an organic polymer material, an antibacterial antithrombogenic composition comprising said organic solvent-soluble mucopolysaccharide and an antibacterial agent (preferably inorganic antibacterial agent such as silver zeolite), and to a medical material comprising said organic solvent-soluble mucopolysaccharide. The organic solvent-soluble mucopolysaccharide, and the antibacterial antithrombogenic composition and medical material containing the same, of the present invention, can easily impart antithrombogenicity and antibacterial property to a polymer to be a base material, which properties being maintained not only immediately after preparation of the material but also after long-term elution. Thus, the organic solvent-soluble mucopolysaccharide and antibacterial antithrombogenic material of the present invention show superior applicability as a material to impart antithrombogenicity and antibacterial ability to medical materials.

  本发明涉及一种有机溶剂可溶性粘多糖，由至少一种粘多糖（优选肝素或肝素衍生物）和季鏻的离子复合物组成；一种抗菌抗血栓形成组合物，由所述有机溶剂可溶性粘多糖和有机聚合物材料组成、由所述有机溶剂溶性粘多糖和抗菌剂（最好是无机抗菌剂，如银沸石）组成的抗菌抗血栓形成组合物，以及由所述有机溶剂溶性粘多糖组成的医用材料。本发明的有机溶剂溶性粘多糖、抗菌抗血栓形成组合物和含有该粘多糖的医用材料可以很容易地将抗血栓形成性和抗菌性赋予作为基础材料的聚合物，这些特性不仅在制备材料后立即保持，而且在长期洗脱后也能保持。因此，本发明的有机溶剂溶性粘多糖和抗菌抗血栓材料作为赋予医用材料抗血栓和抗菌能力的材料，显示出优越的适用性。
• Antibacterial polymeric moldings
  申请人：Toyo Boseki Kabushiki Kaisha

  公开号：EP0887373A2

  公开（公告）日：1998-12-30

  The invention provides an antibacterial polymeric molded product containing an anionic compound capable of combining, by ionic bond, with a cationic component of a water-soluble antibacterial agent, wherein the cationic component is combined with the anionic compound by ionic bond at least at the surface of the molded product.

  本发明提供了一种抗菌聚合物模塑产品，其中含有一种阴离子化合物，能够通过离子键与水溶性抗菌剂的阳离子成分结合，其中阳离子成分至少在模塑产品表面通过离子键与阴离子化合物结合。
• CARBON FIBER-REINFORCED THERMOPLASTIC RESIN COMPOSITION, MOLDING MATERIAL, PREPREG, AND METHODS FOR PRODUCING SAME
  申请人：Toray Industries, Inc.

  公开号：EP2765155A1

  公开（公告）日：2014-08-13

  Provided are a carbon fiber-reinforced thermoplastic resin composition excellent in interfacial adhesion between carbon fiber and a thermoplastic resin and excellent in dynamic characteristics, and a molding material, a prepreg, and a method for producing the same. The carbon fiber-reinforced thermoplastic resin composition includes the following components (A) and (B), carbon fiber and a thermoplastic resin; component (A): (A1) a bifunctional or higher functional epoxy compound and/or (A2) an epoxy compound which has a monofunctional or higher epoxy group and has one or more types of functional groups selected from a hydroxyl group, an amide group, an imide group, a urethane group, a urea group, a sulfonyl group and a sulfo group; and component (B): 0.1 to 25 parts by mass, based on 100 parts by mass of the component (A), of at least one reaction accelerator selected from the group consisting of [a] a specific tertiary amine compound (salt) (B1),[b] a specific quaternary ammonium salt (B2) and [c] a quaternary phosphonium salt and/or phosphine compound (B3).

  本发明提供了一种碳纤维增强热塑性树脂组合物，该组合物在碳纤维和热塑性树脂之间具有优异的界面粘合性和动态特性，还提供了一种成型材料、预浸料和生产方法。碳纤维增强热塑性树脂组合物包括以下组分（A）和（B）、碳纤维和热塑性树脂；组分（A）：（A1）双官能团或更高官能团的环氧化合物和/或（A2）具有单官能团或更高官能团的环氧化合物，该环氧化合物具有选自羟基、酰胺基、酰亚胺基、氨基甲酸酯基、脲基、磺酰基和磺酰基的一种或多种官能团；组分（B）：（A1）具有单官能团或更高官能团的环氧化合物，该环氧化合物具有选自羟基、酰胺基、酰亚胺基、氨基甲酸酯基、脲基、磺酰基和磺酰基的一种或多种官能团：以 100 重量份的组分（A）为基数，0.1 至 25 重量份的至少一种反应促进剂，该促进剂选 自以下组别：[a] 特定的叔胺化合物（盐）（B1）；[b] 特定的季铵盐（B2）；[c] 季鏻盐和/或膦化合物（B3）。
• CARBON FIBER MOLDING MATERIAL, MOLDING MATERIAL, AND CARBON FIBER-STRENGTHENING COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：EP2789648A1

  公开（公告）日：2014-10-15

  Provided is a carbon fiber forming raw material having excellent interfacial adhesion between carbon fibers and a thermosetting resin and capable of giving a molded article having excellent mechanical characteristics. The carbon fiber forming raw material is a carbon fiber forming raw material (Z) as a prepreg including sizing agent-coated carbon fibers and a thermosetting resin or a carbon fiber forming raw material (Y) as a forming material that includes sizing agent-coated carbon fibers and has a woven fabric form or a braid form. The sizing agent includes components (A) and (B). The component (A) is an epoxy compound having two or more epoxy groups or two or more types of functional groups. The component (B) is one or more compounds selected from the group consisting of a tertiary amine compound, a tertiary amine salt, a quaternary ammonium salt, a quaternary phosphonium salt, and a phosphine compound. The component (B) is contained in an amount of 0.1 to 25 parts by mass relative to 100 parts by mass of the component (A).

  本发明提供了一种碳纤维成型原料，该原料在碳纤维和热固性树脂之间具有极佳的界面粘附性，并能使成型品具有极佳的机械特性。该碳纤维成型原料是一种碳纤维成型原料（Z），作为预浸料，包括上浆剂包覆的碳纤维和热固性树脂；或者是一种碳纤维成型原料（Y），作为成型材料，包括上浆剂包覆的碳纤维，并具有编织物或编织物的形态。上浆剂包括组分（A）和（B）。组分（A）是具有两个或两个以上环氧基团或两种或两种以上官能团的环氧化合物。组分（B）是一种或多种化合物，选自由叔胺化合物、叔胺盐、季铵盐、季鏻盐和膦化合物组成的组。相对于 100 重量份的组分（A），组分（B）的含量为 0.1 至 25 重量份。